Citation: Meng Jin, Zhao-Chen Zhu, Qiu-Yan Liao, Qian-Qian Li, Zhen Li. Dendronized Polymers with High FTC-chromophore Loading Density: Large Second-order Nonlinear Optical Effects, Good Temporal and Thermal Stability[J]. Chinese Journal of Polymer Science, ;2020, 38(2): 118-125. doi: 10.1007/s10118-019-2307-z shu

Dendronized Polymers with High FTC-chromophore Loading Density: Large Second-order Nonlinear Optical Effects, Good Temporal and Thermal Stability

Meng Jin ^a ,
Zhao-Chen Zhu ^a ,
Qiu-Yan Liao ^a ,
Qian-Qian Li ^a,, ,
Zhen Li ^a,b,,

a.
Department of Chemistry, Sauvage Center for Molecular Sciences, Wuhan University, Wuhan 430072, China
b.
Institute of Molecular Aggregation Science, Tianjin University, Tianjin 300072, China

Corresponding author: Qian-Qian Li, qianqian-alinda@163.com Zhen Li, lizhen@whu.edu.cn;lichemlab@163.com
Received Date: 4 May 2019
Revised Date: 23 May 2019
Available Online: 24 September 2019

In this study, two new dendronized nonlinear optical (NLO) polymers were synthesized with high FTC chromophore loading density by introduction of high generation chromophore dendrons on the side chains. Due to their suitable molecular weights, both of them possessed good solubility in common solvents. They also inherited the advantages of dendrimers (large NLO coefficient), especially for PG2 whose NLO coefficient d₃₃ value was as high as 282 pm·V^–1. Also, PG2 had a good temporal stability with 80% of its maximum value being retained at the temperature as high as 129 °C.
- Second-order nonlinear optics,
- Dendronized polymers,
- Chromophore
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