Citation: Qiuhe Ren, Yizheng Huang, Hong Ma, Jin Gao, Jie Xu. Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides[J]. Chinese Journal of Catalysis, ;2014, 35(4): 496-500. doi: 10.1016/S1872-2067(14)60012-7 shu

Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides

Qiuhe Ren ^a,b ,
Yizheng Huang ^a ,
Hong Ma ^a ,
Jin Gao ^a ,
Jie Xu ^a,,

1.
a Dalian National Laboratory for Clean Energy, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Jie Xu,
Received Date: 24 November 2013
Available Online: 25 December 2013
Fund Project: 中国科学院知识创新工程重要方向项目(KSCX2-EW-G-5) (KSCX2-EW-G-5)中国科学院战略性先导科技专项-应对气候变化的碳收支认证及相关问题(XDA05010203) (XDA05010203)国家自然科学基金(21233008). (21233008)

The promotion effect of alkali metal halides toward the AlCl₃-catalyzed conversion of glucose to 5-hydroxymethylfurfural (HMF) was investigated. The results show that NaF inhibited the reaction. However, NaI and NaBr promoted the reaction significantly, and the promotion effect of NaI was more obvious than that of NaBr. In N,N-dimethylacetamide (DMAC), when NaI was used as an additive for the AlCl₃-catalyzed conversion of glucose at 130 ℃ for 15 min, glucose conversion increased from 71% to 86%, and the HMF yield increased from 36% to 62%. The AlCl₃-NaI-DMAC system could also be used for the catalytic conversion of other carbohydrates such as fructose, mannose, sucrose, maltose, cellobiose, and inulin to HMF. When sucrose was used as the feedstock, a 63% HMF yield was achieved.
- Carbohydrate,
- 5-Hydroxymethylfurfural,
- Metal halide,
- Catalysis
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