Citation: Zhe-Wei Zhang, Jun-Tao Li, Wan-Yuan Wei, Jie Wei, Jin-Bao Guo. A Luminescent Dicyanodistyrylbenzene-based Liquid Crystal Polymer Network for Photochemically Patterned Photonic Composite Film[J]. Chinese Journal of Polymer Science, ;2018, 36(6): 776-782. doi: 10.1007/s10118-018-2072-4 shu

A Luminescent Dicyanodistyrylbenzene-based Liquid Crystal Polymer Network for Photochemically Patterned Photonic Composite Film

Key Laboratory of Carbon Fibers and Functional Polymers, Ministry of Education; Beijing Engineering Research Center for the Synthesis and Applications of Waterborne Polymers and College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Jin-Bao Guo, guojb@mail.buct.edu.cn
Received Date: 28 September 2017
Accepted Date: 21 October 2017
Available Online: 8 February 2018

A novel photonic composite film based on a luminescent dicyanodistyrylbenzene-based liquid crystal polymer network (LCN) was fabricated by using a silica colloidal crystal as a template. The upper part of inverse opal structure and the luminescence characteristics of dicyanodistyrylbenzene-based moiety endowed the resulting bilayer photonic film with structural color arising from coherent Bragg reflection and fluorescence properties, respectively. A fluorescence enhancement phenomenon was observed in the photonic film due to the overlap between the reflection band and emission band of the fluorescent LCN. More importantly, the photo-induced irreversible Z/E photoisomerization of dicyanodistyrylbenzene-based moiety in the photonic film led to both a reflection spectral shift and an observable fluorescence variation. On the basis of this effective phototuning process, microscopic patterning of photonic film was developed under both fluorescence mode and reflection mode. The work demonstrated here provides a new route to construct photo-responsive photonic film.
- Luminescent liquid crystal,
- Polymer networks,
- Photonic composite,
- Photopatterning
1. [1]
  Kuang M. X., Wang J. X., Jiang L.. Bio-inspired photonic crystals with superwettability[J]. Chem. Soc. Rev, ,45(24):6833-6854. doi: 10.1039/C6CS00562D
2. [2]
  Xu H., Wu P., Zhu C., Elbaz A., Gu Z. Z.. Photonic crystal for gas sensing[J]. J. Mater. Chem. C, 2013,1(38):6087-6098. doi: 10.1039/c3tc30722k
3. [3]
  Nucara L., Greco F., Mattoli V.. Electrically responsive photonic crystals:a review[J]. J. Mater. Chem. C, 2015,3(33):8449-8467. doi: 10.1039/C5TC00773A
4. [4]
  Ge J. P., Yin Y. D.. Responsive photonic crystals[J]. Angew. Chem. Int. Ed., 2011,50(7):1492-522. doi: 10.1002/anie.200907091
5. [5]
  Schaffner M., England G., Kolle M., Aizenberg J., Vogel N.. Combining bottom-up self-assembly with top-down microfabrication to create hierarchical inverse opals with high structural order[J]. Small, 2015,11(34):4334-4340. doi: 10.1002/smll.v11.34
6. [6]
  Ding T., Zhao Q. B., Smoukov S. K., Baumberg J. J.. Selectively patterning polymer opal films via microimprint lithography[J]. Adv. Optical. Mater., 2014,2(11)1098. doi: 10.1002/adom.201400327
7. [7]
  Bao B., Li M. Z., Li , Jiang Y. K., Gu Z. K., Zhang X. Y., Jiang L., Song Y. L.. Quantum dots:patterning fluorescent quantum dot nanocomposites by reactive inkjet printing[J]. Small, 2015,11(14):1649-1654. doi: 10.1002/smll.v11.14
8. [8]
  Schäfer C. G., Gallei M., Zahn J. T., Engelhardt J., Hellmann G. P., Rehahn M.. Reversible light-, thermos-and mechanoresponsive elastomeric polymer opal films[J]. Chem. Mater, 2013,25(11):2309-2318. doi: 10.1021/cm400911j
9. [9]
