Citation: Qi Chen, Min Zuo, Yi-hu Song, Qiang Zheng. Molecular Dynamics and Phase Behavior of Polystyrene/Poly(vinyl methyl ether) Blend in the Presence of Nanosilica[J]. Chinese Journal of Polymer Science, ;2017, 35(12): 1524-1539. doi: 10.1007/s10118-017-1980-z shu

Molecular Dynamics and Phase Behavior of Polystyrene/Poly(vinyl methyl ether) Blend in the Presence of Nanosilica

Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Min Zuo, kezuomin@zju.edu.cn
Received Date: 20 March 2017
Revised Date: 30 April 2017
Accepted Date: 17 May 2017

Fund Project: Zhejiang Natural Science Foundation LY16E030001the Fundamental Research Funds for the Central Universities 2017QNA4038the National Natural Science Foundation of China 51273173

The variation of phase morphology, critical temperature of demixing, and molecular dynamics for polystyrene/poly(vinyl methyl ether) (PS/PVME) blends induced by hydrophilic nanosilica (A200) or hydrophobic nanosilica (R974) was investigated. With the phase separation of blend matrix, A200 migrated into PVME-rich phase due to strong interaction between A200 and PVME, while R974 moved into PS-rich phase. The thermodynamic miscibility and concentration fluctuation during phase separation of blend matrix were remarkably retarded by A200 nanoparticles due to the surface adsorption of PVME on A200, verified by the correlation length ξ near the critical region from rheological measurement and the weakened increment of reversing heat capacity (ΔC_p) during glass transition via modulated differential scanning calorimetry (MDSC). The restricted chain diffusion induced by nanosilica still occurred despite no influence of A200 and R974 on the segmental dynamics of homogenous blend matrix. The interactions between nanosilica and polymer components could restrict the terminal relaxation of blend matrix and further manipulate their phase behavior.
- Phase separation,
- Nanoparticles,
- Rheology,
- Molecular dynamics
1. [1]
  Wang, M., Pramoda, K. and Goh, S.H., Polymer, 2005, 46(25):11510 doi: 10.1016/j.polymer.2005.10.007
2. [2]
  Nair, S.T., Vijayan, P.P., Xavier, P., Bose, S., George, S.C. and Thomas, S., Compos. Sci. Technol., 2015, 116:9 doi: 10.1016/j.compscitech.2015.04.021
3. [3]
  Li, H.H., Zuo, M., Liu, T., Chen, Q., Zhang, J. and Zheng, Q., RSC Adv., 2016, 6(12):10099 doi: 10.1039/C5RA23002K
4. [4]
  Allen, R. C., Kotz, A. L., Carlson, L. W., Nevitt, T. J., Ouderkirk, A. J., Stover, C. A., Weber, M. F. and Majumdar, B., Optical film with co-continuous phases, Google Patents, 2003
5. [5]
  Huang, C., Gao, J., Yu, W. and Zhou, C., Macromolecules, 2012, 45(20):8420 doi: 10.1021/ma301186b
6. [6]
  Gao, J., Huang, C., Wang, N., Yu, W. and Zhou, C., Polymer, 2012, 53(8):1772 doi: 10.1016/j.polymer.2012.02.027
7. [7]
  Li, H., Li, Q., Li, L. and Yang, Q., J. Macromol. Sci. B, 2014, 53(6):993 doi: 10.1080/00222348.2013.879777
