Citation: Xiao-min Kang, Wan-hao Cai, Hong-gang Gu, Shi-yuan Liu, Shu-xun Cui. A Facile and Environment-friendly Method for Fabrication of Polymer Brush[J]. Chinese Journal of Polymer Science, ;2017, 35(7): 857-865. doi: 10.1007/s10118-017-1934-5 shu

A Facile and Environment-friendly Method for Fabrication of Polymer Brush

a.
Key Laboratory of Advanced Technologies of Materials, Ministry of Education, Southwest Jiaotong University, Chengdu 610031, China
b.
State Key Laboratory of Digital Manufacturing Equipment and Technology, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding author: Shu-xun Cui, cuishuxun@swjtu.edu.cn
Received Date: 12 December 2016
Revised Date: 12 January 2017
Accepted Date: 14 January 2017

Fund Project: the National Natural Science Foundation of China No. 21222401the Sichuan Youth Science & Technology Foundation No. 2017JQ0009

A novel environment-friendly system is proposed to fabricate polymer brush, which has the advantages including non-toxic and inexpensive initiator (eosin Y), visible-light exposure (λ= 515 nm), water medium and ambient environment. The experimental results from UV-Vis spectroscopy, AFM-based single molecule force spectroscopy (SMFS) and other measurements indicate that a polymer brush with a living nature is fabricated via free radical polymerization. This polymer brush may find applications in coatings, bio-interfaces and so forth.
- Polymer brush,
- Green chemistry,
- Free radical polymerization,
- Living polymerization
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