Citation: Mohsen Keyvanfard, Maryam Tahmasbi, Hassan Karimi-Maleh, Khadijeh Alizad. A voltammetric sensor with a multiwall carbon nanotube paste electrode and naphthol green as a mediator for the determination of N-actylcysteine in the presence of tryptophan[J]. Chinese Journal of Catalysis, ;2014, 35(4): 501-508. doi: 10.1016/S1872-2067(14)60019-X shu

A voltammetric sensor with a multiwall carbon nanotube paste electrode and naphthol green as a mediator for the determination of N-actylcysteine in the presence of tryptophan

1.
a Department of chemistry, Majlesi Branch, Islamic Azad University, Isfahan, Iran;

Corresponding author: Mohsen Keyvanfard, Hassan Karimi-Maleh,
Received Date: 17 November 2013
Available Online: 27 December 2013

A multiwall carbon nanotube modified electrode prepared by incorporating multiwall carbon nanotubes in the electrode of a sensor and naphthol green as a homogeneous mediator was used as a voltammetric sensor for the determination of N-actylcysteine (N-AC) in the presence of tryptophan (Trp). The voltammograms of differential pulse voltammetry of N-AC in a mixture with Trp were separated from each other by a potential difference of 200 mV, which allowed the determination of both N-AC and Trp simultaneously. Under the optimum conditions, the electrocatalytic currents increased linearly with N-AC concentration in the range of 0.25-400 μmol/L (two linear segments with different slopes). The detection limit for N-AC was 0.08 μmol/L. The kinetic parameters of the system were determined using electrochemical methods. The method was applied for the determination of N-AC in drug and urine samples.
- N-actylcysteine,
- Tryptophan,
- Multiwall carbon nanotube,
- Naphthol green,
- Sensor
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