  Lee J. S., Je K., Kim S. H.. Designing multicolored photonic micropatterns through the regioselective thermal compression of inverse opals[J]. Adv. Funct. Mater, 2016,26(25):4587-4594. doi: 10.1002/adfm.201601095
10. [10]
  Liu J. C., Wan L., Zhang M. B., Jiang K. J., Song K., Wang J. X., Ikeda T., Jiang L.. Lithography:electrowetting-induced morphological evolution of metal-organic inverse opals toward a water-lithography approach[J]. Adv. Funct. Mater., 2017,27(7)1605221. doi: 10.1002/adfm.v27.7
11. [11]
  Tian T., Gao N., Gu C., Li J., Wang H., Lan Y., Yin X. P., Li G. T.. Chemically patterned inverse opal created by a selective photolysis modification process[J]. ACS Appl. Mater. Interfaces, 2015,7(34):19516-19525. doi: 10.1021/acsami.5b06757
12. [12]
  Ohm C., Brehmer M., Zentel R.. Liquid crystalline elastomers as actuators and sensors[J]. Adv. Mater., 2010,22(31):3366-3387. doi: 10.1002/adma.200904059
13. [13]
  White T. J., Broer D. J.. Programmable and adaptive mechanics with liquid crystal polymer networks and elastomers[J]. Nat. Mater., 2015,14(11):1087-1098. doi: 10.1038/nmat4433
14. [14]
  de Haan L. T., Schenning A. P. H. J., Broer D. J.. Programmed morphing of liquid crystal networks[J]. Polymer, 2014,55(23):5885-5896. doi: 10.1016/j.polymer.2014.08.023
15. [15]
  Wu G. L., Jiang Y., Xu D., Tang H., Liang X., Li G. T.. Thermoresponsive inverse opal films fabricated with liquid-crystal elastomers and nematic liquid crystals[J]. Langmuir, 2011,27(4):1505-1509. doi: 10.1021/la1037124
16. [16]
  Jiang Y., Xu D., Li X. S., Lin C. X., Li W. N., An Q., Tao C. A., Tang H., Li G. T.. Electrothermally driven structural colour based on liquid crystal elastomers[J]. J. Mater. Chem., 2012,22:11943-11949. doi: 10.1039/c2jm30176h
17. [17]
  Wei W. Y., Shi A. S., Wu T. H., Wei J., Guo J. B.. Thermo-responsive shape and optical memories of photonic composite films enabled by glassy liquid crystalline polymer networks[J]. Soft Matter, 2016,12(41):8534-8541. doi: 10.1039/C6SM01887D
18. [18]
  Xing H. H., Li J. T., Shi Y., Guo J. B., Wei J.. Thermally driven photonic actuator based on silica opal photonic crystal with liquid crystal elastomer[J]. ACS Appl. Mater. Interfaces, 2016,8(14):9440-9445. doi: 10.1021/acsami.6b01033
19. [19]
  Xing H. H., Li J. T., Guo J. B., Wei J.. Bio-inspired thermalresponsive inverse opal films with dual structural colors based on liquid crystal elastomer[J]. J. Mater. Chem. C, 2015,3(17):4424-4430. doi: 10.1039/C5TC00548E
20. [20]
  Zhao J. Q., Liu Y. Y., Yu Y. L.. Dual-responsive inverse opal films based on a crosslinked liquid crystal polymer containing azobenzene[J]. J. Mater. Chem. C, 2014,2(48):10262-10267. doi: 10.1039/C4TC01825G
21. [21]
  An B. K., Kwon S. K., Jung S. D., Park S. Y.. Enhanced emission and its switching in fluorescent organic nanoparticles[J]. J. Am. Chem. Soc., 2002,124(48):14410-14415. doi: 10.1021/ja0269082
22. [22]
  Lu H. B., Zhang S. N., Ding A. X., Yuan M., Zhang G. Y., Xu W., Zhang G. B., Wang X. H., Qiu L. Z., Yang J. X.. A luminescent liquid crystal with multistimuli tunable emission colors based on different molecular packing structures[J]. New J. Chem., 2014,38(8):3429-3433. doi: 10.1039/C4NJ00218K
23. [23]
  Gierschner J., Park S. Y.. Luminescent distyrylbenzenes:tailoring molecular structure and crystalline morphology[J]. J. Mater. Chem. C, 2013,1(37):5818-5832. doi: 10.1039/c3tc31062k
24. [24]
  Abadía M. M., Varghese S., Giménez R., Ros M. B.. Multiresponsive luminescent dicyanodistyrylbenzenes and their photochemistry in solution and in bulk[J]. J. Mater. Chem. C, 2016,4(14):2886-2893. doi: 10.1039/C5TC02852C
25. [25]
