Citation: Di Xu, Xiang-Xiang Zhao, Zhong-Tao Chen, Yu-Guo Ma. Synergistic Effect and Fluorination Effect in Ethylene Polymerization by Nickel Phenoxyiminato Catalysts[J]. Chinese Journal of Polymer Science, ;2018, 36(2): 244-251. doi: 10.1007/s10118-018-2081-3 shu

Synergistic Effect and Fluorination Effect in Ethylene Polymerization by Nickel Phenoxyiminato Catalysts

Beijing National Laboratory for Molecular Sciences(BNLMS), Center for Soft Matter Science and Engineering, Key Lab of Polymer Chemistry & Physics of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China

Corresponding author: Yu-Guo Ma, ygma@pku.edu.cn
Received Date: 30 September 2017
Accepted Date: 30 October 2017
Available Online: 24 November 2017

A series of binuclear nickel phenoxyiminato catalysts with different linkers and fluorine substituents were efficiently synthesized. Binuclear nickel catalysts with rigid linkers showed higher catalytic activity and thermal stability in ethylene polymerization and produced polymers with higher molecular weight possibly due to the larger steric hindrance and metal-metal synergistic effect. The introduction of fluorine atoms on the N-terphenyl moity also enhanced polymerization activity and molecular weight of polymer due to the electronic effect of fluorine atoms.
- Nickel phenoxyiminato catalysts,
- Fluorination effect,
- Synergistic effect,
- Bimetallic catalysts
1. [1]
  Younkin T. R., Connor E. F., Henderson J. I., Friedrich S. K., Grubbs R. H., Bansleben D. A.. Neutral, single-component nickel(Ⅱ) polyolefin catalysts that tolerate heteroatoms[J]. Science, 2000,287(5452):460-462. doi: 10.1126/science.287.5452.460
2. [2]
  Ittel S. D., Johnson L. K., Brookhart M.. Late-metal catalysts for ethylene homo-and copolymerization[J]. Chem. Rev., 2000,100(4):1169-1204. doi: 10.1021/cr9804644
3. [3]
  Nakamura A., Ito S., Nozaki K.. Coordination-insertion copolymerization of fundamental polar monomers[J]. Chem. Rev., 2009,109(11):5215-5244. doi: 10.1021/cr900079r
4. [4]
  Nakamura A., Anselment T. M. J., Claverie J., Goodall B., Jordan R. F., Mecking S., Rieger B., Sen A., van Leeuwen P. W. N. M., Nozaki K.. Ortho-phosphinobenzenesulfonate:a superb ligand for palladium-catalyzed coordination-insertion copolymerization of polar vinyl monomers[J]. Acc. Chem. Res., 2013,46(7):1438-1449. doi: 10.1021/ar300256h
5. [5]
  Johnson L. K., Mecking S., Brookhart M.. Copolymerization of ethylene and propylene with functionalized vinyl monomers by palladium(Ⅱ) catalysts[J]. J. Am. Chem. Soc., 1996,118(1):267-268. doi: 10.1021/ja953247i
6. [6]
  Mu H., Pan L., Song D., Li Y.. Neutral nickel catalysts for olefin homo-and copolymerization:Relationships between catalyst structures and catalytic properties[J]. Chem. Rev., 2015,115(22):12091-12137. doi: 10.1021/cr500370f
7. [7]
  Guo L., Dai S., Sui X., Chen C.. Palladium and nickel catalyzed chain walking olefin polymerization and copolymerization[J]. ACS Catal., 2016,6(1):428-441. doi: 10.1021/acscatal.5b02426
8. [8]