8. [8]
  Xavier, P., Rao, P. and Bose, S., Phys. Chem. Chem. Phys., 2016, 18(1):47 doi: 10.1039/C5CP05852J
9. [9]
  Lipatov, Y.S., Prog. Polym. Sci., 2002, 27(9):1721 doi: 10.1016/S0079-6700(02)00021-7
10. [10]
  Ginzburg, V.V., Macromolecules, 2005, 38(6):2362 doi: 10.1021/ma0482821
11. [11]
  Klonos, P., Panagopoulou, A., Kyritsis, A., Bokobza, L. and Pissis, P., J. Non-Cryst. Solids, 2011, 357(2):610 doi: 10.1016/j.jnoncrysol.2010.06.058
12. [12]
  Lu, H. and Nutt, S., Macromolecules, 2003, 36(11):4010 doi: 10.1021/ma034049b
13. [13]
  Yurekli, K., Karim, A., Amis, E.J. and Krishnamoorti, R., Macromolecules, 2003, 36 (19):7256 doi: 10.1021/ma020755l
14. [14]
  Xavier, P., Bharati, A., Madras, G. and Bose, S., Phys. Chem. Chem. Phys., 2014, 16(39):21300 doi: 10.1039/C4CP02485K
15. [15]
  Taguet, A., Cassagnau, P. and Lopez-Cuesta, J.M., Prog. Polym. Sci., 2014, 39(8):1526 doi: 10.1016/j.progpolymsci.2014.04.002
16. [16]
  Li, L., Miesch, C., Sudeep, P., Balazs, A.C., Emrick, T., Russell, T.P. and Hayward, R.C., Nano Lett., 2011, 11(5):1997 doi: 10.1021/nl200366z
17. [17]
  Gelb, L.D., Gubbins, K., Radhakrishnan, R. and Sliwinska-Bartkowiak, M., Rep. Prog. Phys., 1999, 62(12):1573 doi: 10.1088/0034-4885/62/12/201
18. [18]
  Hashimoto, T., Kumaki, J. and Kawai, H., Macromolecules, 1983, 16(4):641 doi: 10.1021/ma00238a030
19. [19]
  Snyder, H.L., Meakin, P. and Reich, S., Macromolecules, 1983, 16(5):757 doi: 10.1021/ma00239a011
20. [20]
  Li, L., Nano Lett., 2011, 11(5):1997 doi: 10.1021/nl200366z
21. [21]
  Cahn, J.W., J. Chem. Phys., 1965, 42(1):93 doi: 10.1063/1.1695731
22. [22]
  Cahn, J.W. and Hilliard, J.E., J. Chem. Phys., 1958, 28(2):258 doi: 10.1063/1.1744102
23. [23]
  Rogers, T., Elder, K. and Desai, R.C., Phys. Rev. B, 1988, 37(16):9638 doi: 10.1103/PhysRevB.37.9638
24. [24]
  Kim, D., Srivastava, S., Narayanan, S. and Archer, L.A., Soft Matter, 2012, 8(42):10813 doi: 10.1039/c2sm26325d
25. [25]
  Holt, A.P., Griffin, P.J., Bocharova, V., Agapov, A.L., Imel, A.E., Dadmun, M.D., Sangoro, J.R. and Sokolov, A.P., Macromolecules, 2014, 47(5):1837 doi: 10.1021/ma5000317
26. [26]
  Krishnamoorti, R. and Yurekli, K., Curr. Opin. Colloid Interface Sci., 2001, 6(5):464
27. [27]
  Galgali, G., Ramesh, C. and Lele, A., Macromolecules, 2001, 34(4):852 doi: 10.1021/ma000565f
28. [28]
  Krishnamoorti, R. and Giannelis, E.P., Macromolecules, 1997, 30(14):4097 doi: 10.1021/ma960550a
29. [29]
  Tanaka, H., Phys. Rev. Lett., 1993, 71(19):3158 doi: 10.1103/PhysRevLett.71.3158
30. [30]
  Tanaka, H., Phys. Rev. Lett., 1996, 76(5):787 doi: 10.1103/PhysRevLett.76.787
31. [31]
  Tanaka, H., J. Phys. Condens. Matter, 2000, 12(15):R207 doi: 10.1088/0953-8984/12/15/201
32. [32]
  Ajji, A., Choplin, L. and Prud'Homme, R., J. Polym. Sci., Part B:Polym. Phys., 1988, 26(11):2279 doi: 10.1002/polb.1988.090261108
