Citation: Jun-chao Liu, Yuan-yuan Shang, Da-jie Zhang, Zheng Xie, Rui-xiang Hu, Jing-xia Wang. Single-material Solvent-sensitive Fluorescent Actuator from Carbon Dots Inverse Opals Based on Gradient Dewetting[J]. Chinese Journal of Polymer Science, ;2017, 35(9): 1043-1050. doi: 10.1007/s10118-017-1981-y shu

Single-material Solvent-sensitive Fluorescent Actuator from Carbon Dots Inverse Opals Based on Gradient Dewetting

Jun-chao Liu ^a,b ,
Yuan-yuan Shang ^a,b ,
Da-jie Zhang ^a,b ,
Zheng Xie ^b ,
Rui-xiang Hu ^a,, ,
Jing-xia Wang ^b,c,,

a.
College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China
b.
Key Laboratory of Bio-inspired Materials and Interface Sciences, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
c.
Laboratory of Bioinspired materials, School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Rui-xiang Hu, hurx@hunnu.edu.cn Jing-xia Wang, jingxiawang@mail.ipc.ac.cn
Received Date: 10 April 2017
Revised Date: 11 May 2017
Accepted Date: 17 May 2017

Fund Project: the Ministry of Science and Technology of China 2016YFA0200803Scientific Research Fund of Hunan Provincial Science and Technology Department 09236the National Natural Science Foundation of China 51373183the National Natural Science Foundation of China 51673207the Ministry of Science and Technology of China 2016YFB0402004

A novel solvent-sensitive fluorescent actuator with reversibility has been obtained from carbon dots (CDs) inverse opals, which is prepared via infiltrating CDs solution into the interstice of colloidal crystal template, thermal polymerization of CDs materials and removing the colloidal template. The as-prepared CDs inverse opal actuator shows a bending angle of 75° in 10.2 s, bending rate of 7.35 (°)·s^-1. In particular, the fluorescence intensity of the films varies during the actuating process. The actuating behavior is attributed to the inhomogeneous swelling/shrinking of the film, which originates from the gradient dewetting by solvent evaporation and hydrogen-bonding interaction between the solvent molecules and oxygen/hydrogen ions of CDs side chain. The CDs inverse opal actuator has the advantages of quick response, good repeatability and strong fluorescence, which gives an important insight into the design and manufacture of novel and advanced solvent-actuators.
- Carbon dots inverse opal,
- Fluorescent,
- Single-material,
- Gradient dewetting,
- Solvent-actuator
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