Citation: Zeng-He Liu, Ji-Qing Huang, Li-Jie Sun, v Lei, Jing Cao, Shuo Chen, Wen-Chang Shih, Feng-Ling Qing, Zheng-Wei You. PPC-based Reactive Hot Melt Polyurethane Adhesive (RHMPA) -Efficient Glues for Multiple Types of Substrates[J]. Chinese Journal of Polymer Science, ;2018, 36(1): 58-64. doi: 10.1007/s10118-018-2011-4 shu

PPC-based Reactive Hot Melt Polyurethane Adhesive (RHMPA) -Efficient Glues for Multiple Types of Substrates

Zeng-He Liu ^a ,
Ji-Qing Huang ^b ,
Li-Jie Sun ^a,c ,
v Lei ^a ,
Jing Cao ^c ,
Shuo Chen ^a,c ,
Wen-Chang Shih ^d ,
Feng-Ling Qing ^a,e,, ,
Zheng-Wei You ^a,c,,

a.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China
b.
Beijing Institute of Aerospace Testing Technology, Beijing 100074, China
c.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
d.
Department of Chemical and Materials Engineering, National Chin-Yi University of Technology, Taichung 41170, China
e.
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032, China

Corresponding author: Feng-Ling Qing, flqing@dhu.edu.cn Zheng-Wei You, zyou@dhu.edu.cn
Received Date: 18 May 2017
Revised Date: 15 July 2017
Accepted Date: 15 July 2017
Available Online: 2 November 2017

Tens of billion metric tons of anthropogenic CO₂ discharged from the burning of fossil fuels lead to an enormous environmental and resource burden. It is charming to transform CO₂ to desirable, economical chemicals and materials. Poly(propylene carbonate) (PPC) is an emerging CO₂-based material. Herein, we report the design, synthesis and characterization of the reactive hot melt polyurethane adhesive (RHMPA) based on PPC polyol. The resultant RHMPAs exhibit good adhesion properties to multiple substrates including plastics (PC, PMMA, ABS) and metals (aluminium, steel), which is comparable to or even better than conventional RHMPAs prepared from petro-based polyol. Furthermore, the PPC-based RHMPAs have tunable mechanical properties, and are thermally stable in the typical working range of bonding process (up to 270℃). The study is expected to expand the applications of PPC and provide a new type of CO₂-based renewable and eco-friendly materials.
- CO₂-based poly(propylene carbonate),
- Reactive hot melt polyurethane adhesive,
- Sustainable adhesive,
- Adhesion property
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