Citation: Guan-Hang Yu, Qing Han, Liang-Ti Qu. Graphene Fibers: Advancing Applications in Sensor, Energy Storage and Conversion[J]. Chinese Journal of Polymer Science, ;2019, 37(6): 535-547. doi: 10.1007/s10118-019-2245-9 shu

Graphene Fibers: Advancing Applications in Sensor, Energy Storage and Conversion

Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science Ministry of Education, School of Chemistry, Beijing Institute of Technology, Beijing 100081, China

Corresponding author: Qing Han, qhan@bit.edu.cn Liang-Ti Qu, lqu@bit.edu.cn
Received Date: 18 January 2019
Revised Date: 19 February 2019
Available Online: 27 March 2019

Graphene fibers are a kind of novel carbon fibers assembled by orderly aligned graphene sheets with high flexibility, good conductivity, high thermal conductivity, and low density, which make them possible to be widely used in high-performance and multi-functional compound materials as well as flexible electronic devices. In this review, we summarize the research progress in the synthesis of graphene fibers, and their applications in sensor, energy storage, and energy conversion. Furthermore, the current issues and some prospects for the future trend of graphene fibers are discussed.
- Graphene fibers,
- Assembly,
- Functionalization,
- Sensor,
- Energy storage and conversion
1. [1]
  Donnet, J. B. in Carbon fibers. Marcel Dekker, Inc, 1998.
2. [2]
  He, F. in Carbon fiber and graphite fiber. Chemical Industry Press, 2010.
3. [3]
  Jeffries, R. Prospects for carbon fibres. Nature 1971, 232(5309), 304-307. doi: 10.1038/232304a0
4. [4]
  Frank, E.; Steudle, L. M.; Ingildeev, D.; Spörl, J. M.; Buchmeiser, M. R. Carbon fibers: precursor systems, processing, structure, and properties. Angew. Chem. Int. Ed. 2014, 53(21), 5262-5298. doi: 10.1002/anie.v53.21
5. [5]
  Standage, A. E.; Prescott, R. High elastic modulus carbon fibre. Nature 1966, 211(5045), 169-169.
6. [6]
  Moreton, R.; Watt, W.; Johnson, W. Carbon fibres of high strength and high breaking strain. Nature 1967, 213(5077), 690-691. doi: 10.1038/213690a0
7. [7]
  Iijima, S. Helical microtubules of graphitic carbon. Nature 1991, 354(6348), 56-58. doi: 10.1038/354056a0
8. [8]
  Dalton, A. B.; Collins, S.; Munoz, E.; Razal, J. M.; Ebron, V. H.; Ferraris, J. P.; Coleman, J. N.; Kim, B. G.; Baughman, R. H. Super-tough carbon-nanotube fibres-these extraordinary composite fibres can be woven into electronic textiles. Nature 2003, 423(6941), 703-703. doi: 10.1038/423703a
9. [9]
  Ericson, L. M.; Fan, H.; Peng, H. Q.; Davis, V. A.; Zhou, W.; Sulpizio, J.; Wang, Y. H.; Booker, R.; Vavro, J.; Guthy, C.; Parra-Vasquez, A. N. G.; Kim, M. J.; Ramesh, S.; Saini, R. K.; Kittrell, C.; Lavin, G.; Schmidt, H.; Adams, W. W.; Billups, W. E.; Pasquali, M.; Hwang, W. F.; Hauge, R. H.; Fischer, J. E.; Smalley, R. E. Macroscopic, neat, single-walled carbon nanotube fibers. Science 2004, 305(5689), 1447-1450. doi: 10.1126/science.1101398
10. [10]
