Citation: Ya-Nan Liu, Jian-Zhong Li, Xiao-Bo Wan. Synthesis of Novel Scolopendra-type Polydodecyloxybenzoyl[1, 5]-diazocine as New Material for Optical Sensor[J]. Chinese Journal of Polymer Science, ;2018, 36(6): 736-741. doi: 10.1007/s10118-018-2062-6 shu

Synthesis of Novel Scolopendra-type Polydodecyloxybenzoyl[1, 5]-diazocine as New Material for Optical Sensor

a.
College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao 266109, China
b.
Qingdao institute of Bioprocess Technology, Chinese Academy of Science, Qingdao 266101, China

Corresponding author: Jian-Zhong Li, jzhlee@163.com Xiao-Bo Wan, wanxb@qibebt.ac.cn
Received Date: 1 September 2017
Accepted Date: 11 October 2017
Available Online: 8 February 2018

A new scolopendra-type polymer of polydodecyloxybenzoyl[1, 5]-diazocine (PDBD) was designed and prepared using 2, 5-bis(4-(dodecyloxy)-benzoyl)terephthaloyl azide with trifluoroacetic acid (TFA) via one-pot reaction in good yields. The structure of polymer was characterized using ¹H-NMR, ¹³C-NMR and MALDI-TOF spectra. The polymer PDBD exhibits good thermal stability as measured by TGA and DSC, and can be dissolved well in common organic solvents such as chloroform and tetrahydrofuran. In addition, UV-Vis spectral studies indicate that the polymer PDBD shows unique optical property changes (protonation/deprotonation) in the different trifluoroacetic acid environments. The new polymer is expected to be utilized as an optical functional material for fabricating optical sensors in environmental and biological fields.
- Diazocine,
- Scolopendra-type polymer,
- Trifluoroacetic acid,
- UV-Vis
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沈阳化工大学材料科学与工程学院沈阳 110142