Citation: Ahmad Reza Moosavi-Zare, Mohammad Ali Zolfigol, Omid Khaledian, Vahid Khakyzadeh. Condensation of 2-naphtol with arylaldehydes using acetic acid functionalized ionic liquids as highly efficient and reusable catalysts[J]. Chinese Journal of Catalysis, ;2014, 35(4): 573-578. doi: 10.1016/S1872-2067(14)60030-9 shu

Condensation of 2-naphtol with arylaldehydes using acetic acid functionalized ionic liquids as highly efficient and reusable catalysts

1.
a Department of Chemistry, University of Sayyed Jamaleddin Asadabadi, Asadabad, 6541835583, Iran;

Corresponding author: Ahmad Reza Moosavi-Zare, Mohammad Ali Zolfigol,
Received Date: 3 December 2013
Available Online: 13 January 2014

An efficient solvent-free protocol for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes from the condensation of 2-naphthol with arylaldehydes, using acetic acid functionalized imidazolium salts (1-carboxymethyl-3-methylimidazolium bromide ([cmmim]Br) and 1-carboxymethy1-3-methylimidazolium tetrafluoroborate ([cmmim]BF₄) as reusable catalysts, has been developed. The turn over frequency on the catalysts is several times higher than the other previously reported catalysts. Also, thermal gravimetric analysis and powder X-ray diffraction pattern of the catalysts have been studied.
- 14-Aryl-14H-dibenzo[a,j]xanthene,
- Acetic acid functionalized ionic liquid,
- 2-Naphthol,
- Aldehyde,
- Catalyst,
- Solvent-free
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沈阳化工大学材料科学与工程学院沈阳 110142