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Citation: LIU Yong, MENG Ming, YAO Jin-Song, ZHA Yu-Qing. Preparation and Characterization of the Multi-component Mesoporous Mixed Oxide La-Mn-Ce-O Catalysts[J]. Acta Physico-Chimica Sinica, ;2007, 23(05): 641-646. doi: 10.1016/S1872-1508(07)60041-2 shu

Preparation and Characterization of the Multi-component Mesoporous Mixed Oxide La-Mn-Ce-O Catalysts

1.
Department of Catalysis Science and Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China

Received Date: 8 October 2006
Available Online: 11 April 2007

A series of mesoporous multicomponent mixed oxide catalysts La-Mn-Ce-O with various (nLa+nMn)/(nLa+nMn+nCe) ratios were prepared by citric acid complexation-organic template decomposition (CAC-OTD) method. For comparison, the sample with the same composition was also prepared by conventional coprecipitation method. The results of N2 adsorption/desorption showed that the samples prepared by CAC-OTD method possessed relatively large specific surface area and uniformpore diameter distribution (3.4-4.4 nm). The results of X-ray diffraction (XRD) identified the formation of La-Ce and Mn-Ce solid solution. No Mn species were detected by XRD. The results of X-ray photoelectron spectroscopy (XPS) showed that there was a strong electronic state interaction betweenMn and Ce species, resulting in the formation of Mn 2p shake-up peak. Such interaction enhanced the transfer of oxygen species from Ce to Mn oxide and therefore increased the redox activity of the samples. The sample with the strongest shake-up peak showed the highest oxidation activity. The results of temperature programmed reduction (TPR) showed that the manganese species in the samples prepared by using CAC-OTD method were easier to be reduced, which was relevant to the oxidation activity of the catalysts. The results of activity evaluation showed that the light-off temperature of the LMC(0.5)-500 sample was about 50 ℃ lower than that of the sample prepared by using coprecipitation method. The samples prepared by using CAC-OTDmethod showed od thermal stability.
- Multi-component mesoporous catalyst; Preparation; Citric acid complexation; Organic template; Structural characterization
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沈阳化工大学材料科学与工程学院沈阳 110142

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