Citation: Xiao-ying Liu, Ming Zhong, Fu-kuan Shi, Hao Xu, Xu-ming Xie. Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties[J]. Chinese Journal of Polymer Science, ;2017, 35(10): 1253-1267. doi: 10.1007/s10118-017-1971-0 shu

Multi-bond Network Hydrogels with Robust Mechanical and Self-healable Properties

Laboratory of Advanced Materials (Ministry of Education), Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Corresponding author: Xu-ming Xie, xxm-dce@mail.tsinghua.edu.cn
Received Date: 9 April 2017
Revised Date: 5 May 2017
Accepted Date: 8 May 2017

Fund Project: State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology OIC-201601006the National Natural Science Foundation of China 51633003Tsinghua University Scientific Research Project 2014Z22069the National Natural Science Foundation of China 21474058State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University LK1404

Multi-bond network (MBN) which contains a single network with hierarchical cross-links is a suggested way to fabricate robust hydrogels. In order to reveal the roles of different cross-links with hierarchical bond energy in the MBN, here we fabricate poly(acrylic acid) physical hydrogels with dual bond network composed of ionic cross-links between carboxyl-Fe³⁺ interactions and hydrogen bonds, and compare these dually cross-linked hydrogels with singly and ternarily cross-linked hydrogels. Simple models are employed to predict the tensile property, and the results confirm that the multi-bond network with hierarchical distribution in the bond energy of cross-links endows hydrogel with effective energy-dissipating mechanism. Moreover, the dually cross-linked MBN gels exhibit excellent mechanical properties (tensile strength up to 500 kPa, elongation at break~2400%) and complete self-healing after being kept at 50℃ for 48 h. The factors on promoting self-healing are deeply explored and the dynamic multi-bonds are regarded to trigger the self-healing along with the mutual diffusion of long polymer chains and ferric ions.
- Multi-bond network hydrogels,
- Poly(acrylic acid),
- Dual cross-linking,
- Mechanical properties,
- Self-healing
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