Citation: Jun-ying Weng, Zhuo Tang, Ying Guan, X.X. Zhu, Yong-jun Zhang. Assembly of Highly Ordered 2D Arrays of Silver-PNIPAM Hybrid Microgels[J]. Chinese Journal of Polymer Science, ;2017, 35(10): 1212-1221. doi: 10.1007/s10118-017-1962-1 shu

Assembly of Highly Ordered 2D Arrays of Silver-PNIPAM Hybrid Microgels

a.
Key Laboratory of Functional Polymer Materials and State Key Laboratory of Medicinal Chemical Biology, The Co-Innovation Center of Chemistry and Chemical Engineering of Tianjin, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China
b.
Department of Chemistry, Université de Montréal, C. P. 6128, Succursale Centre-ville, Montreal, QC, H3C 3J7, Canada

Corresponding author: Ying Guan, yingguan@nankai.edu.cn Yong-jun Zhang, yongjunzhang@nankai.edu.cn
Received Date: 16 March 2017
Revised Date: 13 April 2017
Accepted Date: 17 April 2017

Fund Project: Tianjin Committee of Science and Technology 16JCZDJC32900the National Natural Science Foundation of China 51625302the National Natural Science Foundation of China 21374048

A strategy was developed for the synthesis of highly ordered 2D arrays of Ag-PNIPAM hybrid microgel. The highly ordered 2D arrays of PNIPAM microgel were prepared by dispersing PNIPAM microgel on a charge-reversible substrate. The microgel spheres self-assembled into a 3D colloidal crystal, and the first 111 plane was fixed in situ onto the substrate as a result of spontaneous charge reversal of the substrate, leaving a high-quality 2D array of PNIPAM microgel. Ag nanoparticles were then synthesized in situ inside the microgel spheres by introduction of Ag⁺ ions into the microgel spheres and reduction with sodium borohydride. The resulting 2D arrays are highly ordered. The inter-particle distance in the array can be tuned. In addition, the method allows the synthesis of large size arrays and the use of nonplanar substrate.
- 2D colloidal crystal,
- Microgel,
- Charge reversal,
- Self-assembly
1. [1]
  Cong, H.L., Yu, B., Tang, J.G., Li, Z.J. and Liu, X.S., Chem. Soc. Rev., 2013, 42(19):7774 doi: 10.1039/c3cs60078e
2. [2]
  Xue, F., Meng, Z.H., Wang, F.Y., Wang, Q., Xue, M. and Xu, Z.B., J. Mater. Chem. A, 2014, 2(25):9559 doi: 10.1039/C4TA01031K
3. [3]
  Ye, X.Z. and Qi, L.M., Sci. China Chem., 2014, 57(1):58 doi: 10.1007/s11426-013-5018-2
4. [4]
  Yang, S.K. and Lei, Y., Nanoscale, 2011, 3(7):2768 doi: 10.1039/c1nr10296f
5. [5]
  Zhang, J.H., Li, Y.F., Zhang, X.M. and Yang, B., Adv. Mater., 2010, 22:4249 doi: 10.1002/adma.201000755
6. [6]
  Vogel, N., Weiss, C.K. and Landfester, K., Soft Matter, 2012, 8(15):4044 doi: 10.1039/C1SM06650A
7. [7]
  Zhang, J.T., Wang, L.L., Lamont, D.N., Velankar, S.S. and Asher, S.A., Angew. Chem. Int. Ed., 2012, 51(25):6117 doi: 10.1002/anie.201105439
8. [8]
  Men, D.D., Zhang, H.H., Hang, L.F., Liu, D.L., Li, X., Cai, W.P., Xiong, Q.H. and Li, Y., J. Mater. Chem. C, 2015, 3(15):3659 doi: 10.1039/C5TC00174A
9. [9]
  Kargar, M., Pruden, A. and Ducker, W.A., J. Mater. Chem. B, 2014, 2(36):5962 doi: 10.1039/C4TB00835A
10. [10]
  Ye, R., Ye, Y.H., Zhou, Z.T. and Xu, H.H., Langmuir, 2013, 29(6):1796 doi: 10.1021/la3040227
11. [11]