  Vigolo, B.; Penicaud, A.; Coulon, C.; Sauder, C.; Pailler, R.; Journet, C.; Bernier, P.; Poulin, P. Macroscopic fibers and ribbons of oriented carbon nanotubes. Science 2000, 290(5495), 1331-1334. doi: 10.1126/science.290.5495.1331
11. [11]
  Davis, V. A.; Parra-Vasquez, A. N. G.; Green, M. J.; Rai, P. K.; Behabtu, N.; Prieto, V.; Booker, R. D.; Schmidt, J.; Kesselman, E.; Zhou, W.; Fan, H.; Adams, W. W.; Hauge, R. H.; Fischer, J. E.; Cohen, Y.; Talmon, Y.; Smalley, R. E.; Pasquali, M. True solutions of single-walled carbon nanotubes for assembly into macroscopic materials. Nat. Nanotechnol. 2009, 4(12), 830-834. doi: 10.1038/nnano.2009.302
12. [12]
  Jiang, K. L.; Li, Q. Q.; Fan, S. S. Nanotechnology: spinning continuous carbon nanotube yarns-carbon nanotubes weave their way into a range of imaginative macroscopic applications. Nature 2002, 419(6909), 801-801. doi: 10.1038/419801a
13. [13]
  Li, Y. L.; Kinloch, I. A.; Windle, A. H. Direct spinning of carbon nanotube fibers from chemical vapor deposition synthesis. Science 2004, 304(5668), 276-278. doi: 10.1126/science.1094982
14. [14]
  Zhang, M.; Atkinson, K. R.; Baughman, R. H. Multifunctional carbon nanotube yarns by downsizing an ancient technology. Science 2004, 306(5700), 1358-1361. doi: 10.1126/science.1104276
15. [15]
  Zhang, X. B.; Jiang, K. L.; Teng, C.; Liu, P.; Zhang, L.; Kong, J.; Zhang, T. H.; Li, Q. Q.; Fan, S. S. Spinning and processing continuous yarns from 4-inch wafer scale superaligned carbon nanotube arrays. Adv. Mater. 2006, 18(12), 1505-1510. doi: 10.1002/(ISSN)1521-4095
16. [16]
  Weng, W. Z.; He, S. S.; Song, H. Y.; Li, X. Q.; Cao, L. H.; Hu, Y. J.; Cui, J.; Zhou, Q. R.; Peng, H. S.; Su, J. C. Aligned carbon nanotubes reduce hypertrophic scar via regulating cell behavior. ACS Nano 2018, 12(8), 7601−7612. doi: 10.1021/acsnano.7b07439
17. [17]
  He, S. S.; Zhang, Y. Y.; Qiu, L. B.; Zhang, L. S.; Xie, Y.; Pan, J.; Chen, P. N.; Wang, B. J.; Xu, X. J.; Hu, Y. J.; Dinh, C. T.; De Luna, P.; Banis, M. N.; Wang, Z. Q.; Sham, T. K.; Gong, X. G.; Zhang, B.; Peng, H. S.; Sargent, E. H. Chemical-to-electricity carbon: water device. Adv. Mater. 2018, 30(18), 1707635. doi: 10.1002/adma.201707635
18. [18]
  Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A. Electric field effect in atomically thin carbon films. Science 2004, 306(5696), 666-669. doi: 10.1126/science.1102896
19. [19]
  Balandin, A. A.; Ghosh, S.; Bao, W. Z.; Calizo, I.; Teweldebrhan, D.; Miao, F.; Lau, C. N. Superior thermal conductivity of single-layer graphene. Nano Lett. 2008, 8(3), 902-907. doi: 10.1021/nl0731872
20. [20]
  Lee, C. G.; Wei, X. D.; Kysar, J. W.; Hone, J. Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 2008, 321(5887), 385-388. doi: 10.1126/science.1157996
21. [21]
  Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Katsnelson, M. I.; Grigorieva, I. V.; Dubonos, S. V.; Firsov, A. A. Two-dimensional gas of massless dirac fermions in graphene. Nature 2005, 438(7065), 197-200. doi: 10.1038/nature04233
22. [22]
  Zhang, Y. B.; Tan, Y. W.; Stormer, H. L.; Kim, P. Experimental observation of the quantum Hall effect and Berry’s phase in graphene. Nature 2005, 438(7065), 201-204. doi: 10.1038/nature04235
