Citation: Wei-jia Wang, Cheng-huan Huang, Zhao-xia Guo, Jian Yu. Preparation of POE/PS Blends with Fine Particle Sizes by Diffusion and Subsequent Polymerization of Styrene in POE Pellets[J]. Chinese Journal of Polymer Science, ;2017, 35(8): 939-949. doi: 10.1007/s10118-017-1955-0 shu

Preparation of POE/PS Blends with Fine Particle Sizes by Diffusion and Subsequent Polymerization of Styrene in POE Pellets

Key Laboratory of Advanced Materials(Ministry of Education), Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Corresponding author: Zhao-xia Guo, guozx@mail.tsinghua.edu.cn Jian Yu, yujian03@mail.tsinghua.edu.cn
Received Date: 9 February 2017
Revised Date: 20 March 2017
Accepted Date: 22 March 2017

Fund Project: the National Natural Science Foundation of China 51173095

Ethylene-α-octene copolymer (POE)/polystyrene (PS) blend pellets with fine particle sizes were prepared by diffusion and subsequent polymerization of styrene in POE pellets through a one-pot procedure. The effects of the amounts of styrene and BPO on PS content, monomer efficiency and monomer conversion were investigated. The blend pellets were characterized by Micro-FTIR and FESEM, showing homogeneous diametrical distributions of PS and particle size. After melt-processing into rods, the average particle sizes are almost doubled, but still in submicron scale. Compared to neat POE rods, the blend rods with PS content higher than 15% exhibit improved tensile modulus and tensile strength without significantly losing ductility, being attributed to the small sizes, complex nature of particles and the existence of POE-g-PS copolymer that result in good interfacial adhesion. POE/PS pellets were compared with the previously reported PP/PS pellets, and the differences between the two systems are attributed to the different morphology of the two matrices:POE is completely amorphous at the diffusion and polymerization temperature, while iPP is semicrystalline. Without efficient impediment of the crystal lamellae in POE pellets, styrene diffuses easily in POE pellets.
- Blends,
- Mechanical properties,
- Nanostructured polymers,
- Polystyrene
1. [1]
  Hu, G.H., Cartier, H. and Plummer, C., Macromolecules, 1999, 32:4713 doi: 10.1021/ma981924y
2. [2]
  Su, Z.Q., Dong, M., Guo, Z.X. and Yu, J., Macromolecules, 2007, 40:4217 doi: 10.1021/ma0623587
3. [3]
  Su, Z.Q., Chen, X.N., Yu, Z.Z. and Zhang, L., J. Appl. Polym. Sci., 2009, 111:786
4. [4]
  Watkins, J.J. and McCarthy, T.J., Macromolecules, 1994, 27:4845 doi: 10.1021/ma00095a031
5. [5]
  Kung, E., Lesser, A.J. and McCarthy, T.J., Macromolecules, 1998, 31:4160 doi: 10.1021/ma980140h
6. [6]
  Li, Y.J., Iwakura, Y., Zhao, L. and Shimizu, H., Macromolecules, 2008, 41:3120 doi: 10.1021/ma7027402
7. [7]
  Shimizu, H., Li, Y.J., Kaito, A. and Sano, H., Macromolecules, 2005, 38:7880 doi: 10.1021/ma051395f
8. [8]
  Tao, Y., Kim, J. and Torkelson, J.M., Polymer, 2006, 47:6773 doi: 10.1016/j.polymer.2006.07.041
9. [9]
  Chan, S.H., Lin, Y.Y. and Ting, C., Macromolecules, 2003, 36:8910 doi: 10.1021/ma035174q
10. [10]
  Walther, A., Matussek, K. and Muller, A.H.E., ACS Nano, 2008, 2:1167 doi: 10.1021/nn800108y
11. [11]
  Kausar, A., Zulfiqar, S. and Sarwar, M.I., Polym. Adv. Technol., 2014, 25:196 doi: 10.1002/pat.v25.2
12. [12]
  Kausar, A., Zulfiqar, S. and Sarwar, M.I., J. Appl. Polym. Sci., 2014, DOI:10.1002/app.39954 doi: 10.1002/app.39954
13. [13]
  Zavareh, S. and Samandari, G., Polym. Eng. Sci., 2014, 54:1833 doi: 10.1002/pen.v54.8
14. [14]
  Chen, F., Guo, Z.X. and Yu, J., J. Appl. Polym. Sci., 2016, DOI:10.1002/app.43934 doi: 10.1002/app.43934
15. [15]
  Liu, Z.M., Dong, Z.X., Han, B.X., Wang, J.Q., He, J. and Yang, G.Y., Chem. Mater., 2002, 14:4619 doi: 10.1021/cm0203215
16. [16]
  Zhu, R., Hoshi, T., Chishima, Y., Muroga, Y., Hagiwara, T., Yano, S. and Sawaguchi, T., Macromolecules, 2011, 44:6103 doi: 10.1021/ma2001965
17. [17]
  Yao, X.R., Yu, J. and Guo, Z.X., Polymer, 2011, 52:667 doi: 10.1016/j.polymer.2010.12.050
18. [18]
  Yao, X.R., Chen, F., Guo, Z.X. and Yu, J., Chinese Chem. Lett., 2012, 23:753 doi: 10.1016/j.cclet.2012.03.031
19. [19]
  Yao, X.R., Guo, Z.X. and Yu, J., Chemical Journal of Chinese Universities (in Chinese), 2012, 33:2573
20. [20]
  Qiu, H.Y., Chen, F., Guo, Z.X. and Yu, J., Chinese J. Polym. Sci., 2015, 33(10):1380 doi: 10.1007/s10118-015-1686-z
21. [21]
  Chen, F., Guo, Z.X. and Yu, J., Chinese Chem. Lett., 2016, 27:1641 doi: 10.1016/j.cclet.2016.03.020
22. [22]
  Chen, F., Guo, Z.X. and Yu, J., J. Appl. Polym. Sci., 2016, DOI:10.1002/app.43983 doi: 10.1002/app.43983
23. [23]
  Chen, F., Yao, X.R., Guo, Z.X. and Yu, J., Acta Polymerica Sinica (in Chinese), 2016, (12):1717
24. [24]
  Huang, C.H., Chen, F., Guo, Z.X. and Yu, J., J. Appl. Polym. Sci., 2017, DOI:10.1002/app.44554 doi: 10.1002/app.44554
25. [25]
  Jiang, G.J., Wu, H. and Guo, S.Y., J. Macromol. Sci., Part B:Phys., 2007, 46:533
26. [26]
  Guo, Z.H., Tong, L.F. and Fang, Z.P., Polym. Int., 2005, 54:1647 doi: 10.1002/(ISSN)1097-0126
27. [27]
  Guo, Z.H., Tong, L.F., Xu, Z.B. and Fang, Z.P., Polym. Eng. Sci., 2007, 47:951 doi: 10.1002/(ISSN)1548-2634
28. [28]
  Guo, Z.H. and Fang, Z.P., Chemical Journal of Chinese Universities (in Chinese), 2009, 30:1898
29. [29]
  Zhou, W., Yu, W. and Zhou, C.X., Acta Polymerica Sinica (in Chinese), 2010, (6):747
30. [30]
  Huang, C.W. and Yu, W., AIChE J., 2015, 61:285 doi: 10.1002/aic.14633
31. [31]
  Jiang, G.J., Wu, H., Xie, T.T. and Guo, S.Y., J. Appl. Polym. Sci., 2009, 112:2136 doi: 10.1002/app.v112:4
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