  Wang H., Li F., Ravia I., Gao B. R., Li Y. P., Medvedev V., Sun H. B., Tessler N., Ma Y. G.. Cyano-substituted oligo(p-phenylene vinylene) single crystals:a promising laser material[J]. Adv. Funct. Mater., 2011,21(19):3770-3777. doi: 10.1002/adfm.201100783
26. [26]
  Park S. K., Varghese S., Kim J. H., Yoon S. J., Kwon O. K., An B. K., Gierschner J., Park S. Y.. Tailor-made highly luminescent and ambipolar transporting organic mixed stacked charge-transfer crystals:an isometric donor-acceptor approach[J]. J. Am. Chem. Soc., 2013,135(12):4757-4764. doi: 10.1021/ja312197b
27. [27]
  Aparicio F., Cherumukkil S., Ajayaghosh A., Sanchez L.. Colour-tuneable cyano-substituted divinylene arene luminogens as fluorescent π-gelators[J]. Langmuir, 2016,32(1):284-289. doi: 10.1021/acs.langmuir.5b03771
28. [28]
  Wei R. B., He Y., Wang X. G., Keller P.. Photoluminescent nematic liquid crystalline elastomer with a thermomechanical emission variation function[J]. Macromol. Rapid Commun., 2014,35(18):1571-1577. doi: 10.1002/marc.v35.18
29. [29]
  Li J. T., Zhang Z. W., Tian J. J., Li G. Q., Wei J., Guo J. B.. Dicyanodistyrylbenzene-based chiral fluorescence photoswitches:an emerging class of multifunctional switches for dual-mode phototunable liquid crystals[J]. Adv. Opt. Mater., 2017,5(8)1700014. doi: 10.1002/adom.201700014
30. [30]
  Kim H. J., Whang D. R., Gierschner J., Lee C. H., Park S. Y.. High-contrast red-green-blue tricolor fluorescence switching in bicomponent molecular film[J]. Angew. Chem. Int. Ed., 2015,54(14):4330-4333. doi: 10.1002/anie.201411568
31. [31]
  Li J. J., Chen Y., Yu J., Cheng N., Liu Y.. A supramolecular artificial light-harvesting system with an ultrahigh antenna effect[J]. Adv. Mater., 2017,29(30)1701905. doi: 10.1002/adma.201701905
32. [32]
  Broer D. J., Boven J., Mol G. N., Challa G.. In-situ photopolymerization of oriented liquid-crystalline acrylates, 3 Oriented polymer networks from a mesogenic diacrylate[J]. Makromol. Chem., 1989,190(9):2255-2268.
33. [33]
  Mei J., Leung N. L., Kwok R. T., Lam J. W., Tang B. Z.. Aggregation-induced emission:together we shine, united we soar[J]. Chem. Rev., 2015,115(21):11718-11940. doi: 10.1021/acs.chemrev.5b00263
34. [34]
  Su X., Sun X. Q., Wu S. L., Zhang S. F.. Manipulating the emission intensity and lifetime of NaYF₄:Yb³⁺, Er³⁺ simultaneously by embedding it into CdS photonic crystals[J]. Nanoscale, 2017,9(22):7666-9673. doi: 10.1039/C7NR01172E
35. [35]
  Shao B., Yang Z. W., Li J., Yang J. Z., Wang Y. D., Qiu J. B., Song Z. G.. Au nanoparticles embedded inverse opal photonic crystals as substrates for upconversion emission enhancement[J]. J. Am. Ceram. Soc., 2017,100(3):988-997. doi: 10.1111/jace.14623
36. [36]
  Li H., Xu Z. H., Bao B., Sun N., Song Y. L.. Improving the luminescence performance of quantum dot-based photonic crystals for white-light emission[J]. J. Mater. Chem. C, 2015,4(1):39-44.
37. [37]
  Li J., Yang Z., Shao B., Yang J. Z., Wang Y. D., Qiu J. B., Song Z. G., French R. H.. Photoluminescence enhancement of SiO₂-coated LaPO₄:Eu³⁺ inverse opals by surface plasmon resonance of Ag nanoparticles[J]. J. Am. Ceram. Soc., 2016,99(10):3330-3335. doi: 10.1111/jace.14333
38. [38]
  Wang Q., Qiu J. B., Song Z. G., Yang Z. W., Yin Z. Y., Zhou D. C., Wang S. Q.. Enhancement of Tb-Yb quantum cutting emission by inverse opal photonic crystals[J]. Opt. Mater., 2016,54:229-233. doi: 10.1016/j.optmat.2016.01.058
39. [39]
  Huang H., Chen J. B., Yu Y., Shi Z. M., Möhwald H., Zhang G.. Controlled gradient colloidal photonic crystals and their optical properties[J]. Colloid Surface A, 2013,428(13):9-17.