  Vaidya T., Klimovica K., LaPointe A. M., Keresztes I., Lobkovsky E. B., Daugulis O., Coates G. W.. Secondary alkene insertion and precision chain-walking:a new route to semicrystalline "polyethylene" from α-olefins by combining two rare catalytic events[J]. J. Am. Chem. Soc., 2014,136(20):7213-7216. doi: 10.1021/ja502130w
9. [9]
  Cherian A. E., Rose J. M., Lobkovsky E. B., Coates G.W.. A C2-symmetric, living α-diimine Ni(Ⅱ) catalyst:regioblock copolymers from propylene[J]. J. Am. Chem. Soc., 2005,127(40):13770-13771. doi: 10.1021/ja0540021
10. [10]
  McCord E. F., McLain S. J., Nelson L. T. J., Ittel S. D., Tempel D., Killian C. M., Johnson L. K., Brookhart M.. ¹³C-NMR analysis of α-olefin enchainment in poly(α-olefins) produced with nickel and palladium α-diimine catalysts[J]. Macromolecules, 2007,40(3):410-420. doi: 10.1021/ma061547m
11. [11]
  Guo L., Chen C.. (α-diimine)palladium catalyzed ethylene polymerization and (co)polymerization with polar comonomers[J]. Sci. China Chem., 2015,58(11):1663-1673. doi: 10.1007/s11426-015-5433-7
12. [12]
  Guan Z., Cotts P. M., McCord E. F., McLain S. J.. Chain walking:a new strategy to control polymer topology[J]. Science, 1999,283(5410):2059-2062. doi: 10.1126/science.283.5410.2059
13. [13]
  Zuideveld M. A., Wehrmann P., Röhr C., Mecking S.. Remote substituents controlling catalytic polymerization by very active and robust neutral nickel(Ⅱ) complexes[J]. Angew. Chem. Int. Ed., 2004,43(7):869-873. doi: 10.1002/(ISSN)1521-3773
14. [14]
  Mu H. L., Ye W. P., Song D. P., Li Y. S.. Highly active single-component neutral nickel ethylene polymerization catalysts:The influence of electronic effects and spectator ligands[J]. Organometallics, 2010,29(23):6282-6290. doi: 10.1021/om100658j
15. [15]
  Hu X., Dai S., Chen C.. Ethylene polymerization by salicylaldimine nickel(Ⅱ) complexes containing a dibenzhydryl moiety[J]. Dalton Trans., 2016,45(4):1496-1503. doi: 10.1039/C5DT04408A
16. [16]
  Rhinehart J. L., Brown L. A., Long B. K.. A robust Ni(Ⅱ) α-diimine catalyst for high temperature ethylene polymerization[J]. J. Am. Chem. Soc., 2013,135(44):16316-16319. doi: 10.1021/ja408905t
17. [17]
  Dai S., Zhou S., Zhang W., Chen C.. Systematic investigations of ligand steric effects on α-diimine palladium catalyzed olefin polymerization and copolymerization[J]. Macromolecules, 2016,49(23):8855-8862. doi: 10.1021/acs.macromol.6b02104
18. [18]
  Dai S., Chen C.. Direct synthesis of functionalized high-molecular-weight polyethylene by copolymerization of ethylene with polar monomers[J]. Angew. Chem. Int. Ed., 2016,55(42):13281-13285. doi: 10.1002/anie.201607152
19. [19]
  Kenyon P., Mecking S.. Pentafluorosulfanyl substituents in polymerization catalysis[J]. J. Am. Chem. Soc., 2017,139(39):13786-13790. doi: 10.1021/jacs.7b06745
20. [20]
  Chen M., Chen C.. Rational design of high-performance phosphine sulfonate nickel catalysts for ethylene polymerization and copolymerization with polar monomers[J]. ACS Catal., 2017,7(2):1308-1312. doi: 10.1021/acscatal.6b03394
21. [21]
  Dai S., Sui X., Chen C.. Highly robust palladium(Ⅱ) α-diimine catalysts for slow-chain-walking polymerization of ethylene and copolymerization with methyl acrylate[J]. Angew. Chem. Int. Ed., 2015,54(34):9948-9953. doi: 10.1002/anie.201503708
