Citation: Xue Wei, Cong Lv, Yao Jing, Feng Chen, Qiang Fu. Fabrication of Electrospun PVDF Nanofibers with Higher Content of Polar β Phase and Smaller Diameter by Adding a Small Amount of Dioctadecyl Dimethyl Ammonium Chloride[J]. Chinese Journal of Polymer Science, ;2017, 35(8): 992-1000. doi: 10.1007/s10118-017-1937-2 shu

Fabrication of Electrospun PVDF Nanofibers with Higher Content of Polar β Phase and Smaller Diameter by Adding a Small Amount of Dioctadecyl Dimethyl Ammonium Chloride

College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China

Corresponding author: Feng Chen, fengchen@scu.edu.cn Qiang Fu, qiangfu@scu.edu.cn
Received Date: 27 December 2016
Revised Date: 23 January 2017
Accepted Date: 2 February 2017

Fund Project: the National Natural Science Foundation of China 51210005the National Natural Science Foundation of China 51421061

In this work, the effect of dioctadecyl dimethyl ammonium chloride (DDAC, a kind of alkyl ammonium salt) on polar β phase content and the diameter of electrospun PVDF nanofibers was investigated for the first time. Our experimental results show that the diameter of the electrospun PVDF nanofiber could be largely reduced and the content of polar β phase also become dominant immediately by just adding a little amount of DDAC. When the mass fraction of DDAC reached 4%, the content of polar β phase increased by about 39.1% compared with PVDF nanofibers without DDAC. Besides, the crystallinity of PVDF nanofibers also increased with the addition of DDAC. Based on the results, the possible mechanism of cooperative effect between electrospinning and DDAC on fiber diameter and formation of β phase in PVDF was discussed.
- Poly (vinylidene fluoride),
- Electrospinning,
- Dioctadecyl dimethyl ammonium chloride,
- Polymorphism
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