Citation: He-xin Zhang, Seong-Rok Huh, Eun-Bin Ko, Byung-Sik Park, Keun-Byoung Yoon. Isothermal-crystallization Kinetics and Spherulite Growth of Aliphatic Polyketone/Polyamide-6 Blends[J]. Chinese Journal of Polymer Science, ;2017, 35(6): 782-792. doi: 10.1007/s10118-017-1936-3 shu

Isothermal-crystallization Kinetics and Spherulite Growth of Aliphatic Polyketone/Polyamide-6 Blends

a.
Department of Polymer Science and Engineering, Kyungpook National University, Korea
b.
Key Laboratory of Synthetic Rubber, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
c.
Department of Pharmaceutical Engineering, International University of Korea, Jinju, Korea

Corresponding author: Keun-Byoung Yoon, kbyoon@knu.ac.kr
Received Date: 17 December 2016
Revised Date: 28 December 2016
Accepted Date: 23 January 2017

In this research, the morphologies, isothermal-crystallization kinetics, and spherulite growth of aliphatic polyketone/polyamide-6 blends were studied. A single glass-transition temperature (T_g) was determined, and the composition dependence of T_g for these blends was well described by the Kwei equation. The strong intermolecular interaction between the two polymer components was confirmed by melting-point depression. The isothermal-crystallization kinetics were analyzed on the basis of the Avrami approach. A linear increase in the radii of the spherulites with time was observed for all compositions. All the spherulites continued to grow at nearly identical growth rates. With increasing polyamide-6 content, the size of the spherulites in the polyketone/polyamide-6 blends gradually decreased, and the number of spherulites in the blends increased.
- Polyketone,
- Polyamide-6,
- Crystallization kinetics,
- Spherulite growth
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1.
沈阳化工大学材料科学与工程学院沈阳 110142