Citation: Tiago P. Braga, Regina C. R. Santos, Barbara M. C. Sales, Bruno R. da Silva, Antônio N. Pinheiro, Edson R. Leite, Antoninho Valentini. CO₂ mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology[J]. Chinese Journal of Catalysis, ;2014, 35(4): 514-523. doi: 10.1016/S1872-2067(14)60018-8 shu

CO₂ mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology

1.
a Department of Analytical Chemistry and Physical Chemistry, Federal University of Ceara, Fortaleza, CE, CEP:60440-554, Brazil;

Corresponding author: Antoninho Valentini,
Received Date: 19 September 2013
Available Online: 30 December 2013

A factorial experimental design was combined with response surface methodology (RSM) to optimize the catalyzed CO₂ consumption by coke deposition and syngas production during the dry reforming of CH₄. The CH₄/CO₂ feed ratio and the reaction temperature were chosen as the variables, and the selected responses were CH₄ and CO₂conversion, the H₂/CO ratio, and coke deposition. The optimal reaction conditions were found to be a CH₄/CO₂ feed ratio of approximately 3 at 700 ℃, producing a large quantity of coke and realizing high CO₂ conversion. Furthermore, Raman results showed that the CH₄/CO₂ ratio and reaction temperature affect the system's response, particularly the characteristics of the coke produced, which indicates the formation of carbon nanotubes and amorphous carbon.
- Factorial design,
- Carbon dioxide,
- Reforming,
- Methane,
- Carbon nanotube
1. [1]
  [1] Nigam P S, Singh A. Prog Energy Combust Sci, 2011, 37: 52
2. [2]
  [2] Figueroa J D, Fout T, Plasynski S, McIlvried H, Srivastava R D. Int J Greenh Gas Control, 2008, 2: 9
3. [3]
  [3] Demirbas A. Appl Energy, 2009, 86: S108
4. [4]
  [4] Naik S N, Goud V V, Rout P K, Dalai A K. Renew Sustain Energy Rev, 2010, 14: 578
5. [5]
  [5] Kang K M, Kim H W, Shim I W, Kwak H Y. Fuel Process Technol, 2011, 92: 1236
6. [6]
  [6] Barroso-Quironga M M, Castro-Luna A E. Int J Hydrogen Energy, 2010, 35: 6052
7. [7]
  [7] Rivas M E, Fierro J L G, Goldwasser M R, Pietri E, Perez-Zurita M J, Griboval-Constant A, Leclercq G. Appl Catal A, 2008, 344: 10
8. [8]
  [8] Shi C, Zhang A J, Li X S, Zhang S H, Zhu A M, Ma Y F, Au C. Appl Catal A, 2012, 431-432: 164
9. [9]
  [9] Ibrahim A A, Fakeeha A H, Al-Fatesh A S. Int J Hydrogen Energy, 2014, 39: 1680
10. [10]
  [10] Sokolov S, Kondratenko E V, Pohl M M, Rodemerck U. Int J Hydrogen Energy, 2013, 38: 16121
11. [11]
  [11] Fukuhara C, Hyodo R, Yamamoto K, Masuda K, Watanabe R. Appl Catal A, 2013, 468: 18
12. [12]
  [12] da Silva B R, dos Santos R C R, Valentini A. Curr Top Catal, 2012, 10: 93
13. [13]
  [13] Albarazi A, Beaunier P, Da Costa P. Int J Hydrogen Energy, 2013, 38: 127
14. [14]
  [14] Pour A N, Shahri S M K, Bozorgzadeh H R, Zamani Y, Tavasoli A, Marvast M A. Appl Catal A, 2008, 348: 201
15. [15]
  [15] Guo J Z, Hou Z Y, Gao J, Zheng X M. Fuel, 2008, 87: 1348
16. [16]
  [16] Maluf S S, Assaf E M. Fuel, 2009, 88: 1547
17. [17]
  [17] Hou Z Y, Gao J, Guo J Z, Liang D, Lou H, Zheng X M. J Catal, 2007, 250: 331
18. [18]
  [18] Gao J, Hou Z Y, Guo J Z, Zhu Y H, Zheng X M. Catal Today, 2008, 131: 278
19. [19]
  [19] Zhang J G, Wang H, Dalai A K. Appl Catal A, 2008, 339: 121
20. [20]
  [20] Zhao C G, Ji L J, Liu H J, Hu G J, Zhang S M, Yang M S, Yang Z Z. J Solid State Chem, 2004, 177: 4394
21. [21]
  [21] Mittal H, Mishra S B, Mishra A K, Kaith B S, Jindal R. J Inorg Organomet Polym Mater, 2013, 23: 1128
22. [22]
  [22] Wu Y Y, Zhou S Q, Qin F H, Ye X Y, Zheng K. J Hazard Mater, 2010, 180: 456
23. [23]
  [23] Olmez-Hanci T, Arslan-Alaton I, Basar G. J Hazard Mater, 2011, 185: 193
24. [24]
  [24] Braga T P, Sales B M C, Pinheiro A N, Herrera W T, Baggio-Saitovitch E, Valentini A. Catal Sci Technol, 2011, 1: 1383
25. [25]
  [25] Hormozi-Nezhad M R, Jalali-Heravi M, Robatjazi H, Ebrahimi-Najafabadi H. Colloids Surf A, 2012, 393: 46
26. [26]
  [26] de la Osa A R, de Lucas A, Sanchez-Silva L, Diaz-Maroto J, Valverde J L, Sanchez P. Fuel, 2012, 95: 587
27. [27]
  [27] Karimipour S, Gerspacher R, Gupta R, Spiteri R J. Fuel, 2013, 103: 308
28. [28]
  [28] Pompeo F, Nichio N N, Souza M M V M, Cesar D V, Ferretti O A, Schmal M. Appl Catal A, 2007, 316: 175
29. [29]
  [29] Gonçalves N S, Carvalho J A, Lima Z M, Sasaki J M. Mater Lett, 2012, 72: 36
30. [30]
  [30] Zhao J F, Zhao J J, Chen J H, Wang X H, Han Z D, Li Y H. Ceram Int, 2014, 40: 3379
31. [31]
  [31] Chen G, Chen J, Srinivasakannan C, Peng J H. Appl Surf Sci, 2012, 258: 3068
32. [32]
  [32] Pavlova S, Kapokova L, Bunina R, Alikina G, Sazonova N, Krieger T, Ishchenko A, Rogov V, Gulyaev R, Sadykov V, Mirodatos C. Catal Sci Technol, 2012, 2: 2099
33. [33]
  [33] Xu L L, Song H L, Chou L J. Appl Catal B, 2011, 108-109: 177
34. [34]
  [34] Pocsik I, Hundhausen M, Koos M, Ley L. J Non-Cryst Solids, 1998, 227-230 (Pt. B): 1083
35. [35]
  [35] Klar P, Lidorikis E, Eckmann A, Verzhbitskiy I A, Ferrari A C, Casiraghi C. Phys Rev B, 2013, 87: 205435
36. [36]
  [36] Ferrari A C. Solid State Commun, 2007, 143: 47
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沈阳化工大学材料科学与工程学院沈阳 110142

CO2 mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology

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通讯作者: 陈斌, bchen63@163.com

CO₂ mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology