Citation: Jing Nie, Zhi-liang Wang, Jie-fu Li, Ying Gong, Jia-xing Sun, Shu-guang Yang. Interface Hydrogen-bonded Core-Shell Nanofibers by Coaxial Electrospinning[J]. Chinese Journal of Polymer Science, ;2017, 35(8): 1001-1008. doi: 10.1007/s10118-017-1984-8 shu

Interface Hydrogen-bonded Core-Shell Nanofibers by Coaxial Electrospinning

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-dimension Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620, China

Corresponding author: Shu-guang Yang, shgyang@dhu.edu.cn
Received Date: 31 December 2016
Revised Date: 23 March 2017
Accepted Date: 27 March 2017

Fund Project: Science and Technology Commission of Shanghai Municipality 16JC1400700the National Natural Science Foundation of China 51373032

Core-shell nanofibers were prepared by coaxial electrospinning technology, with poly(ethylene oxide) (PEO) as the core while poly(acrylic acid) (PAA) as the shell. PEO and PAA can form polymer complexes based on hydrogen bonding. In order to avoid forming strong hydrogen bonding complexes at nozzle and blocking spinning process, a polar aprotic solvent, N, N-dimethylformamide (DMF), was selected to dissolve PEO and PAA respectively. SEM, TEM and DSC were utilized to characterize the morphology and structure of PEO-PAA core-shell nanofibers. FTIR spectra demonstrated that hydrogen bonding was formed at the core-shell interface. In addition, the PAA shell of the nanofibers can be cross-linked by ethylene glycol (EG) under heat treatment, which increases the stability and extends the potential applications in aqueous environment.
- Coaxial electrospinning,
- Core-shell nanofibers,
- Hydrogen bonding
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