Citation: Gao-lai Du, Yang Cong, Long Chen, Jing Chen, Jun Fu. Tough and Multi-responsive Hydrogels Based on Core-Shell Structured Macro-crosslinkers[J]. Chinese Journal of Polymer Science, ;2017, 35(10): 1286-1296. doi: 10.1007/s10118-017-1979-5 shu

Tough and Multi-responsive Hydrogels Based on Core-Shell Structured Macro-crosslinkers

Gao-lai Du ^a ,
Yang Cong ^b ,
Long Chen ^b ,
Jing Chen ^a ,
Jun Fu ^a,,

a.
Polymers and Composites Division & Cixi Institute of Biomedical Engineering, Ningbo Institution of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
b.
School of Chemical Engineering, Ningbo University of Technology, Ningbo 315201, China

Corresponding author: Jun Fu, fujun@nimte.ac.cn
Received Date: 23 April 2017
Revised Date: 11 May 2017
Accepted Date: 17 May 2017

Fund Project: the National Natural Science Foundation of China 21574145Zhejiang Natural Science Foundation of China LY17E030011

Novel hydrogels based on core-shell structured macro-crosslinkers were synthesized, which exhibited high toughness and multiple responsiveness. Sodium dodecyl sulfate (SDS) micelles mediated by NaCl were used to encapsulate hydrophobic stearyl methacrylate (C18) in the core, and hydrophilic 2-acrylamido-2-methyl-1-propanesulfonic (AMPS) monomers in the corona. Such core-shell micelles were simultaneously copolymerized with acrylamide monomers through free radical polymerization. As a result, hydrogels crosslinked by amphiphilic "poly(C18)-PAMPS" macro-crosslinkers were obtained. These hydrogels showed excellent tensile and compression strength and toughness. Cyclic compression loading-unloading tests demonstrated that the hydrogels were of outstanding fatigue resistance, and showed partial damage of energy dissipation mechanism. The damaged energy dissipation mechanism could be recovered at room temperature and the recovery could be accelerated at elevated temperatures. The hydrogels were sensitive to the change in pH and ion strength, showing reversible swelling/deswelling behaviors.
- Macro-crosslinker,
- Toughness,
- Multi-responsive,
- Hydrophobic association,
- Hydrogel
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