23. [23]
  Bolotin, K. I.; Sikes, K. J.; Jiang, Z.; Klima, M.; Fudenberg, G.; Hone, J.; Kim, P.; Stormer, H. L. Ultrahigh electron mobility in suspended graphene. Solid State Commun. 2008, 146(9-10), 351-355. doi: 10.1016/j.ssc.2008.02.024
24. [24]
  Morozov, S. V.; Novoselov, K. S.; Katsnelson, M. I.; Schedin, F.; Elias, D. C.; Jaszczak, J. A.; Geim, A. K. Giant intrinsic carrier mobilities in graphene and its bilayer. Phys. Rev. Lett. 2008, 100(1), 016602. doi: 10.1103/PhysRevLett.100.016602
25. [25]
  Chen, H. J.; Jang, C.; Xiao, S. D.; Ishigami, M.; Fuhrer, M. S. Intrinsic and extrinsic performance limits of graphene devices on SiO₂. Nat. Nanotechnol. 2008, 3(4), 206-209. doi: 10.1038/nnano.2008.58
26. [26]
  Hummers, W. S.; Offeman, R. E. Preparation of graphitic oxide. J. Am. Chem. Soc. 1958, 80(6), 1339-1339. doi: 10.1021/ja01539a017
27. [27]
  Brodie, B. C. On the atomic weight of graphite. Philos. Trans. R. Soc. Lond. 1859, 149, 249-259. doi: 10.1098/rstl.1859.0013
28. [28]
  Staudenmaier, L. Verfahren zur darstellung der graphitsäure. Ber. Dtsch. Chem. Ges. 1898, 31(2), 1481-1487. doi: 10.1002/(ISSN)1099-0682
29. [29]
  Si, Y. C.; Samulski, E. T. Synthesis of water soluble graphene. Nano Lett. 2008, 8(6), 1679-1682. doi: 10.1021/nl080604h
30. [30]
  Pei, S.; Zhao, J.; Du, J.; Ren, W.; Cheng, H. M. Direct reduction of graphene oxide films into highly conductive and flexible graphene films by hydrohalic acids. Carbon 2010, 48(15), 4466-4474. doi: 10.1016/j.carbon.2010.08.006
31. [31]
  Moon, K.; Lee, J.; Ruoff, R. S.; Lee, H. Reduced graphene oxide by chemical graphitization. Nat. Commun. 2010, 1, 73-78.
32. [32]
  Becerril, H. A.; Mao, J.; Liu, Z.; Stoltenberg, R. M.; Bao, Z.; Chen, Y. S. Evaluation of solution-processed reduced graphene oxide films as transparent conductors. ACS Nano 2008, 2(3), 463-470. doi: 10.1021/nn700375n
33. [33]
  McAllister, M. J.; Li, J.; Adamson, D. H.; Schniepp, H. C.; Abdala, A. A.; Liu, J.; Herrera-Alonso, M.; Milius, D. L.; Car, R.; Prud’homme, R. K.; Aksay, I. A. Single sheet functionalized graphene by oxidation and thermal expansion of graphite. Chem Mater. 2007, 19(18), 4396-4404. doi: 10.1021/cm0630800
34. [34]
  Zhu, Y. W.; Stoller, M. D.; Cai, W. W.; Velamakanni, A.; Piner, R. D.; Chen, D.; Ruoff, R. S. Exfoliation of graphite oxide in propylene carbonate and thermal reduction of the resulting graphene oxide platelets. ACS Nano 2010, 4(2), 1227-1233. doi: 10.1021/nn901689k
35. [35]
  Wang, Z. J.; Zhou, X. Z.; Zhang, J.; Boey, F.; Zhang, H. Direct electrochemical reduction of single-layer graphene oxide and subsequent functionalization with glucose oxidase. J. Phys. Chem, C 2009, 113(32), 14071-14075. doi: 10.1021/jp906348x
36. [36]
  Guo, H.; Wang, X.; Qian, Q.; Wang, F.; Xia, X. H. A green approach to the dynthesis of graphene nanosheets. ACS Nano 2009, 3(9), 2653-2659. doi: 10.1021/nn900227d
37. [37]
  Geim, A. K.; Novoselov, K. S. The rise of graphene. Nat. Mater. 2006, 6(3), 183-191.
