Citation: Sheng-tong Sun, Pei-yi Wu. Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy[J]. Chinese Journal of Polymer Science, ;2017, 35(6): 700-712. doi: 10.1007/s10118-017-1938-1 shu

Spectral Insights into Microdynamics of Thermoresponsive Polymers from the Perspective of Two-dimensional Correlation Spectroscopy

Sheng-tong Sun ^a,, ,
Pei-yi Wu ^b,,

a.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Chemistry, Chemical Engineering and Biotechnology, Center for Advanced Low-Dimension Materials, Donghua University, Shanghai 201620, China
b.
State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Polymers and Polymer Composite Materials, Department of Macromolecular Science and Laboratory for Advanced Materials, Fudan University, Shanghai 200433, China

Corresponding author: Sheng-tong Sun, shengtongsun@gmail.com Pei-yi Wu, peiyiwu@fudan.edu.cn
Received Date: 16 December 2016
Revised Date: 9 February 2017
Accepted Date: 17 February 2017

Fund Project: the Natural Science Foundation of Shanghai 17ZR1440400the Open Project of State Key Laboratory of Chemical Engineering SKL-ChE-16C02financially supported by the National Natural Science Foundation of China 21604024financially supported by the National Natural Science Foundation of China 51473038financially supported by the National Natural Science Foundation of China 21274030

Generalized two-dimensional correlation spectroscopy (2DCOS) and its derivate technique, perturbation correlation moving window (PCMW), have found great potential in studying a series of physico-chemical phenomena in stimuli-responsive polymeric systems. By spreading peaks along a second dimension, 2DCOS can significantly enhance spectral resolution and discern the sequence of group dynamics applicable to various external perturbation-induced spectroscopic changes, especially in infrared (IR), near-infrared (NIR) and Raman spectroscopy. On the basis of 2DCOS synchronous power spectra changing, PCMW proves to be a powerful tool to monitor complicated spectral variations and to find transition points and ranges. This article reviews the recent work of our research group in the application of 2DCOS and PCMW in thermoresponsive polymers, mainly focused on liquid crystalline polymers and lower critical solution temperature (LCST)-type polymers. Details of group motions and chain conformational changes upon temperature perturbation can thus be elucidated at the molecular level, which contribute to the understanding of their phase transition nature.
- Thermoresponsive polymers,
- Phase transition,
- Two-dimensional correlation spectroscopy,
- Perturbation correlation moving window
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