Citation: Jie-xin Liao, Jia-he Huang, Tao Wang, Wei-xiang Sun, Zhen Tong. Rapid Shape Memory and pH-modulated Spontaneous Actuation of Dopamine Containing Hydrogels[J]. Chinese Journal of Polymer Science, ;2017, 35(10): 1297-1306. doi: 10.1007/s10118-017-1991-9 shu

Rapid Shape Memory and pH-modulated Spontaneous Actuation of Dopamine Containing Hydrogels

Jie-xin Liao ^a ,
Jia-he Huang ^a ,
Tao Wang ^a,, ,
Wei-xiang Sun ^a ,
Zhen Tong ^a,b,,

a.
Research Institute of Materials Science, South China University of Technology, Guangzhou 510640, China
b.
State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, China

Corresponding author: Tao Wang, fetwang@scut.edu.cn Zhen Tong, mcztong@scut.edu.cn
Received Date: 26 April 2017
Revised Date: 30 May 2017
Accepted Date: 6 June 2017

Fund Project: the Pearl River S & T Nova Program of Guangzhou 201710010146the National Natural Science Foundation of China 21427805the National Natural Science Foundation of China 51573060

The dopamine containing hydrogels with rapid responsive shape memory capability were synthesized by a one-pot method. The temporary shape of hydrogel was fixed within 20 s in NaOH solution by the tris-complex crosslinking of metal-ligand complex between Fe³⁺ ions and catechol groups, while the permanent shape was recovered completely in HCl solution within 60 s upon the change from tris-complex to mono-complex. The hydrogel showed unique spontaneous actuation behavior. It could curl spontaneously without further external force deformation when immersed in NaOH solution again after the first shape recovery in HCl solution. This might be attributed to the competitive result of swelling and additional tris-complex crosslinking formation when immersed in NaOH solution. In addition, the hydrogels also had proper modulus, elongation ratio and tensile strength. Such hydrogel provides a new candidate material for designing soft actuators and robots modulated with spontaneous actuating.
- Shape memory hydrogel,
- Spontaneous actuation,
- Dopamine,
- pH-modulated,
- Metal-ligand cross-link
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