38. [38]
  Xu, Z.; Liu, Y.; Zhao, X.; Peng, L.; Sun, H.; Xu, Y.; Ren, X.; Jin, C.; Xu, P.; Wang, M.; Gao, C. Ultrastiff and strong graphene fibers via full-scale synergetic defect engineering. Adv. Mater. 2016, 28(30), 6449-6456. doi: 10.1002/adma.201506426
39. [39]
  Liu, Y. J.; Liang, H.; Xu, Z.; Xi, J. B.; Chen, G. F.; Gao, W. W.; Xue, M. Q.; Gao, C. Superconducting continuous graphene fibers via calcium intercalation. ACS Nano 2017, 11(4), 4301−4306. doi: 10.1021/acsnano.7b01491
40. [40]
  Lim, L.; Liu, Y. S.; Liu, W. W.; Tjandra, R.; Rasenthiram, L.; Chen, Z. W.; Yu, A. P. All-in-one graphene based composite fiber: toward wearable supercapacitor. ACS Appl. Mater. Interfaces 2017, 9(45), 39576-39583. doi: 10.1021/acsami.7b10182
41. [41]
  Meng, J.; Nie, W. Q.; Zhang, K.; Xu, F. J.; Ding, X.; Wang, S. R.; Qiu, Y. P. Enhancing electrochemical performance of graphene fiber-based supercapacitors by plasma treatment. ACS Appl. Mater. Interfaces 2018, 10(16), 13652−13659. doi: 10.1021/acsami.8b04438
42. [42]
  Choi, S. J.; Yu, H. Y.; Jang, J. S.; Kim, M. H.; Kim, S. J.; Jeong, H. S.; Kim, I. D. Nitrogen-doped single graphene fiber with platinum water dissociation catalyst for wearable humidity sensor. Small 2018, 14(13), 1703934. doi: 10.1002/smll.v14.13
43. [43]
  Xu, Z.; Gao, C. Graphene chiral liquid crystals and macroscopic assembled fibres. Nat. Commun. 2011, 2, 571. doi: 10.1038/ncomms1583
44. [44]
  Xu, Z.; Zhang, Y.; Li, P. G.; Gao, C. Strong, conductive, lightweight, neat graphene aerogel fibers with aligned pores. ACS Nano 2012, 6(8), 7103-7113. doi: 10.1021/nn3021772
45. [45]
  Ritchie, R. O. The conflicts between strength and toughness. Nat. Mater. 2011, 10(11), 817−822. doi: 10.1038/nmat3115
46. [46]
  Li, M. C.; Zhang, X. H.; Wang, X.; Ru, Y.; Qiao, J. L. Ultrastrong graphene-based fibers with increased elongation. Nano Lett. 2016, 16(10), 6511-6515. doi: 10.1021/acs.nanolett.6b03108
47. [47]
  Zhao, Y.; Jiang, C. C.; Hu, C. G.; Dong, Z. L.; Xue, J. L.; Meng, Y. N.; Zheng, N.; Chen, P. W.; Qu, L. T. Large-scale spinning assembly of neat, morphology-defined, graphene-based hollow fibers. ACS Nano 2013, 7(3), 2406-2412. doi: 10.1021/nn305674a
48. [48]
  Xu, Y. X.; Sheng, K. X.; Li, C.; Shi, G. Q. Self-assembled graphene hydrogel via a onestep hydrothermal process. ACS Nano 2010, 4(7), 4324-4330. doi: 10.1021/nn101187z
49. [49]
  Dong, Z. L.; Jiang, C. C.; Cheng, H. H.; Zhao, Y.; Shi, G. Q.; Jiang, L.; Qu, L. T. Facile fabrication of light, flexible and multifunctional graphene fibers. Adv. Mater. 2012, 24(14), 1856-1861. doi: 10.1002/adma.v24.14
50. [50]
  Wu, G.; Tan, P. F.; Wu, X. J.; Peng, L.; Cheng, H. Y.; Wang, C. F.; Chen, W.; Yu, Z. Y.; Chen, S. High-performance wearable micro-supercapacitors based on microfluidic-directed nitrogen-doped graphene fiber electrodes. Adv. Funct. Mater. 2017, 27(36), 1702493. doi: 10.1002/adfm.v27.36