22. [22]
  Weberski M. P., Chen C., Delferro M., Zuccaccia C., Macchioni A., Marks T. J.. Suppression of β-hydride chain transfer in nickel(Ⅱ)-catalyzed ethylene polymerization via weak fluorocarbon ligand-product interactions[J]. Organometallics, 2012,31(9):3773-3789. doi: 10.1021/om3002735
23. [23]
  Popeney C. S., Rheingold A. L., Guan Z.. Nickel(Ⅱ) and palladium(Ⅱ) polymerization catalysts bearing a fluorinated cyclophane ligand:stabilization of the reactive intermediate[J]. Organometallics, 2009,28(15):4452-4463. doi: 10.1021/om900302r
24. [24]
  Wang J., Yao E., Chen Z., Ma Y.. Fluorinated nickel(Ⅱ) phenoxyiminato catalysts:exploring the role of fluorine atoms in controlling polyethylene productivities and microstructures[J]. Macromolecules, 2015,48(16):5504-5510. doi: 10.1021/acs.macromol.5b01090
25. [25]
  Chen M., Yang B., Chen C.. Redox-controlled olefin (co)polymerization catalyzed by ferrocene-bridged phosphine-sulfonate palladium complexes[J]. Angew. Chem. Int. Ed., 2015,54(51):15520-15524. doi: 10.1002/anie.201507274
26. [26]
  Zhao M., Chen C.. Accessing multiple catalytically active states in redox-controlled olefin polymerization[J]. ACS Catal., 2017,7(11):7490-7494. doi: 10.1021/acscatal.7b02564
27. [27]
  Li M., Wang X., Luo Y., Chen C.. A second-coordination-sphere strategy to modulate nickel-and palladium-catalyzed olefin polymerization and copolymerization[J]. Angew. Chem. Int. Ed., 2017,56(38):11604-11609. doi: 10.1002/anie.v56.38
28. [28]
  Zhang D., Chen C.. Influence of polyethylene glycol unit on palladium-and nickel-catalyzed ethylene polymerization and copolymerization[J]. Angew. Chem. Int. Ed., 2017. doi: 10.1002/anie.201708212
29. [29]
  Stephenson C. J., McInnis J. P., Chen C., Weberski M. P., Motta A., Delferro M., Marks T. J.. Ni(Ⅱ) phenoxyiminato olefin polymerization catalysis:Striking coordinative modulation of hyperbranched polymer microstructure and stability by a proximate sulfonyl group[J]. ACS Catal., 2014,4(3):999-1003. doi: 10.1021/cs500114b
30. [30]
  Xin B. S., Sato N., Tanna A., Oishi Y., Konishi Y., Shimizu F.. Nickel catalyzed copolymerization of ethylene and alkyl acrylates[J]. J. Am. Chem. Soc., 2017,139(10):3611-3614. doi: 10.1021/jacs.6b13051
31. [31]
  McInnis J. P., Delferro M., Marks T. J.. Multinuclear group 4 catalysis:Olefin polymerization pathways modified by strong metal-metal cooperative effects[J]. Acc. Chem. Res., 2014,47(8):2545-2557. doi: 10.1021/ar5001633
32. [32]
  Chen Z., Yao E., Wang J., Gong X., Ma Y.. Ethylene (co)polymerization by binuclear nickel phenoxyiminato catalysts with cofacial orientation[J]. Macromolecules, 2016,49(23):8848-8854. doi: 10.1021/acs.macromol.6b02078
33. [33]
  Johnson L. K., Killian C. M., Brookhart M.. New Pd(Ⅱ)-and Ni(Ⅱ)-based catalysts for polymerization of ethylene and α-olefins[J]. J. Am. Chem. Soc., 1995,117(23):6414-6415. doi: 10.1021/ja00128a054
34. [34]
  Popeney C., Guan Z.. Ligand electronic effects on late transition metal polymerization catalysts[J]. Organometallics, 2005,24(6):1145-1155. doi: 10.1021/om048988j
