Citation: Shibiao Ren, Hongzhi Wen, Xianzhong Cao, Zhicai Wang, Zhiping Lei, Chunxiu Pan, Shigang Kang, Hengfu Shui. Promotion of Ni/clay catalytic activity for hydrogenation of naphthalene by organic modification of clay[J]. Chinese Journal of Catalysis, ;2014, 35(4): 546-552. doi: 10.1016/S1872-2067(14)60028-0 shu

Promotion of Ni/clay catalytic activity for hydrogenation of naphthalene by organic modification of clay

1.
Anhui Key Laboratory of Clean Coal Conversion and Utilization, School of Chemistry and Chemical Engineering, Anhui University of Technology, Ma'anshan 243002, Anhui, China

Corresponding author: Shibiao Ren, Hengfu Shui,
Received Date: 7 December 2013
Available Online: 7 January 2014
Fund Project: 国家自然科学基金委员会-神华集团有限公司煤炭联合基金(U1361125, U1261208) (U1361125, U1261208)国家自然科学基金(21176001, 51174254) (21176001, 51174254)

A Ni/montmorillonite (MMT) catalyst was prepared by an impregnation method using cetyltrimethylammonium bromide (CTAB)-pillared MMT as the supporting matrix and was characterized using infrared spectroscopy, X-ray diffraction, H₂ temperature-programmed desorption, N₂ adsorption-desorption, and ultraviolet diffuse reflectance spectroscopy. The catalytic activity of the Ni/MMT for the hydrogenation of naphthalene was also evaluated. The results show that the organic modification of MMT greatly improved the Ni dispersion and textural properties of the Ni/MMT catalyst. The as-prepared Ni/MMT catalyst showed high naphthalene conversion (88.2%) in the hydrogenation reaction; this is much higher than those achieved using Ni supported on pristine MMT (13.1%), Al₂O₃-pillared MMT (24.2%), and SBA-15 (68.2%). As a result of thermal decomposition of CTAB pillars during reduction of the Ni/MMT catalyst, the CTAB pillars mainly play a role in the Ni/MMT catalyst during impregnation. A mechanism for the promotion of the Ni/MMT catalytic activity by organic modification during impregnation is proposed.
- Nickel,
- Organic montmorillonite,
- High activity,
- Naphthalene,
- Hydrogenation
1. [1]
  [1] Stanislaus A, Cooper B H. Catal Rev-Sci Eng, 1994, 36: 75
2. [2]
  [2] Hu J B, Yu C L, Bi Y D, Wei L F, Chen J C, Chen X R. Chin J Catal (胡久彪, 余长林, 毕亚东, 魏龙福, 陈建钗, 陈喜蓉. 催化学报), 2014, 35: 8
3. [3]
  [3] Smoláková L, Botková Š, Čapek L, Priecel P, Sołtysek A, Kout M, Matějová L. Chin J Catal (催化学报), 2013, 34: 1905
4. [4]
  [4] Zhang G Q, Peng J X, Sun T J, Wang S D. Chin J Catal (张国权, 彭家喜, 孙天军, 王树东. 催化学报), 2013, 34: 1745
5. [5]
  [5] Anjaneyulu C, Kumar V V, Bhargava S K, Venugopal A. J Energy Chem, 2013, 22: 853
6. [6]
  [6] Nagendrappa G. Appl Clay Sci, 2011, 53: 106
7. [7]
  [7] Gil A, Korili S A, Vicente M A. Catal Rev-Sci Eng, 2008, 50: 153
8. [8]
  [8] De Stefanis A, Tomlinson A A G. Catal Today, 2006, 114: 126
9. [9]
  [9] Belver C, Mata G, Trujillano R, Vicente M A. Catal Lett, 2008, 123: 32
10. [10]
  [10] Mata G, Trujillano R, Vicente M A, Korili S A, Gil A, Belver C, Ciuffi K J, Nassar E J, Ricci G P, Cestari A, Nakagaki S. Microporous Mesoporous Mater, 2009, 124: 218
11. [11]
  [11] Louloudi A, Michalopoulos J, Gangas N H, Papayannakos N. Appl Catal A, 2003, 242: 41
12. [12]
  [12] Louloudi A, Papayannakos N. Appl Catal A, 2000, 204: 167
13. [13]
  [13] Zhou L M, Qi X L, Jiang X H, Zhou Y F, Fu H Y, Chen H. J Colloid Interf Sci, 2013, 392: 201
14. [14]
  [14] Scheuermann G M, Thomann R, Mülhaupt R. Catal Lett, 2009, 132: 355
15. [15]
  [15] Wang Y M, Wu Z Y, Shi L Y, Zhu J H. Adv Mater, 2005, 17: 323
16. [16]
  [16] Kirumakki S R, Shpeizer B G, Sagar G V, Chary K V R, Clearfield A. J Catal, 2006, 242: 319
17. [17]
  [17] Sun H J, Li S H, Zhang Y X, Jiang H B, Qu L L, Liu S C, Liu Z Y. Chin J Catal (孙海杰, 李帅辉, 张元馨, 江厚兵, 曲良龙, 刘寿长, 刘仲毅. 催化学报), 2013, 34: 1482
18. [18]
  [18] Zhou Y H, Liu J, Li X Y, Pan X L, Bao X H. J Nat Gas Chem, 2012, 21: 241
19. [19]
  [19] Li X F, Zhang W J, Zhang L M, Yang H Q. Chin J Catal (李晓菲, 张文娟, 张丽敏, 杨恒权. 催化学报), 2013, 34: 1192
20. [20]
  [20] Sivaiah M V, Petit S, Brendlé J, Patrier P. Appl Clay Sci, 2010, 48: 138
21. [21]
  [21] Ren S B, Zhao R, Zhang P, Lei Z P, Wang Z C, Kang S G, Pan C X, Shui H F. React Kinet Mech Cat, 2014, 111: 247
22. [22]
  [22] Ren S B, Zhang P, Shui H F, Lei Z P, Wang Z C, Kang S G. Catal Commun, 2010, 12: 132
23. [23]
  [23] Hao Q Q, Liu Z W, Zhang B S, Wang G W, Ma C Y, Frandsen W, Li J J, Liu Z T, Hao Z P, Su D S. Chem Mater, 2012, 24: 972
24. [24]
  [24] Velu S, Gangwal S K. Solid State Ionics, 2006, 177: 803
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