Citation: Jun-ying Weng, Zhuo Tang, Ying Guan, X.X. Zhu, Yong-jun Zhang. Assembly of Highly Ordered 2D Arrays of Silver-PNIPAM Hybrid Microgels[J]. Chinese Journal of Polymer Science, ;2017, 35(10): 1212-1221. doi: 10.1007/s10118-017-1962-1 shu

Assembly of Highly Ordered 2D Arrays of Silver-PNIPAM Hybrid Microgels

a.
Key Laboratory of Functional Polymer Materials and State Key Laboratory of Medicinal Chemical Biology, The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China
b.
Department of Chemistry, Université de Montréal, C. P. 6128, Succursale Centre-ville, Montreal, QC, H3C 3J7, Canada

Corresponding author: Ying Guan, yingguan@nankai.edu.cn Yong-jun Zhang, yongjunzhang@nankai.edu.cn
Received Date: 16 March 2017
Revised Date: 13 April 2017
Accepted Date: 17 April 2017

Fund Project: Tianjin Committee of Science and Technology 16JCZDJC32900the National Natural Science Foundation of China 51625302the National Natural Science Foundation of China 21374048

A strategy was developed for the synthesis of highly ordered 2D arrays of Ag-PNIPAM hybrid microgel. The highly ordered 2D arrays of PNIPAM microgel were prepared by dispersing PNIPAM microgel on a charge-reversible substrate. The microgel spheres self-assembled into a 3D colloidal crystal, and the first 111 plane was fixed in situ onto the substrate as a result of spontaneous charge reversal of the substrate, leaving a high-quality 2D array of PNIPAM microgel. Ag nanoparticles were then synthesized in situ inside the microgel spheres by introduction of Ag⁺ ions into the microgel spheres and reduction with sodium borohydride. The resulting 2D arrays are highly ordered. The inter-particle distance in the array can be tuned. In addition, the method allows the synthesis of large size arrays and the use of nonplanar substrate.
- 2D colloidal crystal,
- Microgel,
- Charge reversal,
- Self-assembly
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