51. [51]
  Hu, C. G.; Zhao, Y.; Cheng, H. H.; Wang, Y. H.; Dong, Z. L.; Jiang, C. C.; Zhai, X. Q.; Jiang, L.; Qu, L. T. Graphene microtubings: controlled fabrication and site-specific functionalization. Nano Lett. 2012, 12(11), 5879-5884. doi: 10.1021/nl303243h
52. [52]
  Ma, T.; Gao, H. L.; Cong, H. P.; Yao, H. B.; Wu, L.; Yu, Z. Y.; Chen, S. M.; Yu, S. H. A Bioinspired interface design for improving the strength and electrical conductivity of graphene-based fibers. Adv. Mater. 2018, 30(15), 1706435. doi: 10.1002/adma.v30.15
53. [53]
  Li, X. M.; Zhao, T. S.; Wang, K. L.; Yang, Y.; Wei, J. Q.; Kang, F. Y.; Wu, D. H.; Zhu, H. W. Directly drawing self-assembled, porous, and monolithic graphene fiber from chemical vapor deposition grown graphene film and its electrochemical properties. Langmuir 2011, 27(19), 12164-12171. doi: 10.1021/la202380g
54. [54]
  Li, X.; Sun, P. Z.; Fan, L. L.; Zhu, M.; Wang, K. L.; Zhong, M. L.; Wei, J. Q.; Wu, D. H.; Cheng, Y.; Zhu, H. W. Multifunctional graphene woven fabrics. Sci. Rep. 2012, 2, 395. doi: 10.1038/srep00395
55. [55]
  Chen, T.; Dai, L. M. Macroscopic graphene fibers directly assembled from CVD-grown fiber-shaped hollow graphene tubes. Angew. Chem. Int. Ed. 2015, 54(49), 14947-14950. doi: 10.1002/anie.201507246
56. [56]
  Hu, C. G.; Zhai, X. Q.; Liu, L. L.; Zhao, Y.; Jiang, L.; Qu, L. T. Spontaneous reduction and assembly of graphene oxide into three-dimensional graphene network on arbitrary conductive substrates. Sci. Rep. 2013, 3, 2065. doi: 10.1038/srep02065
57. [57]
  Jang, E. Y.; Carretero-Gonzalez, J.; Choi, A.; Kim, W. J.; Kozlov, M. E.; Kim, T.; Kang, T. J.; Baek, S. J.; Kim, D. W.; Park, Y. W.; Baughman, R. H.; Kim, Y. H. Fibers of reduced graphene oxide nanoribbons. Nanotechnology 2012, 23(23), 235601. doi: 10.1088/0957-4484/23/23/235601
58. [58]
  Zhao, F.; Zhao, Y.; Cheng, H. H.; Qu, L. T. A Graphene fibriform responsor for sensing heat, humidity, and mechanical changes. Angew. Chem. Int. Ed. 2015, 54(49), 14951-14955. doi: 10.1002/anie.201508300
59. [59]
  Ding, X. T.; Bai, J.; Xu, T.; Li, C. X.; Zhang, H. M.; Qu, L. T. A novel nitrogen-doped graphene fiber microelectrode with ultrahigh sensitivity for the detection of dopamine. Electrochem. Commun. 2016, 72, 122-125. doi: 10.1016/j.elecom.2016.09.021
60. [60]
  Zhou, G. M.; Li, F.; Cheng, H. M. Progress in flexible lithium batteries and future prospects. Energy Environ. Sci. 2014, 7(4), 1307−1338. doi: 10.1039/C3EE43182G
61. [61]
  Chen, B.; Liu, E. Z.; Cao, T. T.; He, F.; Shi, C. S.; He, C. N.; Ma, L. Y.; Li, Q. Y.; Li, J. J.; Zhao, N. Q. Controllable graphene incorporation and defect engineering in MoS₂-TiO₂ based composites: Towards high-performance lithium-ion batteries anode materials. Nano Energy 2017, 3, 247−256.
