Citation: Sheng-tong Sun, Pei-yi Wu. Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy[J]. Chinese Journal of Polymer Science, ;2017, 35(6): 700-712. doi: 10.1007/s10118-017-1938-1 shu

Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy

Sheng-tong Sun ^a,, ,
Pei-yi Wu ^b,,

a.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Chemistry, Chemical Engineering and Biotechnology, Center for Advanced Low-Dimension Materials, Donghua University, Shanghai 201620, China
b.
State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Polymers and Polymer Composite Materials, Department of Macromolecular Science and Laboratory for Advanced Materials, Fudan University, Shanghai 200433, China

Corresponding author: Sheng-tong Sun, shengtongsun@gmail.com Pei-yi Wu, peiyiwu@fudan.edu.cn
Received Date: 16 December 2016
Revised Date: 9 February 2017
Accepted Date: 17 February 2017

Fund Project: the Natural Science Foundation of Shanghai 17ZR1440400the Open Project of State Key Laboratory of Chemical Engineering SKL-ChE-16C02financially supported by the National Natural Science Foundation of China 21604024financially supported by the National Natural Science Foundation of China 51473038financially supported by the National Natural Science Foundation of China 21274030

Generalized two-dimensional correlation spectroscopy (2DCOS) and its derivate technique, perturbation correlation moving window (PCMW), have found great potential in studying a series of physico-chemical phenomena in stimuli-responsive polymeric systems. By spreading peaks along a second dimension, 2DCOS can significantly enhance spectral resolution and discern the sequence of group dynamics applicable to various external perturbation-induced spectroscopic changes, especially in infrared (IR), near-infrared (NIR) and Raman spectroscopy. On the basis of 2DCOS synchronous power spectra changing, PCMW proves to be a powerful tool to monitor complicated spectral variations and to find transition points and ranges. This article reviews the recent work of our research group in the application of 2DCOS and PCMW in thermoresponsive polymers, mainly focused on liquid crystalline polymers and lower critical solution temperature (LCST)-type polymers. Details of group motions and chain conformational changes upon temperature perturbation can thus be elucidated at the molecular level, which contribute to the understanding of their phase transition nature.
- Thermoresponsive polymers,
- Phase transition,
- Two-dimensional correlation spectroscopy,
- Perturbation correlation moving window
1. [1]
  Noda, I., Bull. Am. Phys. Soc., 1986, 31: 520
2. [2]
  Noda, I., Appl. Spectrosc., 1993, 47(9): 1329 doi: 10.1366/0003702934067694
3. [3]
  Noda, I. and Ozaki, Y., "Two-dimensional correlation spectroscopy: Applications in vibrational and optical spectroscopy", Chichester: Wiley, 2004
4. [4]
  Park, Y., Noda, I. and Jung, Y.M., J. Mol. Struct., 2016, 1124: 11 doi: 10.1016/j.molstruc.2016.01.028
5. [5]