35. [35]
  Popeney C. S., Guan Z.. Effect of ligand electronics on the stability and chain transfer rates of substituted Pd(Ⅱ) α-diimine catalysts[J]. Macromolecules, 2010,43(9):4091-4097. doi: 10.1021/ma100220n
36. [36]
  Osichow A., Göttker-Schnetmann I., Mecking S.. Role of electron-withdrawing remote substituents in neutral nickel(Ⅱ) polymerization catalysts[J]. Organometallics, 2013,32(18):5239-5242. doi: 10.1021/om400757f
37. [37]
  Göttker-Schnetmann I., Wehrmann P., Röhr C., Mecking S.. Substituent effects in (κ2-N, O)-salicylaldiminato nickel(Ⅱ)-methyl pyridine polymerization catalysts:terphenyls controlling polyethylene microstructures[J]. Organometallics, 2007,26(9):2348-2362. doi: 10.1021/om0611498
38. [38]
  Bastero A., Göttker-Schnetmann I., Röhr C., Mecking S.. Polymer microstructure control in catalytic polymerization exclusively by electronic effects of remote substituents[J]. Adv. Synth. Catal., 2007,349(14-15):2307-2316. doi: 10.1002/(ISSN)1615-4169
39. [39]
  Saito J., Mitani M., Mohri J., Yoshida Y., Matsui S., Ishii S., Kojoh S., Kashiwa N., Fujita T.. Living polymerization of ethylene with a titanium complex containing two phenoxy-imine chelate ligands[J]. Angew. Chem. Int. Ed., 2001,40(15):2918-2920. doi: 10.1002/(ISSN)1521-3773
40. [40]
  Mitani M., Mohri J.-i., Yoshida Y., Saito J., Ishii S., Tsuru K., Matsui S., Furuyama R., Nakano T., Tanaka H., Kojoh S.-i., Matsugi T., Kashiwa N., Fujita T.. Living polymerization of ethylene catalyzed by titanium complexes having fluorine-containing phenoxy-imine chelate ligands[J]. J. Am. Chem. Soc., 2002,124(13):3327-3336. doi: 10.1021/ja0117581
41. [41]
  Mitani M., Furuyama R., Mohri J.-i., Saito J., Ishii S., Terao H., Nakano T., Tanaka H., Fujita T.. Syndiospecific living propylene polymerization catalyzed by titanium complexes having fluorine-containing phenoxy-imine chelate ligands[J]. J. Am. Chem. Soc., 2003,125(14):4293-4305. doi: 10.1021/ja029560j
42. [42]
  Ishii S.-i., Saito J., Mitani M., Mohri J.-i., Matsukawa N., Tohi Y., Matsui S., Kashiwa N., Fujita T.. Highly active ethylene polymerization catalysts based on titanium complexes having two phenoxy-imine chelate ligands[J]. J. Mol. Catal. A:Chem., 2002,179(1):11-16.
43. [43]
  Tian J., Hustad P. D., Coates G. W.. A new catalyst for highly syndiospecific living olefin polymerization:homopolymers and block copolymers from ethylene and propylene[J]. J. Am. Chem. Soc., 2001,123(21):5134-5135. doi: 10.1021/ja0157189
44. [44]
  Makio H., Fujita T.. Development and application of FI catalysts for olefin polymerization:unique catalysis and distinctive polymer formation[J]. Acc. Chem. Res., 2009,42(10):1532-1544. doi: 10.1021/ar900030a
45. [45]
  Delferro M., Marks T. J.. Multinuclear olefin polymerization catalysts[J]. Chem. Rev., 2011,111(3):2450-2485. doi: 10.1021/cr1003634
46. [46]
  Motta A., Fragalà I. L., Marks T. J.. Proximity and cooperativity effects in binuclear d0 olefin polymerization catalysis. Theoretical analysis of structure and reaction mechanism[J]. J. Am. Chem. Soc., 2009,131(11):3974-3984.