62. [62]
  Lee, J. G.; Kwon, Y. B.; Ju, J. Y.; Choi, S. H.; Kang, Y. K.; Yu, W. R.; Kim, D. W. Fiber electrode by one-pot wet-spinning of graphene and manganese oxide nanowires for wearable lithium-ion batteries. J. Appl. Electrochem. 2017, 47(8), 865−875. doi: 10.1007/s10800-017-1085-y
63. [63]
  Wang, B.; Ryu, J. G.; Choi, S. H.; Song, G. J.; Hong, D. K.; Hwang, C. Y.; Chen, X.; Wang, B.; Li, W.; Song, H. K.; Park, S. J.; Ruoff, R. S. Folding graphene film yields high areal energy storage in lithium-ion batteries. ACS Nano, 2018, 12(2), 1736−1746.
64. [64]
  Hoshide, T.; Zheng, Y. C.; Hou, J. Y.; Wang, Z. Q.; Li, Q. W.; Zhao, Z. G.; Ma, R. Z.; Sasaki, T.; Geng, F. X. Flexible lithium-ion fiber battery by the regular stacking of two-dimensional titanium oxide nanosheets hybridized with reduced graphene oxide. Nano Lett. 2017, 17(6), 3543−3549. doi: 10.1021/acs.nanolett.7b00623
65. [65]
  Rao, J. Y.; Liu, N. S.; Zhang, Z.; Su, J.; Li, L. Y.; Xiong, L.; Gao, Y. H. All-fiber-based quasi-solid-state lithium-ion battery towards wearable electronic devices with outstanding flexibility and self-healing ability. Nano Energy 2018, 51, 425−433. doi: 10.1016/j.nanoen.2018.06.067
66. [66]
  Pech, D.; Brunet, M.; Durou, H.; Huang, P. H.; Mochalin, V.; Gogotsi, Y.; Taberna, P. L.; Simon, P. Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon. Nat. Nanotechnol. 2010, 5(9), 651-654. doi: 10.1038/nnano.2010.162
67. [67]
  Beidaghi, M.; Wang, C. L. Micro-supercapacitors based on interdigital electrodes of reduced graphene oxide and carbon nanotube composites with ultrahigh power handling performance. Adv. Funct. Mater, 2012, 22(21), 4501-4510. doi: 10.1002/adfm.v22.21
68. [68]
  Chen, J.; Li, C.; Shi, G. Q. Graphene materials for electrochemical capacitors. J. Phys. Chem. Lett. 2013, 4(8), 1244-1253. doi: 10.1021/jz400160k
69. [69]
  Huang, L.; Li, C.; Shi, G. Q. High-performance and flexible electrochemical capacitors based on graphene/polymer composite films. J. Mater. Chem. A 2014, 2(4), 968-974. doi: 10.1039/C3TA14511E
70. [70]
  Hu, Y.; Cheng, H. H.; Zhao, F.; Chen, N.; Jiang, L.; Feng, Z. H.; Qu, L. T. All-in-one graphene fiber supercapacitors. Nanoscale 2014, 6(12), 6448-6451. doi: 10.1039/c4nr01220h
71. [71]
  Zhao, Y.; Han, Q.; Cheng, Z. H.; Jiang, L.; Qu, L. T. Integratedgraphene systems by laser irradiation for advanced deviced. Nano Today 2017, 12, 14-30. doi: 10.1016/j.nantod.2016.12.010
72. [72]
  Liang, Y.; Wang, Z.; Huang, J.; Cheng, H. H.; Zhao, F.; Hu, Y.; Jiang, L.; Qu, L. T. Series of in-fiber graphene supercapacitors for flexible wearable devices. J. Mater. Chem. A 2015, 3(6), 2547-2551. doi: 10.1039/C4TA06574C
