Citation: Bin Chen, Feng Wang, Jing-Yu Li, Jia-Lu Zhang, Yan Zhang, Hai-Chao Zhao. Synthesis of Eugenol Bio-based Reactive Epoxy Diluent and Study on the Curing Kinetics and Properties of the Epoxy Resin System[J]. Chinese Journal of Polymer Science, ;2019, 37(5): 500-508. doi: 10.1007/s10118-019-2210-7 shu

Synthesis of Eugenol Bio-based Reactive Epoxy Diluent and Study on the Curing Kinetics and Properties of the Epoxy Resin System

Bin Chen ^1,, ,
Feng Wang ^1,2 ,
Jing-Yu Li ^1,2 ,
Jia-Lu Zhang ^1,2 ,
Yan Zhang ^1,2 ,
Hai-Chao Zhao ^2,,

a.
School of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China
b.
Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

Corresponding author: Bin Chen, Hai-Chao Zhao, zhaohaichao@nimte.ac.cn
Received Date: 6 September 2018
Revised Date: 8 December 2018
Accepted Date: 1 January 2018
Available Online: 11 January 2019

In this study, monoglycidyl silyl etherated eugenol (GSE) was synthesized as reactive epoxy diluent, and the chemical structure of GSE, intermediates, and products were characterized by Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (¹H-NMR). GSE existed as a potential bio-based reactive diluent for petroleum-based epoxy resin. The curing kinetics of EP/HHPA/GSE system was studied by non-isothermal DSC method. The kinetics parameters were calculated by using the Kissinger model, Crane model, Ozawa model, and β-T (temperature-heating rate) extrapolation, respectively. In addition, the effects of GSE on the thermo-mechanical properties and thermal stability of EP/HHPA/GSE systems were studied, indicating that GSE can effectively improve the toughness and thermal decomposition temperature of the epoxy system.
- Bio-based epoxy,
- Reactive diluent,
- Eugenol,
- Curing kinetics
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