Citation: Lin Tang, Fu-xin Liang, Qian Wang, Xiao-zhong Qu, Bing-yin Jiang, Zhen-zhong Yang. Polymer/Metal Segmental Janus Nanoparticles[J]. Chinese Journal of Polymer Science, ;2017, 35(7): 799-808. doi: 10.1007/s10118-017-1946-1 shu

Polymer/Metal Segmental Janus Nanoparticles

a.
State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Zhen-zhong Yang, rgliu@iccas.ac.cn
Received Date: 26 January 2017
Revised Date: 24 February 2017
Accepted Date: 1 March 2017

Fund Project: the National Natural Science Foundation of China 51233007the National Natural Science Foundation of China 51622308

Polymer/metal composite segmental Janus nanoparticles (NPs) are synthesized by sequential growth against poly(4-vinylpyridine) (P4VP) crosslinked cP4VP-PS Janus NPs. A Janus cluster of poly(4-vinylpyridine)-block-polystyrene (P4VP-b-PS) diblock copolymer is self-organized after absorption onto a silica patchy sphere via hydrogen bonding. Selective crosslinking of P4VP leads to the formation of robust cP4VP-PS Janus NPs. Within the cP4VP domain, functional species such as metals are preferentially grown by in situ reduction. Other thiol-capped polymers, for example, thiol-capped poly(N-isopropylacrylamide) (PNIPAM-SH), can be conjugated onto the opposite side to form polymer/metal triple segmental Janus NPs. The hyperthermia effect of Au NP of PNIPAM-Au@cP4VP-PS by near infrared (NIR) irradiation can trigger a fast transition from amphiphilic to hydrophobic of the Janus NPs at low surrounding temperature. De-stabilization of the emulsion is NIR triggered although the system temperature is below LCST (~32℃).
- Janus,
- Polymer,
- Composite,
- Nanoparticle,
- Interactive performance
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