33. [33]
  Xavier, P. and Bose, S., J. Phys. Chem. B, 2013, 117(28):8633 doi: 10.1021/jp404610w
34. [34]
  Yeganeh, J.K., Goharpey, F., Moghimi, E., Petekidis, G. and Foudazi, R., Soft Matter, 2014, 10 (46):9270 doi: 10.1039/C4SM01499E
35. [35]
  Bode, R., Ferch, H. and Fratzscher, H., Tech. Bulletin Fine Particles, 2006, 11(4):55
36. [36]
  de Gennes, P.G., J. Chem. Phys., 1980, 72(9):4756 doi: 10.1063/1.439809
37. [37]
  Pincus, P., J. Chem. Phys., 1981, 75(4):1996 doi: 10.1063/1.442226
38. [38]
  Hirose, Y., Urakawa, O. and Adachi, K., Macromolecules, 2003, 36(10):3699 doi: 10.1021/ma0217940
39. [39]
  Kumar, S.K., Shenogin, S. and Colby, R.H., Macromolecules, 2007, 40(16):5759 doi: 10.1021/ma070502y
40. [40]
  Bogoslovov, R., Roland, C., Ellis, A., Randall, A. and Robertson, C., Macromolecules, 2008, 41(4):1289 doi: 10.1021/ma702372a
41. [41]
  Comer, A., Heilman, A. and Kalika, D., Polymer, 2010, 51(22):5245 doi: 10.1016/j.polymer.2010.08.053
42. [42]
  Xavier, P. and Bose, S., Phys. Chem. Chem. Phys., 2014, 16(20):9309 doi: 10.1039/c4cp00832d
43. [43]
  Donth, E., J. Non-Cryst. Solids, 1982, 53(3):325 doi: 10.1016/0022-3093(82)90089-8
44. [44]
  Han, C.D., Baek, D.M., Kim, J.K., Ogawa, T., Sakamoto, N. and Hashimoto, T., Macromolecules, 1995, 28(14):5043 doi: 10.1021/ma00118a038
45. [45]
  Friedrich, C., Schwarzwaelder, C. and Riemann, R.E., Polymer, 1996, 37(12):2499 doi: 10.1016/0032-3861(96)85365-1
46. [46]
  Ajji, A. and Choplin, L., Macromolecules, 1991, 24(18):5221 doi: 10.1021/ma00018a031
47. [47]
  Fredrickson, G.H. and Larson, R., J. Chem. Phys., 1987, 86(3):1553 doi: 10.1063/1.452194
48. [48]
  Khademzadeh Yeganeh, J., Goharpey, F., Moghimi, E., Petekidis, G. and Foudazi, R., Phys. Chem. Chem. Phys., 2015, 17 (41), 27446 doi: 10.1039/C5CP04042F
49. [49]
  Gao, J., Huang, C., Wang, N., Yu, W. and Zhou, C., Polymer, 2012, 53(8):1772 doi: 10.1016/j.polymer.2012.02.027
50. [50]
  Xia, T., Huang, Y., Peng, X. and Li, G., Macromol. Chem. Phys., 2010, 211(20):2240 doi: 10.1002/macp.v211:20
51. [51]
  Gharachorlou, A. and Goharpey, F., Macromolecules, 2008, 41(9):3276 doi: 10.1021/ma7020985
52. [52]
  Khademzadeh Yeganeh, J., Goharpey, F. and Foudazi, R., Macromolecules, 2010, 43(20):8670 doi: 10.1021/ma101421s
53. [53]
  Kar, G.P., Begam, N., Basu, J.K. and Bose, S., Macromolecules, 2014, 47(21):7525 doi: 10.1021/ma501844s
54. [54]
  Bharati, A., Xavier, P., Kar, G.P., Madras, G. and Bose, S., J. Phys. Chem. B, 2014, 118(8):2214
55. [55]
  Pathak, J.A., Colby, R.H., Floudas, G. and Jérôme, R., Macromolecules, 1999, 32(8):2553 doi: 10.1021/ma9817121
56. [56]
  Lipatov, Y.S., Nesterov, A.E., Ignatova, T.D. and Nesterov, D.A., Polymer, 2002, 43(3):875 doi: 10.1016/S0032-3861(01)00632-2
57. [57]