  Czarnecki, M.A., Appl. Spectrosc. Rev., 2011, 46(1): 67 doi: 10.1080/05704928.2010.503529
6. [6]
  Dluhy, R., Shanmukh, S. and Morita, S.I., Surf. Interface Anal., 2006, 38(11): 1481 doi: 10.1002/(ISSN)1096-9918
7. [7]
  You, Z., Zhuo, L., Yang, X., Hong, H., Liu, Z., Gong, Z. and Cheng, F., Appl. Spectrosc. Rev., 2015, 50(10): 840 doi: 10.1080/05704928.2015.1087402
8. [8]
  Shashilov, V.A. and Lednev, I.K., J. Raman Spectrosc., 2009, 40(12): 1749 doi: 10.1002/jrs.v40:12
9. [9]
  Stuart, M.A.C., Huck, W.T.S., Genzer, J., Muller, M., Ober, C., Stamm, M., Sukhorukov, G.B., Szleifer, I., Tsukruk, V.V., Urban, M., Winnik, F., Zauscher, S., Luzinov, I. and Minko, S., Nat. Mater., 2010, 9(2): 101 doi: 10.1038/nmat2614
10. [10]
  Roy, D., Brooks, W.L.A. and Sumerlin, B.S., Chem. Soc. Rev., 2013, 42(17): 7214 doi: 10.1039/c3cs35499g
11. [11]
  Morita, S., Shinzawa, H., Tsenkova, R., Noda, I. and Ozaki, Y., J. Mol. Struct., 2006, 799(1): 111
12. [12]
  Czarnik-Matusewicz, B., Pilorz, S., Ashton, L. and Blanch, E.W., J. Mol. Struct., 2006, 799(1-3): 253 doi: 10.1016/j.molstruc.2006.03.064
13. [13]
  Sun, S., Tang, H. and Wu, P., Phys. Chem. Chem. Phys., 2009, 11(35): 7611 doi: 10.1039/b906773f
14. [14]
  Sun, S.T., Tang, H., Wu, P.Y. and Wan, X.H., Phys. Chem. Chem. Phys., 2009, 11(42): 9861 doi: 10.1039/b909914j
15. [15]
  Thomas, M. and Richardson, H.H., Vib. Spectrosc., 2000, 24(1): 137 doi: 10.1016/S0924-2031(00)00086-2
16. [16]
  Morita, S., Shinzawa, H., Noda, I. and Ozaki, Y., Appl. Spectrosc., 2006, 60(4): 398 doi: 10.1366/000370206776593690
17. [17]
  Wang, M.Y., Sun, S.T. and Wu, P.Y., Appl. Spectrosc., 2010, 64(12): 1396 doi: 10.1366/000370210793561529
18. [18]
  Czarnecki, M.A., Okretic, S. and Siesler, H.W., J. Phys. Chem. B, 1997, 101(3): 374 doi: 10.1021/jp961588s
19. [19]
  Czarnecki, M.A., Okretic, S. and Siesler, H.W., Vib. Spectrosc., 1998, 18(1): 17 doi: 10.1016/S0924-2031(98)00036-8
20. [20]
  Chen, X.F., Shen, Z., Wan, X.H., Fan, X.H., Chen, E.Q., Ma, Y. and Zhou, Q.F., Chem. Soc. Rev., 2010, 39(8): 3072 doi: 10.1039/b814540g
21. [21]
  Shen, Y., Chen, E.Q., Ye, C., Zhang, H.L., Wu, P.Y., Noda, I. and Zhou, Q.F., J. Phys. Chem. B, 2005, 109(13): 6089 doi: 10.1021/jp045014w
22. [22]
  Jing, Y., Tang, H. and Wu, P., Polym. Chem., 2013, 4(24): 5768 doi: 10.1039/c3py00764b
23. [23]
  Sun, S.T., Tang, H. and Wu, P.Y., J. Phys. Chem. B, 2010, 114(10): 3439 doi: 10.1021/jp908951c
24. [24]
  Tang, H., Sun, S.T., Wu, J.W., Wu, P.Y. and Wan, X.H., Polymer, 2010, 51(23): 5482 doi: 10.1016/j.polymer.2010.09.036
25. [25]
  Schild, H.G., Prog. Polym. Sci., 1992, 17(2): 163 doi: 10.1016/0079-6700(92)90023-R
26. [26]
  Sun, B., Lin, Y., Wu, P. and Siesler, H.W., Macromolecules, 2008, 41(4): 1512 doi: 10.1021/ma702062h
27. [27]
  Lai, H.J. and Wu, P.Y., Polymer, 2010, 51(6): 1404 doi: 10.1016/j.polymer.2010.01.036
28. [28]
  Sun, S.T. and Wu, P.Y., Macromolecules, 2010, 43(22): 9501 doi: 10.1021/ma1016693
29. [29]
  Wang, Z.W. and Wu, P.Y., RSC Adv., 2012, 2(18): 7099 doi: 10.1039/c2ra01349e
