Citation: Xu-Lin Yang, Kui Li, Ming-Zhen Xu, Xiao-Bo Liu. Designing a Phthalonitrile/Benzoxazine Blend for the Advanced GFRP Composite Materials[J]. Chinese Journal of Polymer Science, ;2018, 36(1): 106-112. doi: 10.1007/s10118-018-2033-y shu

Designing a Phthalonitrile/Benzoxazine Blend for the Advanced GFRP Composite Materials

Research Branch of Functional Materials, Institute of Microelectronic & Solid State Electronic, University of Electronic Science and Technology of China, Chengdu 610054, China

Corresponding author: Ming-Zhen Xu, mzxu628@uestc.edu.cn Xiao-Bo Liu, liuxb@uestc.edu.cn
Received Date: 30 June 2017
Accepted Date: 5 September 2017
Available Online: 30 October 2017

High performance resin must be used in the high performance glass fiber-reinforced plastic (GFRP) composites, but it is sometimes difficult to balance the processabilities and the final properties in the design of advanced thermoset GFRP composites. In this study, a phthalonitrile/benzoxazine (PPN/BZ) blend with excellent processability has been designed and applied in the GFRP composite materials. PPN/BZ blend with good solubility, low melt viscosity, appropriate gel condition and low-temperature curing behavior could enable their GFRP composite preparation with the prepreg-laminate method under a relatively mild condition. The resulted PPN/BZ GFRP composites exhibit excellent mechanical properties with flexural strength over 700 MPa and flexural modulus more than 19 GPa. Fracture surface morphologies of the PPN/BZ GFRP composites show that the interfacial adhesion between resin and GF is improved. The temperatures at weight loss 5% (T_5%) and char residue at 800℃ of all PPN/BZ GFRP composites are over 435℃ and 65% respectively. PPN/BZ GFRP composites with high performance characteristics may find applications under some critical circumstances with requirements of high mechanical properties and high service temperatures.
- Phthalonitrile,
- Benzoxazine,
- High performance composite,
- GFRP composites
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