  Nesterov, A.E., Lipatov, Y.S., Horichko, V.V. and Gritsenko, O.T., Polymer, 1992, 33(3):619 doi: 10.1016/0032-3861(92)90740-N
58. [58]
  Yurekli, K., Karim, A., Amis, E.J. and Krishnamoorti, R., Macromolecules, 2004, 37(2):507 doi: 10.1021/ma0302098
59. [59]
  Chung, H.J., Wang, H. and Composto, R.J., Macromolecules, 2006, 39(1):153 doi: 10.1021/ma051513z
60. [60]
  Lorén, N., Altskär, A. and Hermansson, A.M., Macromolecules, 2001, 34(23):8117 doi: 10.1021/ma010722q
61. [61]
  Snyder, H.L., Meakin, P. and Reich, S., J. Chem. Phys., 1983, 78(6):3334 doi: 10.1063/1.445200
62. [62]
  Xia, T., Huang, Y., Jiang, X., Lv, Y., Yang, Q. and Li, G., Macromolecules, 2013, 46(20):8323 doi: 10.1021/ma4011582
63. [63]
  Xavier, P., Sharma, K., Elayaraja, K., Vasu, K.S., Sood, A.K. and Bose, S., RSC Adv., 2014, 4(24):12376 doi: 10.1039/c3ra46902f
64. [64]
  Jancar, J., Douglas, J., Starr, F.W., Kumar, S., Cassagnau, P., Lesser, A., Sternstein, S.S. and Buehler, M., Polymer, 2010, 51(15):3321 doi: 10.1016/j.polymer.2010.04.074
65. [65]
  Bailly, M., Kontopoulou, M. and El Mabrouk, K., Polymer, 2010, 51(23):5506 doi: 10.1016/j.polymer.2010.09.051
66. [66]
  Akcora, P., Kumar, S.K., Moll, J., Lewis, S., Schadler, L.S., Li, Y., Benicewicz, B.C., Sandy, A., Narayanan, S. and Ilavsky, J., Macromolecules, 2009, 43(2):1003
67. [67]
  Jiao, Y. and Akcora, P., Macromolecules, 2012, 45(8):3463 doi: 10.1021/ma3000576
68. [68]
  Cassagnau, P., Polymer, 2008, 49(9):2183 doi: 10.1016/j.polymer.2007.12.035
69. [69]
  Ngai, K. and Plazek, D., Rubber Chem. Technol., 1995, 68(3):376 doi: 10.5254/1.3538749
70. [70]
  Kant, R., Kumar, S.K. and Colby, R.H., Macromolecules, 2003, 36(26):10087 doi: 10.1021/ma0347215
71. [71]
  Yu, W., Wang, J. and You, W., Polymer, 2016, 98:190 doi: 10.1016/j.polymer.2016.06.028
72. [72]
  Wu, S., Polymer, 1985, 26(12):1855 doi: 10.1016/0032-3861(85)90015-1
73. [73]
  Gam, S., Meth, J.S., Zane, S.G., Chi, C., Wood, B.A., Seitz, M.E., Winey, K.I., Clarke, N. and Composto, R.J., Macromolecules, 2011, 44(9):3494 doi: 10.1021/ma102463q
74. [74]
  Schneider, G., Nusser, K., Willner, L., Falus, P. and Richter, D., Macromolecules, 2011, 44(15):5857 doi: 10.1021/ma200899y
75. [75]
  Yamamoto, U. and Schweizer, K.S., J. Chem. Phys., 2011, 135(22):224902 doi: 10.1063/1.3664863
76. [76]
  ten Brinke, J., Litvinov, V., Wijnhoven, J. and Noordermeer, J., Macromolecules, 2002, 35(27):10026 doi: 10.1021/ma020555+
77. [77]
  Harton, S.E., Kumar, S.K., Yang, H., Koga, T., Hicks, K., Lee, H., Mijovic, J., Liu, M., Vallery, R.S. and Gidley, D.W., Macromolecules, 2010, 43(7):3415 doi: 10.1021/ma902484d
78. [78]
  Nauman, E.B. and He, D.Q., Chem. Eng. Sci., 2001, 56(6):1999 doi: 10.1016/S0009-2509(01)00005-7
79. [79]
  Xavier, P. and Bose, S., Phys. Chem. Chem. Phys., 2015, 17(22):14972 doi: 10.1039/C5CP01865J
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