Citation: Ming-jian Jiang, Xin-yuan Li, Lei-tao Sun, Xiao-long Niu, Qiu-min Liang, Xiao-qiang Cai, Jin-chang Huang, Jun Ling, Yue-qi Mo. Special Photophysical Properties of Poly(2, 11-diquinoxalinopyrene)s[J]. Chinese Journal of Polymer Science, ;2017, 35(9): 1097-1109. doi: 10.1007/s10118-017-1961-2 shu

Special Photophysical Properties of Poly(2, 11-diquinoxalinopyrene)s

a.
College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China
b.
Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Jun Ling, lingjun@zju.edu.cn Yue-qi Mo, pomoy@scut.edu.cn
Received Date: 26 February 2017
Revised Date: 14 April 2017
Accepted Date: 17 April 2017

Fund Project: the National Natural Science Foundation of China 21174042Fund of Project on the Integration of Industry, Education and Research of Guangdong Province 2013B090500072

A diquinoxalinopyrene (DQP) derivative and the corresponding oligomers (PDQPs) with M_n of ca. 3300, 4200, 5600, and 7300 have been synthesized. It is found that the band gaps and highest occupied molecular orbital (HOMO)/lowest unoccupied molecular orbital (LUMO) levels between DQP and its homopolymers only have a slight difference, implying a limited conjugation extension achieved from unimer to heptamer. The DFT calculation is in accordance with the experimental results. It reveals that the nodal planes are across the 2, 11-positions in the LUMO and/or HOMO of DQP, dimer and trimer, which can be used to explain this special phenomenon.
- Polydiquinoxalinopyrene,
- Photophysical properties,
- Nodal
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