Citation: Abolghasem Davoodnia, Maryam Khashi, Niloofar Tavakoli-Hoseini. Cerium (IV) sulfate：A highly efficient reusable heterogeneous catalyst for the one-pot synthesis of 2,3-dihydroquinazolin-4(1H)-ones under solvent-free conditions[J]. Chinese Journal of Catalysis, ;2014, 35(7): 1054-1058. doi: 10.1016/S1872-2067(14)60041-3 shu

Cerium (IV) sulfate：A highly efficient reusable heterogeneous catalyst for the one-pot synthesis of 2,3-dihydroquinazolin-4(1H)-ones under solvent-free conditions

1.
Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, Iran

Corresponding author: Abolghasem Davoodnia,
Received Date: 7 December 2013
Available Online: 20 January 2014
Fund Project: This work was supported by Islamic Azad University, Mashhad Branch as research project (92429/302/64). (92429/302/64)

Cerium (IV) sulfate tetrahydrate, Ce(SO₄)₂·4H₂O, is a novel inorganic solid acidic catalyst that efficiently catalyzes the synthesis of 2,3-dihydroquinazolin-4(1H)-ones via the one-pot three-component reaction of isatoic anhydride, aromatic aldehydes, and a nitrogen source (ammonium acetate, ammonium carbonate, ammonium chloride, or methylamine) under solvent-free conditions. The desired products are obtained in short reaction time with high yields. The catalyst is inexpensive and readily available and can be recovered conveniently and reused such that considerable catalytic activity can still be achieved after the fifth run. Easy work-up and avoiding the use of harmful organic solvents are other advantages of this simple procedure.
- Cerium (IV) sulfate,
- 2,3-Dihydroquinazolin-4(1H)-ones,
- Heterogeneous catalysis,
- Solvent-free conditions
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沈阳化工大学材料科学与工程学院沈阳 110142