Citation: Gui-Qiu Ma, Guan-Kai Sun, Zhe Ma, Jing-Qing Li, Jing Sheng. In-line Plasma-induced Graft-copolymerization of Pentaerythritol Triacrylate onto Polypropylene[J]. Chinese Journal of Polymer Science, ;2018, 36(8): 979-983. doi: 10.1007/s10118-018-2023-0 shu

In-line Plasma-induced Graft-copolymerization of Pentaerythritol Triacrylate onto Polypropylene

Department of Polymer Material Science and Engineering, Institute of Advanced Polymer Materials, School of Material Science and Engineering, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300350, China

Corresponding author: Gui-Qiu Ma, magq@tju.edu.cn
Received Date: 9 November 2017
Accepted Date: 9 December 2017
Available Online: 6 March 2018

Pentaerythritol triacrylate (PETA) was successfully grafted onto the plasma-treated isotactic polypropylene (iPP) via the in situ melt processing. The X-ray photoelectron spectroscopy (XPS) results showed that the hydroxyl and carbonyl groups, and peroxides could be generated via plasma treatment. The content of free radical in plasma-treated iPP (PiPP) was measured by 2,2-diphenyl-1-picrylhydrazyl (DPPH). It was found that the resulting peroxides induced the grafting copolymerization of PETA onto iPP, and the grafted PETA promoted the formation of β-crystal in PiPP, which was evidenced by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD) measurements, respectively.
- Plasma treatment,
- Melt processing,
- Graft copolymerization,
- Pentaerythritol triacrylate
1. [1]
  Bhattacharya, A.; Misra, B. N. Grafting: a versatile means to modify polymers: techniques, factors and applications. Prog. Polym. Sci. 2004, 29(8), 767−814 doi: 10.1016/j.progpolymsci.2004.05.002
2. [2]
  Xu, G. H. , Jiang, E. Y., and Sheng, J. , " Plasma technologies and application” (in Chinese), Chemical Engineering Publication, Beijing, 2006, p. 218
3. [3]
  Weng, W.; Hu, W.; Dekmezian, A. H.; Ruff, C. J. Long chain branched isotactic polypropylene. Macromolecules 2002, 35(10), 3838−3843 doi: 10.1021/ma020050j
4. [4]
  Liu, Z. M.; Xu, Z. K.; Wang, J. Q.; Wu, J.; Fu, J. J. Surface modification of polypropylene microfiltration membranes by graft polymerization of N-vinyl-2-pyrrolidone. Eur. Polym. J. 2004, 40(9), 2077−2087 doi: 10.1016/j.eurpolymj.2004.05.020
5. [5]
  Kaur, S.; Ma, Z. W.; Gopal, R.; Singh, G.; Matsuura, T. Plasma-induced graft copolymerization of poly(methacrylic acid) on electrospun poly(vinylidene fluoride) nanofiber membrane. Langmuir 2007, 23(26), 13085−13092 doi: 10.1021/la701329r
6. [6]
  Borsig, E.; Duin, M. V.; Gotsis, A. D.; Picchioni, F. Long chain branching on linear polypropylene by solid state reactions. Eur. Polym. J. 2008, 44(1), 200−212 doi: 10.1016/j.eurpolymj.2007.10.008
7. [7]
  Samanta, K. K.; Jassal, M.; Agrawal, A. K. Improvement in water and oil absorbency of textile substrate by atmospheric pressure cold plasma treatment. Surf. Coat. Technol. 2009, 203(10-11), 1336−1342 doi: 10.1016/j.surfcoat.2008.10.044
8. [8]
  Li, S.; Xiao, M.; Wei, D.; Xiao, H. N.; Hu, F.; Zheng, A. The melt grafting preparation and rheological characterization of long chain branching polypropylene. Polymer 2009, 50(25), 6121−6128 doi: 10.1016/j.polymer.2009.10.006
9. [9]
  Li, S.; Xiao, M.; Guan, Y.; Wei, D.; Xiao, H. N.; Zheng, A. A novel strategy for the preparation of long chain branching polypropylene and the investigation on foamability and rheology. Eur. Polym. J. 2012, 48(2), 362−371 doi: 10.1016/j.eurpolymj.2011.11.015