40. [40]
  Kunzelman J., Kinami M., Crenshaw B. R., Protasiewicz J. D., Weder C.. Oligo(p-phenylene vinylene)s as a "New" class of piezochromic fluorophores[J]. Adv. Mater., 2008,20(1):119-122. doi: 10.1002/(ISSN)1521-4095
1. [1]
  Jiakun Bai , Junhui Jia , Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323
2. [2]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
3. [3]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
4. [4]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
5. [5]
  Peizhe Li , Qiaoling Liu , Mengyu Pei , Yuci Gan , Yan Gong , Chuchen Gong , Pei Wang , Mingsong Wang , Xiansong Wang , Da-Peng Yang , Bo Liang , Guangyu Ji . Chlorogenic acid supported strontium polyphenol networks ensemble microneedle patch to promote diabetic wound healing. Chinese Chemical Letters, 2024, 35(8): 109457-. doi: 10.1016/j.cclet.2023.109457
6. [6]
  Jie Wu , Xiaoqing Yu , Guoxing Li , Su Chen . Engineering particles towards 3D supraballs-based passive cooling via grafting CDs onto colloidal photonic crystals. Chinese Chemical Letters, 2024, 35(4): 109234-. doi: 10.1016/j.cclet.2023.109234
7. [7]
  Rui Liu , Jinbo Pang , Weijia Zhou . Monolayer water shepherding supertight MXene/graphene composite films. Chinese Journal of Structural Chemistry, 2024, 43(10): 100329-100329. doi: 10.1016/j.cjsc.2024.100329
8. [8]
  Mengjun Sun , Zhi Wang , Jvhui Jiang , Xiaobing Wang , Chuang Yu . Gelation mechanisms of gel polymer electrolytes for zinc-based batteries. Chinese Chemical Letters, 2024, 35(5): 109393-. doi: 10.1016/j.cclet.2023.109393
9. [9]
  Huimin Gao , Zhuochen Yu , Xuze Zhang , Xiangkun Yu , Jiyuan Xing , Youliang Zhu , Hu-Jun Qian , Zhong-Yuan Lu . A mini review of the recent progress in coarse-grained simulation of polymer systems. Chinese Journal of Structural Chemistry, 2024, 43(5): 100266-100266. doi: 10.1016/j.cjsc.2024.100266
10. [10]
  Dong Lv , Xuelei Liu , Wei Li , Qiang Zhang , Xinhong Yu , Yanchun Han . Single droplet formation by controlling the viscoelasticity of polymer solutions during inkjet printing. Chinese Chemical Letters, 2024, 35(6): 109401-. doi: 10.1016/j.cclet.2023.109401
11. [11]
  Jinjie Lu , Qikai Liu , Yuting Zhang , Yi Zhou , Yanbo Zhou . Antibacterial performance of cationic quaternary phosphonium-modified chitosan polymer in water. Chinese Chemical Letters, 2024, 35(9): 109406-. doi: 10.1016/j.cclet.2023.109406
12. [12]
  Kexin Yuan , Yulei Liu , Haoran Feng , Yi Liu , Jun Cheng , Beiyang Luo , Qinglian Wu , Xinyu Zhang , Ying Wang , Xian Bao , Wanqian Guo , Jun Ma . Unlocking the potential of thin-film composite reverse osmosis membrane performance: Insights from mass transfer modeling. Chinese Chemical Letters, 2024, 35(5): 109022-. doi: 10.1016/j.cclet.2023.109022
13. [13]
  Minying Wu , Xueliang Fan , Wenbiao Zhang , Bin Chen , Tong Ye , Qian Zhang , Yuanyuan Fang , Yajun Wang , Yi Tang . Highly dispersed Ru nanospecies on N-doped carbon/MXene composite for highly efficient alkaline hydrogen evolution. Chinese Chemical Letters, 2024, 35(4): 109258-. doi: 10.1016/j.cclet.2023.109258
14. [14]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
15. [15]
  Miaomiao Li , Mengwei Yuan , Xingzi Zheng , Kunyu Han , Genban Sun , Fujun Li , Huifeng Li . Highly polar CoP/Co₂P heterojunction composite as efficient cathode electrocatalyst for Li-air battery. Chinese Chemical Letters, 2024, 35(9): 109265-. doi: 10.1016/j.cclet.2023.109265
16. [16]
  Ning DING , Siyu WANG , Shihua YU , Pengcheng XU , Dandan HAN , Dexin SHI , Chao ZHANG . Crystalline and amorphous metal sulfide composite electrode materials with long cycle life: Preparation and performance of hybrid capacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1784-1794. doi: 10.11862/CJIC.20240146
17. [17]
  Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164
18. [18]
  Huihui LIU , Baichuan ZHAO , Chuanhui WANG , Zhi WANG , Congyun ZHANG . Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059
19. [19]
  Hongxia Li , Xiyang Wang , Du Qiao , Jiahao Li , Weiping Zhu , Honglin Li . Mechanism of nanoparticle aggregation in gas-liquid microfluidic mixing. Chinese Chemical Letters, 2024, 35(4): 108747-. doi: 10.1016/j.cclet.2023.108747
20. [20]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(579)
HTML views(0)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142