Citation: Zhen Yang, Ning Li, Xiao-xue Yang, Xiao-a Zhang, Sheng-ling Jiang, Ya-fei Lyu. Synthesis and Characterization of Carborane-containing Poly(hydroxy ethers) with Excellent Thermal Stability[J]. Chinese Journal of Polymer Science, ;2017, 35(12): 1463-1473. doi: 10.1007/s10118-017-1994-6 shu

Synthesis and Characterization of Carborane-containing Poly(hydroxy ethers) with Excellent Thermal Stability

Zhen Yang ^a,† ,
Ning Li ^b,† ,
Xiao-xue Yang ^a ,
Xiao-a Zhang ^a,, ,
Sheng-ling Jiang ^a ,
Ya-fei Lyu ^a

a.
Key Laboratory of Carbon Fiber and Functional Polymers of Ministry of Education, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
b.
School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China

Corresponding author: Xiao-a Zhang, zhangxiaoa1982@163.com

^†

Received Date: 7 May 2017
Revised Date: 6 June 2017
Accepted Date: 16 June 2017

Fund Project: National Key R & D Program of China 2016YFB0302105

o-Carborane-containing poly(hydroxy ethers) (P1, P2 and P3) were synthesized via "advancement reaction" of o-carborane-containing bisphenol (4) and diglycidyl ether of bisphenols (DGEBA and 1). FTIR and ¹H-, ¹³C-, and ¹¹B-NMR were utilized to characterize the obtained polymers. TGA test was conducted under nitrogen and air. It is found that the shielding effect of carborane moiety on its adjacent aromatic structures contributes to high initial decomposition temperatures, while oxygen in air has an adverse effect on the initial decomposition temperature. The oxygen can combine with polymer chain to form peroxide and hydroperoxide groups, which are more reactive during the degradation process. Besides, o-carborane-containing poly(hydroxy ethers) have high char yield at elevated temperatures. The boron atom combines with oxygen from the polymer structure or/and from air, thus to form a three-dimensional network linked with B-O-B and B-C bonds, and retain the polymer weight to a large extent.
- Carborane,
- Poly (hydroxy ethers),
- Thermal stability
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