  Sun, X.Y., Li, Y., Zhang, T.H., Ma, Y.Q. and Zhang, Z.X., Langmuir, 2013, 29(24):7216 doi: 10.1021/la304720h
12. [12]
  Ng, E.C.H., Chin, K.M. and Wong, C.C., Langmuir, 2011, 27(6):2244 doi: 10.1021/la104265b
13. [13]
  Born, P., Munoz, A., Cavelius, C. and Kraus, T., Langmuir, 2012, 28(22):8300 doi: 10.1021/la2048618
14. [14]
  Xue, F., Asher, S.A., Meng, Z., Wang, F.Y., Lu, W., Xue, M. and Qi, F.L., RSC Adv., 2015, 5(24):18939 doi: 10.1039/C4RA16006A
15. [15]
  Xue, F., Meng, Z.H., Qi, F.L., Xue, M. and Qiu, L., Colloid. Polym. Sci., 2016, 294(2):479 doi: 10.1007/s00396-015-3809-z
16. [16]
  Yang, H.T., Gozubenli, N., Fang, Y. and Jiang, P., Langmuir, 2013, 29(25):7674 doi: 10.1021/la4011554
17. [17]
  Jiang, P. and McFarland, M.J., J. Am. Chem. Soc., 2004, 126(42):13778 doi: 10.1021/ja0470923
18. [18]
  Zhang, G., Wang, D.Y., Gu, Z.Z., Hartmann, J. and Möhwald, H., Chem. Mater., 2005, 17(21):5268 doi: 10.1021/cm050414x
19. [19]
  Schmidt, S., Hellweg, T. and von Klitzing, R., Langmuir, 2008, 24(21):12595 doi: 10.1021/la801770n
20. [20]
  Horecha, M., Senkovskyy, V., Synytska, A., Stamm, M., Chervanyov, A.I. and Kiriy, A., Soft Matter, 2010, 6(23):5980 doi: 10.1039/c0sm00634c
21. [21]
  Pelton, R.H. and Chibante, P., Colloids Surf., 1986, 20(3):247 doi: 10.1016/0166-6622(86)80274-8
22. [22]
  Tsuji, S. and Kawaguchi, H., Langmuir, 2005, 21(18):8439 doi: 10.1021/la050271t
23. [23]
  Lu, Y. and Drechsler, M., Langmuir, 2009, 25(22):13100 doi: 10.1021/la903418m
24. [24]
  Horigome, K. and Suzuki, D., Langmuir, 2012, 28(36):12962 doi: 10.1021/la302465w
25. [25]
  Rey, B.M., Elnathan, R., Ditcovski, R., Geisel, K., Zanini, M., Fernandez-Rodriguez, M., Naik, V.V., Frutiger, A., Richtering, W., Ellenbogen, T., Voelcker, N.H. and Isa, L., Nano Lett., 2016, 16(1):157 doi: 10.1021/acs.nanolett.5b03414
26. [26]
  Quint, S.B. and Pacholski, C., Soft Matter, 2011, 7(8):3735 doi: 10.1039/c1sm05058c
27. [27]
  Geisel, K., Richtering, W. and Isa, L., Soft Matter, 2014, 10(40):7968 doi: 10.1039/C4SM01166J
28. [28]
  Vogel, N., Fernandez-Lopez, C., Perez-Juste, J., Liz-Marzan, L.M., Landfester, K. and Weiss, C.K., Langmuir, 2012, 28(24):8985 doi: 10.1021/la2051299
29. [29]
  Xia, Y.Q., He, X.L., Cao, M.W., Wang, X.J., Sun, Y.W., He, H., Xu, H. and Lu, J.R., Biomacromolecules, 2014, 15(11):4021 doi: 10.1021/bm501069w
30. [30]
  Li, X.Y., Weng, J.Y., Guan, Y. and Zhang, Y.J., Langmuir, 2016, 32(16):3977 doi: 10.1021/acs.langmuir.6b00835
31. [31]
  Weng, J.Y., Li, X.Y., Guan, Y., Zhu, J.X.X. and Zhang, Y.J., RSC Adv., 2016, 6(85):82006 doi: 10.1039/C6RA18622J
32. [32]
  Weng, J.Y., Li, X.Y., Guan, Y., Zhu, X.X. and Zhang, Y.J., Langmuir, 2016, 32(48):12876 doi: 10.1021/acs.langmuir.6b03359
33. [33]
  Hu, Z.B. and Huang, G., Angew. Chem. Int. Ed., 2003, 42(39):4799 doi: 10.1002/(ISSN)1521-3773
34. [34]
  Debord, J.D., Eustis, S., Debord, S.B., Lofye, M.T. and Lyon, L.A., Adv. Mater., 2002, 14(9):658 doi: 10.1002/(ISSN)1521-4095
35. [35]
  Chen, M., Zhou, L., Guan, Y. and Zhang, Y.J., Angew. Chem. Int. Ed., 2013, 52(38):9961 doi: 10.1002/anie.201302466
36. [36]
  Liu, Y., Guan, Y. and Zhang, Y.J., Macromol. Rapid Commun., 2014, 35(6):630 doi: 10.1002/marc.v35.6
