Citation: Tian-Qi Wang, Yang Xu, Zi-Dong He, Ming-Hong Zhou, Kun Huang. Microporous Organic Nanotube Networks from Hyper Cross-linking Core-shell Bottlebrush Copolymers for Selective Adsorption Study[J]. Chinese Journal of Polymer Science, ;2018, 36(1): 98-105. doi: 10.1007/s10118-018-2007-0 shu

Microporous Organic Nanotube Networks from Hyper Cross-linking Core-shell Bottlebrush Copolymers for Selective Adsorption Study

School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241, China

Corresponding author: Kun Huang, khuang@chem.ecnu.edu.cn
Received Date: 2 May 2017
Accepted Date: 3 July 2017
Available Online: 27 September 2017

We report a synthesis of microporous organic nanotube networks (MONNs) by a combination of hyper cross-linking and molecular templating of core-shell bottlebrush copolymers. The intrabrush and interbrush cross-linking of polystyrene (PS) shell layer in the core-shell bottlebrush copolymers led to the formation of micropores and large-sized nanopores (meso/macrospores) in MONNs, respectively, while selective removal of polylactide (PLA) core layer generated mesoporous tubular structure. The size of PLA-templated mesoporous cores and porous structure both at micro-and meso-scale could be controlled by simple tuning of the ratio of core/shell or the PLA core fraction in the bottlebrush precursors. Moreover, the resultant MONNs showed a highly selective adsorption capacity for the positively charged dyes on the basis of multi-porosity and carboxylate group-rich structure. In addition, MONNs also exhibited effective performance in size-selective adsorption of biomacromolecules. This work represents a new avenue for the preparation of MONNs and also provides a new application for molecular bottlebrushes in nanotechnology.
- Microporous organic nanotube networks,
- Hyper cross-linking,
- Core-shell bottlebrush copolymers,
- Meso/Macrospores,
- Selective adsorption capacity
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