73. [73]
  Li, Z.; Huang, T.; Gao, W.; Xu, Z.; Chang, D.; Zhang, C.; Gao, C. Hydrothermally activated graphene fiber fabrics for textile electrodes of supercapacitors. ACS Nano 2017, 11(11), 11056−11065. doi: 10.1021/acsnano.7b05092
74. [74]
  Cheng, H. H.; Liu, J.; Zhao, Y.; Hu, C. G.; Zhang, Z. P.; Chen, N.; Jiang, L.; Qu, L. T. Graphene fibers with predetermined deformation as moisture-triggered actuators and robots. Angew. Chem. Int. Ed. 2013, 52(40), 10482-10486. doi: 10.1002/anie.201304358
75. [75]
  Cheng, H. H.; Hu, Y.; Zhao, F.; Dong, Z. L.; Wang, Y. H.; Chen, N.; Zhang, Z. P.; Qu, L. T. Moisture-activated torsional graphene-fiber motor. Adv. Mater. 2014, 26(18), 2909-2913. doi: 10.1002/adma.v26.18
76. [76]
  Conley, H.; Lavrik, N. V.; Prasai, D.; Bolotin, K. I. Graphene bimetallic-like cantilevers: probing graphene/substrate interactions. Nano Lett. 2011, 11(11), 4748-4752. doi: 10.1021/nl202562u
77. [77]
  Wang, Y. H.; Bian, K.; Hu, C. G.; Zhang, Z. P.; Chen, N.; Zhang, H. M.; Qu, L. T. Flexible and wearable graphene/polypyrrole fibers towards multifunctional actuator applications. Electrochem. Commun. 2013, 35, 49-52. doi: 10.1016/j.elecom.2013.07.044
78. [78]
  Xie, X. J.; Qu, L. T.; Zhou, C.; Li, Y.; Bai, H.; Shi, G. Q.; Dai, L. M. An Asymmetrically surface-modified graphene film electrochemical actuator. ACS Nano 2010, 4(10), 6050-6054. doi: 10.1021/nn101563x
79. [79]
  Liang, J. J.; Huang, Y.; Oh, J. Y.; Kozlov, M.; Sui, D.; Fang, S. L.; Baughman, R. H.; Ma, Y. F.; Chen, Y. S. Electromechanical actuators based on graphene and graphene/Fe₃O₄ hybrid paper. Adv. Funct. Mater. 2011, 21(19), 3778-3784. doi: 10.1002/adfm.201101072
80. [80]
  Liu, J.; Wang, Z.; Xie, X. J.; Cheng, H. H.; Zhao, Y.; Qu, L. T. A rationally-designed synergetic polypyrrole/graphene bilayer actuator. J. Mater. Chem. 2012, 22(9), 4015-4020. doi: 10.1039/c2jm15266e
81. [81]
  Huang, Y.; Liang, J. J.; Chen, Y. S. The application of graphene based materials for actuators. J. Mater. Chem. 2012, 22(9), 3671-3679. doi: 10.1039/c2jm15536b
82. [82]
  Zhu, C. H.; Lu, Y.; Peng, J.; Chen, J. F.; Yu, S. H. Photothermally sensitive poly(N-isopropylacrylamide)/graphene oxide nanocomposite hydrogels as remote lightcontrolled liquid microvalves. Adv. Funct. Mater. 2012, 22(19), 4017-4022. doi: 10.1002/adfm.v22.19
83. [83]
  Wu, C. Z.; Feng, J.; Peng, L. L.; Ni, Y.; Liang, H. Y.; He, L. H.; Xie, Y. Large-area graphene realizing ultrasensitive photothermal actuator with high transparency: new prototype robotic motions under infrared-light stimuli. J. Mater. Chem. 2011, 21(46), 18584-18591. doi: 10.1039/c1jm13311j