37. [37]
  Chen, M., Zhang, Y.P., Jia, S.Y., Zhou, L., Guan, Y. and Zhang, Y.J., Angew. Chem. Int. Ed., 2015, 54(32):9257 doi: 10.1002/anie.201503004
38. [38]
  Gao, J. and Hu, Z.B., Langmuir, 2002, 18(4):1360 doi: 10.1021/la011405f
39. [39]
  Debord, J.D. and Lyon, L.A., J. Mater. Chem. B, 2000, 104(27):6327
40. [40]
  Iyer, A.S. and Lyon, L.A., Angew. Chem. Int. Ed., 2009, 48(25):4562 doi: 10.1002/anie.v48:25
41. [41]
  Hellweg, T., Angew. Chem. Int. Ed., 2009, 48(37):6777 doi: 10.1002/anie.v48:37
42. [42]
  Xu, S.Q., Zhang, J.G., Paquet, C., Lin, Y.K. and Kumacheva, E., Adv. Funct. Mater., 2003, 13(6):468 doi: 10.1002/adfm.200304338
43. [43]
  Suzuki, D., McGrath, J.G., Kawaguchi, H. and Lyon, L.A., J. Mater. Chem. C, 2007, 111(15):5667
44. [44]
  Jaber, S., Karg, M., Morfa, A. and Mulvaney, P., Phys. Chem. Chem. Phys., 2011, 13(13):5576 doi: 10.1039/c0cp02494e
45. [45]
  Karg, M. and Hellweg, T., Curr. Opin. Colloid. In., 2009, 14(6):438 doi: 10.1016/j.cocis.2009.08.002
46. [46]
  Lu, Y., Mei, Y., Drechsler, M. and Ballauff, M., Angew. Chem. Int. Ed., 2006, 45(5):813 doi: 10.1002/(ISSN)1521-3773
47. [47]
  Liu, Y.Y., Liu, X.Y., Yang, J.M., Lin, D.L., Chen, X. and Zha, L.S., Colloids Surf. A, 2012, 393:105 doi: 10.1016/j.colsurfa.2011.11.007
48. [48]
  Wu, W.T., Zhou, T., Aiello, M. and Zhou, S.Q., Biosens. Bioelectron., 2010, 38(7):1343
49. [49]
  Suzuki, D. and Kawaguchi, H., Langmuir, 2006, 22(8):3818 doi: 10.1021/la052999f
50. [50]
  Zhang, Y.P., Liu, K., Guan, Y. and Zhang, Y.J., RSC Adv., 2012, 2(11):4768 doi: 10.1039/c2ra20466e
51. [51]
  Suzuki, D. and Kawaguchi, H., Langmuir, 2006, 22(8):3818 doi: 10.1021/la052999f
52. [52]
  Zhang, J.G., Xu, S.Q. and Kumacheva, E., J. Am. Chem. Soc., 2004, 126(25):7908 doi: 10.1021/ja031523k
53. [53]
  Dong, Y., Ma, Y., Zhai, T.Y., Shen, F.G., Zeng, Y., Fu, H. and Yao, J.N., Macromol. Rapid Commun., 2007, 28(24):2339 doi: 10.1002/(ISSN)1521-3927
54. [54]
  Jones, C.D. and Lyon, L.A., Macromolecules, 2000, 33(22):8301 doi: 10.1021/ma001398m
55. [55]
  Xu, P., van Kirk, E.A., Zhan, Y., Murdoch, W.J., Radosz, M. and Shen, Y., Angew. Chem. Int. Ed., 2007, 46(26):4999 doi: 10.1002/(ISSN)1521-3773
56. [56]
  Zhang, W.J., Zhang, A.J., Guan, Y., Zhang, Y.J. and Zhu, X.X., J. Mater. Chem., 2011, 21(2):548 doi: 10.1039/C0JM02369H
57. [57]
  Zhang, W.J., Song, J., Liao, W., Guan, Y., Zhang, Y.J. and Zhu, X.X., J. Mater. Chem. C, 2013, 1(10):2036 doi: 10.1039/c3tc00415e
58. [58]
  Song, J., Hou, J.X., Tian, L.L., Guan, Y., Zhang, Y.J. and Zhu, X.X., Polymer, 2015, 63:237 doi: 10.1016/j.polymer.2015.03.009
59. [59]
  Prieto, P., Nistor, V., Nouneh, K., Oyama, M., Abd-Lefdil, M. and Díaz, R., Appl. Surf. Sci., 2012, 258(22):8807 doi: 10.1016/j.apsusc.2012.05.095
60. [60]
  Rengarajan, R., Mittleman, D., Rich, C. and Colvin, V., Phys. Rev. E, 2005, 71(1):016615 doi: 10.1103/PhysRevE.71.016615
61. [61]
  Prevo, B.G. and Velev, O.D., Langmuir, 2004, 20(6):2099 doi: 10.1021/la035295j
62. [62]
  Zhang, J., Chao, X., Liu, X. and Asher, S.A., Chem. Commun., 2013, 49(56):6337 doi: 10.1039/c3cc43396j
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