30. [30]
  Sun, S. and Wu, P., Macromolecules, 2013, 46(1): 236 doi: 10.1021/ma3022376
31. [31]
  Zhang, B., Tang, H. and Wu, P., Macromolecules, 2014, 47(14): 4728 doi: 10.1021/ma500774g
32. [32]
  Gu, W.X. and Wu, P.Y., Anal. Sci., 2007, 23(7): 823 doi: 10.2116/analsci.23.823
33. [33]
  Guo, Y., Sun, B. and Wu, P., Langmuir, 2008, 24(10): 5521 doi: 10.1021/la7038398
34. [34]
  Sun, B.J., Lai, H.J. and Wu, P.Y., J. Phys. Chem. B, 2011, 115(6): 1335 doi: 10.1021/jp1066007
35. [35]
  Sun, S. and Wu, P., J. Phys. Chem. B, 2011, 115(40): 11609 doi: 10.1021/jp2071056
36. [36]
  Li, T., Tang, H. and Wu, P., Langmuir, 2015, 31(24): 6870 doi: 10.1021/acs.langmuir.5b01009
37. [37]
  Li, W. and Wu, P., Polym. Chem., 2014, 5(19): 5578 doi: 10.1039/C4PY00593G
38. [38]
  Wang, G. and Wu, P., Soft Matter, 2015, 11(26): 5253 doi: 10.1039/C5SM00603A
39. [39]
  Lai, H.J., Chen, G.T., Wu, P.Y. and Li, Z.C., Soft Matter, 2012, 8(9): 2662 doi: 10.1039/c2sm06779j
40. [40]
  Sun, S.T., Zhang, W.D., Zhang, W., Wu, P.Y. and Zhu, X.L., Soft Matter, 2012, 8(14): 3980 doi: 10.1039/c2sm06908c
41. [41]
  Wang, Z., Lai, H. and Wu, P., Soft Matter, 2012, 8(46): 11644 doi: 10.1039/c2sm26172c
42. [42]
  Wang, Q., Tang, H. and Wu, P., Langmuir, 2015, 31(23): 6497 doi: 10.1021/acs.langmuir.5b00878
43. [43]
  Dai, Y. and Wu, P., Phys. Chem. Chem. Phys., 2016, 18(31): 21360 doi: 10.1039/C6CP04286D
44. [44]
  Wang, Q., Tang, H. and Wu, P., J. Polym. Sci., Part B: Polym. Phys., 2016, 54(3): 385 doi: 10.1002/polb.v54.3
45. [45]
  Jia, L., Guo, C., Yang, L., Xiang, J., Tang, Y., Liu, C. and Liu, H., J. Colloid Interf. Sci., 2010, 345(2): 332 doi: 10.1016/j.jcis.2010.01.060
46. [46]
  Ye, Z., Li, Y., An, Z. and Wu, P., Langmuir, 2016, 32(26): 6691 doi: 10.1021/acs.langmuir.6b01785
47. [47]
  Li, T., Tang, H. and Wu, P., Soft Matter, 2015, 11(15): 3046 doi: 10.1039/C5SM00186B
48. [48]
  Wang, G. and Wu, P., Langmuir, 2016, 32(15): 3728 doi: 10.1021/acs.langmuir.6b00392
49. [49]
  Wang, G. and Wu, P., Soft Matter, 2016, 12(3): 925 doi: 10.1039/C5SM02032H
50. [50]
  Motornov, M., Roiter, Y., Tokarev, I. and Minko, S., Prog. Polym. Sci., 2010, 35(1-2): 174 doi: 10.1016/j.progpolymsci.2009.10.004
51. [51]
  Sun, S., Hu, J., Tang, H. and Wu, P., J. Phys. Chem. B, 2010, 114(30): 9761 doi: 10.1021/jp103818c
52. [52]
  Sun, S., Hu, J., Tang, H. and Wu, P., Phys. Chem. Chem. Phys., 2011, 13(11): 5061 doi: 10.1039/c0cp01939a
53. [53]
  Hou, L., Ma, K., An, Z. and Wu, P., Macromolecules, 2014, 47(3): 1144 doi: 10.1021/ma4021906
54. [54]
  Zhang, B., Sun, S. and Wu, P., Soft Matter, 2013, 9(5): 1678 doi: 10.1039/C2SM27355A
55. [55]
  Zhou, Y., Tang, H. and Wu, P., Phys. Chem. Chem. Phys., 2015, 17(38): 25525 doi: 10.1039/C5CP03676C
56. [56]
  Hou, L. and Wu, P., RSC Adv., 2014, 4(74): 39231 doi: 10.1039/C4RA06471B
57. [57]
  Sun, W. and Wu, P., Phys. Chem. Chem. Phys., 2017, 19(1): 127 doi: 10.1039/C6CP06862F
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3. [3]
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