84. [84]
  Zhang, J.; Zhao, F.; Zhang, Z. P.; Chen, N.; Qu, L. T. Dimension-tailored functional graphene structures for energy conversion and storage. Nanoscale 2013, 5(8), 3112-3126. doi: 10.1039/c3nr00011g
85. [85]
  Lu, L. H.; Liu, J. H.; Hu, Y.; Zhang, Y. W.; Chen, W. Graphene-stabilized silver nanoparticle electrochemical electrode for actuator design. Adv. Mater. 2013, 25(9), 1270-1274. doi: 10.1002/adma.v25.9
86. [86]
  Liang, J. J.; Huang, L.; Li, N.; Huang, Y.; Wu, Y. P.; Fang, S. L.; Oh, J. Y.; Kozlov, M.; Ma, Y. F.; Li, F. F.; Baughman, R.; Chen, Y. S. Electromechanical actuator with controllable motion, fast response rate, and high-frequency resonance based on graphene and polydiacetylene. ACS Nano 2012, 6(5), 4508-4509. doi: 10.1021/nn3006812
87. [87]
  Cheng, H. H.; Huang, Y. X.; Shi, G. Q.; Jiang, L.; Qu, L. T. Graphene-based functional architectures: sheets regulation and macrostructure construction toward actuators and power generators. Acc. Chem. Res. 2017, 50(7), 1663−1671. doi: 10.1021/acs.accounts.7b00131
88. [88]
  Liang, Y.; Zhao, F.; Cheng, Z. H.; Zhou, Q. H.; Shao, H. B.; Jiang, L.; Qu, L. T. Self-powered wearable graphene fiber for information expression. Nano Energy 2017, 32, 329-335. doi: 10.1016/j.nanoen.2016.12.062
89. [89]
  Yang, Z. B.; Sun, H.; Chen, T.; Qiu, L. B.; Luo, Y. F.; Peng, H. S. Photovoltaic wire derived from a graphene composite fiber achieving an 8.45% energy conversion efficiency. Angew. Chem. Int. Ed. 2013, 52(29), 7545-7548.
90. [90]
  Zou, Y. H.; Yang, X. F.; Lv, C. X.; Liu, T. C.; Xia, Y. Z.; Shang, L.; Waterhouse, G. I. N.; Yang, D. J.; Zhang, T. R. Multishelled Ni-rich Li(Ni_xCo_yMn_z)O₂ hollow fibers with low cation mixing as high-performance cathode materials for Li-ion batteries. Adv. Sci. 2017, 4(1), 1600262. doi: 10.1002/advs.201600262
91. [91]
  Xu, J.; Chen, Z. Y.; Zhang, H. W.; Lin, G. B.; Wang, X. X.; Long, J. L. Cd₃(C₃N₃S₃)₂ coordination polymer/graphene nanoarchitectures for enhanced photocatalytic H₂O₂ production under visible light. Sci. Bull. 2017, 62(9), 610-618. doi: 10.1016/j.scib.2017.04.013
92. [92]
  Shang, L.; Bian, T.; Zhang, B. H.; Zhang, D. H.; Wu, L. Z.; Tung, C. H.; Yin, Y. D.; Zhang, T. R. Graphene-supported ultrafine metal nanoparticles encapsulated by mesoporous silica: robust catalysts for oxidation and reduction reactions. Angew. Chem. Int. Ed. 2014, 53, 250-254. doi: 10.1002/anie.v53.1
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沈阳化工大学材料科学与工程学院沈阳 110142