47. [47]
  Sujith S., Joe D. J., Na S. J., Park Y. W., Choi C. H., Lee B. Y.. Ethylene/polar norbornene copolymerizations by bimetallic salicylaldimine-nickel catalysts[J]. Macromolecules, 2005,38(24):10027-10033. doi: 10.1021/ma051344i
48. [48]
  Chen Q., Yu J., Huang J.. Arene-bridged salicylaldimine-based binuclear neutral nickel(Ⅱ) complexes:Synthesis and ethylene polymerization activities[J]. Organometallics, 2007,26(3):617-625. doi: 10.1021/om060778e
49. [49]
  Radlauer M. R., Buckley A. K., Henling L. M., Agapie T.. Bimetallic coordination insertion polymerization of unprotected polar monomers:copolymerization of amino olefins and ethylene by dinickel bisphenoxyiminato catalysts[J]. J. Am. Chem. Soc., 2013,135(10):3784-3787. doi: 10.1021/ja4004816
50. [50]
  Wang J., Li H., Guo N., Li L., Stern C. L., Marks T. J.. Covalently linked heterobimetallic catalysts for olefin polymerization[J]. Organometallics, 2004,23(22):5112-5114. doi: 10.1021/om049481b
51. [51]
  Kuwabara J., Takeuchi D., Osakada K.. Zr/Zr and Zr/Fe dinuclear complexes with flexible bridging ligands. Preparation by olefin metathesis reaction of the mononuclear precursors and properties as polymerization catalysts[J]. Organometallics, 2005,24(11):2705-2712.
52. [52]
  Cano Sierra J., Hüerländer D., Hill M., Kehr G., Erker G., Fröhlich R.. Formation of dinuclear titanium and zirconium complexes by olefin metathesis-catalytic preparation of organometallic catalyst systems[J]. Chem. Eur. J., 2003,9(15):3618-3622. doi: 10.1002/chem.200304789
53. [53]
  Chen Z., Zhao X., Gong X., Xu D., Ma Y.. Macrocyclic trinuclear nickel phenoxyimine catalysts for high-temperature polymerization of ethylene and isospecific polymerization of propylene[J]. Macromolecules, 2017,50(17):6561-6568. doi: 10.1021/acs.macromol.7b00996
54. [54]
  Wehrmann P., Mecking S.. Highly active binuclear neutral nickel(Ⅱ) catalysts affording high molecular weight polyethylene[J]. Organometallics, 2008,27(7):1399-1408. doi: 10.1021/om700942z
55. [55]
  Takeuchi D., Chiba Y., Takano S., Osakada K.. Double-decker-type dinuclear nickel catalyst for olefin polymerization:efficient incorporation of functional co-monomers[J]. Angew. Chem. Int. Ed., 2013,52(48):12536-12540. doi: 10.1002/anie.201307741
56. [56]
  Wang C., Friedrich S., Younkin T. R., Li R. T., Grubbs R. H., Bansleben D. A., Day M. W.. Neutral nickel(Ⅱ)-based catalysts for ethylene polymerization[J]. Organometallics, 1998,17(15):3149-3151. doi: 10.1021/om980176y
57. [57]
  Connor E. F., Younkin T. R., Henderson J. I., Waltman A. W., Grubbs R. H.. Synthesis of neutral nickel catalysts for ethylene polymerization-the influence of ligand size on catalyst stability[J]. Chem. Commun., 2003,18:2272-2273.
58. [58]
  Delferro M., McInnis J. P., Marks T. J.. Ethylene polymerization characteristics of an electron-deficient nickel(Ⅱ) phenoxyiminato catalyst modulated by non-innocent intramolecular hydrogen bonding[J]. Organometallics, 2010,29(21):5040-5049. doi: 10.1021/om100251j
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