10. [10]
  Wang, X. C.; Tzoganakis, C.; Rempel, G. L. Chemical modification of polypropylene with peroxide/pentaerythritol triacrylate by reactive extrusion. J. Appl. Polym. Sci. 1996, 61(8), 1395−1404 doi: 10.1002/(ISSN)1097-4628
11. [11]
  Tian, J. H.; Yu, W.; Zhou, C. X. The preparation and rheology characterization of long chain branching polypropylene. Polymer 2006, 47(23), 7962−7969 doi: 10.1016/j.polymer.2006.09.042
12. [12]
  Wang, K.; Wang, S. C.; Wu, F.; Pang, Y. Y.; Liu, W.; Zhai, W. T.; Zheng, W. G. A new strategy for preparation of long-chain branched polypropylene via reactive extrusion with supercritical CO₂ designed for an improved foaming approach. J. Mater. Sci. 2016, 51(5), 2705−2715 doi: 10.1007/s10853-015-9584-x
13. [13]
  Ma, G. Q.; Liu, X. N.; Huang, D. H.; Yuan, X. B.; Sheng, J. Surface modification of polypropylene and compatibilization of interfaces in incompatible blends of polypropylene with polystyrene by plasma of CO₂. Appl. Surf. Sci. 2009, 255(17), 7483−7494 doi: 10.1016/j.apsusc.2009.03.066
14. [14]
  Saxena, S.; Ray, A. R.; Gupta, B. Graft polymerization of acrylic acid onto polypropylene monofilament by RF plasma. J. Appl. Polym. Sci. 2010, 116, 2884−2892
15. [15]
  Ma, G. Q.; Liu, B.; Li, C.; Huang, D. H.; Sheng, J. Plasma modification of polypropylene surfaces and its alloying with styrene in situ. Appl. Surf. Sci. 2012, 258(7), 2424−2432 doi: 10.1016/j.apsusc.2011.10.065
16. [16]
  Ma, G. Q.; Zhai, J. J.; Liu, B.; Huang, D. H.; Sheng, J. Plasma modification of polypropylene surfaces and grafting copolymerization of styrene onto polypropylene. Chinese J. Polym. Sci. 2012, 30(3), 423−435 doi: 10.1007/s10118-012-1130-6
17. [17]
  Mazloumpour, M.; Malshe, P.; El-Shafei, A.; Hauser, P. Conferring durable antimicrobial properties on nonwoven polypropylene via plasma-assisted graft polymerization of DADMAC. Surf. Coat. Technol. 2013, 224(224), 1−7
18. [18]
  Abednejad, A. S.; Amoabediny, G.; Ghaee, A. Surface modification of polypropylene membrane by polyethylene glycol graft polymerization. Mater. Sci. Eng. C 2014, 42, 443−450 doi: 10.1016/j.msec.2014.05.060
19. [19]
  Ma, G. Q.; Liu, Y. P.; Wei, S. X.; Sheng, J. Surface modification of polypropylene by ethylene plasma and its induced β-form in polypropylene. Chinese J. Polym. Sci. 2015, 33(5), 669−673 doi: 10.1007/s10118-015-1631-1
20. [20]
  Pandiyaraj, K. N.; Kumar, M. C. R.; Kumar, A. A.; Padmanabhan, P. V. A.; Deshmukh, R. R.; Bah, M.; Shah, S. I.; Su, P. G.; Jr, M. H.; Halim, A. S. Tailoring the surface properties of polypropylene films through cold atmospheric pressure plasma (CAPP) assisted polymerization and immobilization of biomolecules for enhancement of anti-coagulation activity. Appl. Surf. Sci. 2016, 370, 545−556 doi: 10.1016/j.apsusc.2016.02.137
21. [21]
  Fargere, T.; Abdennadher, M.; Delmas, M.; Boutevin, B. Determination of peroxides and hydroperoxides with 2,2-diphenyl-1-picrylhydrazyl (DPPH). Application to ozonized ethylene vinyl acetate copolymers (EVA). Eur. Polym. J. 1995, 31(5), 489−497
22. [22]
  Wang, C.; Chen, J. R. Study on peroxide of poly(tetrafluoroethylene) surface modified with argon remote-plasma. Chemical Industry and Engineering Progress (in Chinese) 2008, 27(9), 1465−1468
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