Citation: Guifu Chen, Feng Wang, Yehong Wang, Xiaochen Zhang, Hongqiang Qin, Hanfa Zou, Jie Xu. Imine-linked conjugated organic polymer bearing bis(imino)pyridine ligands and its catalytic application in C-C coupling reactions[J]. Chinese Journal of Catalysis, ;2014, 35(4): 540-545. doi: 10.1016/S1872-2067(14)60021-8 shu

Imine-linked conjugated organic polymer bearing bis(imino)pyridine ligands and its catalytic application in C-C coupling reactions

Guifu Chen ^a,b ,
Feng Wang ^a,, ,
Yehong Wang ^a ,
Xiaochen Zhang ^a ,
Hongqiang Qin ^a ,
Hanfa Zou ^a ,
Jie Xu ^a,,

1.
a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Feng Wang, Jie Xu,
Received Date: 1 November 2013
Available Online: 6 January 2014
Fund Project: 国家自然科学基金(21073184, 21273231) (21073184, 21273231)

Covalent organic polymers are an emerging class of materials with potential applications in areas including molecular separation, gas sorption, and catalysis. A novel fully conjugated organic polymer bearing bis(imino)pyridine (COP-BIP) and its catalytic function are reported here. Unlike previous COP materials, the imine bonds of COP-BIP act as both linkages and complexation sites for the binding of metal ions. A clear structure is presented based on ultraviolet-visible, Fourier transform infrared, and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry characterization. The COP-BIP materials are thermally stable up to 440 ℃ and are insoluble in conventional solvents. In addition, COP-BIP complexes Pd ions on bis(imino)pyridine sites and forms a heterogeneous catalyst, which exhibits excellent catalytic activity in the Suzuki-Miyaura C-C coupling reaction.
- Conjugated organic polymer material,
- Bis(imino)pyridine ligand,
- Catalysis,
- Suzuki-Miyaura C-C coupling
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