Citation: Jing Jiang, Evgeny Zhuravlev, Wen-bing Hu, Christoph Schickc, Dong-shan Zhou. The Effect of Self-nucleation on Isothermal Crystallization Kinetics of Poly (butylene succinate)(PBS) Investigated by Differential Fast Scanning Calorimetry[J]. Chinese Journal of Polymer Science, ;2017, 35(8): 1009-1019. doi: 10.1007/s10118-017-1942-5 shu

The Effect of Self-nucleation on Isothermal Crystallization Kinetics of Poly (butylene succinate)(PBS) Investigated by Differential Fast Scanning Calorimetry

a.
Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China
b.
School of Physical Science and Technology, Xinjiang Key Laboratory and Phase Transitions and Microstructures in Condensed Matters, Yili Normal University, Yining 835000, China
c.
University of Rostock, Institute of Physics, Wismarsche Strasse 43-45, 18051 Rostock, Germany

Corresponding author: Dong-shan Zhou, dzhou@nju.edu.cn
Received Date: 30 December 2016
Revised Date: 23 January 2017
Accepted Date: 8 February 2017

Fund Project: the National Natural Science Foundation of China 21474049the National Natural Science Foundation of China 51673094the Shenzhen Science and Technology Innovation Committee JCYJ20160608140827794the National Natural Science Foundation of China 21404055the Shenzhen Science and Technology Innovation Committee JCYJ20160531151102203

Differential fast scanning calorimetry (DFSC) was employed on the study of self-nucleation behavior of poly(butylene succinate) (PBS). The ultra-fast cooling ability of DFSC allows investigating the effect of self-nucleation on the isothermal crystallization kinetics over a wide temperature range. Crystallization half-time, instead of crystallization peak temperature, was used to describe the self-nucleation behavior, and the self-nucleation domain for the samples crystallized at different temperatures was determined. Due to the competition between homogenous nucleation and self-nuclei, the effect of self-nucleation was less pronounced at high supercooling than that for the sample isothermally crystallized at higher temperature. An efficiency scale to judge the efficiency of nucleating agents from the crystallization half-time was also introduced in this work.
- Self-nucleation,
- Differential scanning calorimetry,
- Fast scanning calorimetry,
- Nucleation efficiency,
- Poly (butylene succinate)
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