Citation: Zi-xu Gu, Jun Cheng, Ming-zu Zhang, Jin-lin He, Pei-hong Ni. Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate[J]. Chinese Journal of Polymer Science, ;2017, 35(9): 1061-1072. doi: 10.1007/s10118-017-1966-x shu

Effect of Sequence Structure on Wetting Behaviors of Fluorinated Methacrylate Polymers Based on Perfluorohexylethyl Methacrylate and Stearyl Acrylate

College of Chemistry, Chemical Engineering and Materials Science, State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, Soochow University, Suzhou 215123, China

Corresponding author: Pei-hong Ni, phni@suda.edu.cn
Received Date: 8 March 2017
Revised Date: 18 April 2017
Accepted Date: 20 April 2017

Fund Project: the National Natural Science Foundation of China 20474041the National Natural Science Foundation of China 21374066the Natural Science Foundation of Jiangsu Province BK20151263the Major Program of the Natural Science Project of Jiangsu Higher Education Institutions 15KJA150007

Due to the non-crystalline properties of short chain perfluoroalkyl groups, using short chain perfluoroalkyl to stabilize low surface free energy polymers has been a challenging task. In this study, we prepare a series of random copolymers poly(perfluorohexylethyl methacrylate)-co-poly(stearyl acrylate) (P13FMA-co-PSA) and block copolymers poly(perfluorohexylethyl methacrylate)-b-poly(stearyl acrylate) (P13FMA-b-PSA), and systematically investigate the effects of the sequence structure and the content of 13FMA of the fluorinated copolymers on surface free energy and surface reorganization. Static/dynamic contact angle goniometry and water/oil repellency analyses demonstrate that the random polymer P13FMA-co-PSA could not achieve low surface free energy and low surface reorganization at the same time. In contrast, for the block copolymer P13FMA-b-PSA, both low surface free energy and low surface reorganization are acquired simultaneously. The results of X-ray photoelectron spectroscopy (XPS), dynamic contact angle goniometry and differential scanning calorimetry (DSC) reveal the above-mentioned properties. The consecutive 13FMA segments improve the surface fluorine density, while the consecutive SA chains enhance the crystallinity of the SA segments, and further hinder the surface reorganization of the perfluoroalkyl groups. Therefore, P13FMA-b-PSA exhibits a higher utilization efficiency of fluorine atoms and a better structural stability than P13FMA-co-PSA.
- Surface free energy,
- Surface reorganization,
- Perfluorohexylethyl methacrylate (13FMA),
- Stearyl acrylate (SA),
- Water/oil repellency
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