Citation: Liyun Song, Zongcheng Zhan, Xiaojun Liu, Hong He, Wenge Qiu, Xuehong Zi. NO_x selective catalytic reduction by ammonia over Cu-ETS-10 catalysts[J]. Chinese Journal of Catalysis, ;2014, 35(7): 1030-1035. doi: 10.1016/S1872-2067(14)60035-8 shu

NO_x selective catalytic reduction by ammonia over Cu-ETS-10 catalysts

1.
Key Laboratory of Beijing on Regional Air Pollution Control, Beijing University of Technology, Beijing 100124, China

Corresponding author: Hong He,
Received Date: 9 November 2013
Available Online: 14 January 2014
Fund Project:

Ion exchange method was used to fabricate Cu-ETS-10 titanosilicate catalysts, which possessed high activity, N₂ selectivity and SO₂ resistance for NO_x selective catalytic reduction (SCR). N₂ sorption measurements indicated that the microporous catalysts had high surface areas of 288-380 m²/g. The Cu content and speciation were investigated by inductively coupled plasma atomic emission spectrometry, H₂ temperature-programmed reduction, and diffuse reflectance infrared Fourier transform spectroscopy. Various Cu species coexisted within the catalyst. Isolated Cu²⁺ species were the active sites for NH₃-SCR, the number of which initially increased and then decreased with increasing Cu content. The catalytic activity of Cu-ETS-10 depended on the isolated Cu²⁺ species content.
- Titanosilicate,
- Copper,
- Nitrogen oxide,
- Ammonia,
- Selective catalytic reduction
1. [1]
  [1] Liu F D, Shan W P, Shi X Y, Zhang C B, He H. Chin J Catal (刘福东, 单文坡, 石晓燕, 张长斌, 贺泓. 催化学报), 2011, 32: 1113
2. [2]
  [2] Ye Q, Wang L F, Yang R T. Appl Catal A, 2012, 427-428: 24
3. [3]
  [3] Kwak J H, Tonkyn R G, Kim D H, Szanyi J, Peden C H F. J Catal, 2010, 275: 187
4. [4]
  [4] Shi X Y, Liu F D, Shan W P, He H. Chin J Catal (石晓燕, 刘福东, 单文波, 贺泓. 催化学报), 2012, 33: 454
5. [5]
  [5] Putluru S S R, Jensen A D, Riisager A, Fehrmann R. Catal Commun, 2012, 18: 41
6. [6]
  [6] Putluru S S R, Riisager A, Fehrmann R. Appl Catal B, 2011, 101: 183
7. [7]
  [7] Corma A, Fornés V, Palomares E. Appl Catal B, 1997, 11: 233
8. [8]
  [8] Fickel D W, D'Addio E, Lauterbach J A, Lobo R F. Appl Catal B, 2011, 102: 441
9. [9]
  [9] Xue J J, Wang X Q, Qi G S, Wang J, Shen M Q, Li W. J Catal, 2013, 297: 56
10. [10]
  [10] Ren L M, Zhang Y B, Zeng S J, Zhu L F, Sun Q, Zhang H Y, Yang C G, Meng X J, Yang X G, Xiao F S. Chin J Catal (任利敏, 张一波, 曾尚景, 朱龙凤, 孙琦, 张海燕, 杨承广, 孟祥举, 杨向光, 肖丰收. 催化学报), 2012, 33: 92
11. [11]
  [11] Martínez-Franco R, Moliner M, Franch C, Kustov A, Corma A. Appl Catal B, 2012, 127: 273
12. [12]
  [12] Kuznicki S M. US Patent 4 853 202. 1989
13. [13]
  [13] Pavel C C, Park S H, Dreier A, Tesche B, Schmidt W. Chem Mater 2006, 18: 3813
14. [14]
  [14] Bordiga S, Pazé C, Berlier G, Scarano D, Spoto G, Zecchina A, Lamberti C. Catal Today, 2001, 70: 91
15. [15]
  [15] Ren Y H, Gu M, Hu Y C, Yue B, Jiang L, Kong Z P, He H Y. Chin J Catal (任远航, 辜敏, 胡怡晨, 岳斌, 江磊, 孔祖萍, 贺鹤勇. 催化学报), 2012, 33: 123
16. [16]
  [16] Surolia P K, Tayade R J, Jasra R V. Ind Eng Chem Res, 2010, 49: 3961
17. [17]
  [17] Gervasini A, Picciau C, Auroux A. Microporous Mesoporous Mater, 2000, 35-36: 457
18. [18]
  [18] Carniti P, Gervasini A, Auroux A. Langmuir, 2001, 17: 6938
19. [19]
  [19] Gao F, Walter E D, Washton N M, Szanyi J, Peden C H F. ACS Catal, 2013, 3: 2083
20. [20]
  [20] Yu T, Wang J, Shen M Q, Li W. Catal Sci Technol, 2013, 3: 3234
21. [21]
  [21] Wang J, Yu T, Wang X Q, Qi G S, Xue J J, Shen M Q, Li W. Appl Catal B, 2012, 127: 137
22. [22]
  [22] Jiang X Y, Ding G H, Lou L P, Chen Y X, Zheng X M. J Mol Catal A, 2004, 218: 187
23. [23]
  [23] Krisnandi Y K, Lachowski E E, Howe R F. Chem Mater, 2006, 18: 928
24. [24]
  [24] Góra-Marek K, Palomares A E, Glanowska A, Sadowska K, Datka J. Microporous Mesoporous Mater, 2012, 162: 175
25. [25]
  [25] Tounsia H, Djemal S, Petitto C, Delahay G. Appl Catal B, 2011, 107: 158
26. [26]
  [26] Pereda-Ayo B, De La Torre U, Illán-Gómez M J, Bueno-López A, González-Velasco J R. Appl Catal B, 2014, 147: 420
27. [27]
  [27] Lu G, Li X Y, Qu Z P, Zhao Q D, Zhao L, Chen G H. Chem Eng J, 2011, 168: 1128
28. [28]
  [28] Praliaud H, Mikhailenko S, Chajar Z, Primet M. Appl Catal B, 1998, 16: 359
29. [29]
  [29] Zhang Q L, Qiu C T, Xu H D, Lin T, Gong M C, Chen Y Q. Chin J Catal (张秋林, 邱春天, 徐海迪, 林涛, 龚茂初, 陈耀强. 催化学报), 2010, 31: 1411
1. [1]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
2. [2]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
3. [3]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
4. [4]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
5. [5]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
6. [6]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
7. [7]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
8. [8]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
9. [9]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
10. [10]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
11. [11]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-. doi: 10.3866/PKU.WHXB202404023
12. [12]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
13. [13]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
14. [14]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
15. [15]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
16. [16]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
17. [17]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
18. [18]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
19. [19]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
20. [20]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(502)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

NOx selective catalytic reduction by ammonia over Cu-ETS-10 catalysts

Metrics

通讯作者: 陈斌, bchen63@163.com

NO_x selective catalytic reduction by ammonia over Cu-ETS-10 catalysts