Citation: Hua-qing Liang, Qi-hua Zhou, Yong-jiang Long, Wan-chu Wei, Guo-dong Liang, Qing Wu, Hai-yang Gao, Fang-ming Zhu. Synthesis of Isotactic Polystyrene-block-Polyethylene by the Combination of Sequential Monomer Addition and Hydrogenation of 1, 4-Trans-polybutadiene Block[J]. Chinese Journal of Polymer Science, ;2017, 35(7): 866-873. doi: 10.1007/s10118-017-1933-6 shu

Synthesis of Isotactic Polystyrene-block-Polyethylene by the Combination of Sequential Monomer Addition and Hydrogenation of 1, 4-Trans-polybutadiene Block

a.
Guangdong Provincial Key Laboratory for High Performance Polymeric Composites, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
b.
Key Laboratory for Polymer Composite and Functional Materials of Ministry of Education, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China

Corresponding author: Fang-ming Zhu, ceszfm@mail.sysu.edu.cn
Received Date: 7 December 2016
Revised Date: 3 January 2017
Accepted Date: 14 January 2017

Fund Project: the National Natural Science Foundation of China 51573212the Natural Science Foundation of Guangdong Province Nos. S2013030013474the Natural Science Foundation of Guangdong Province 2014A030313178the National Natural Science Foundation of China Nos. 21174167

Herein, we demonstrate the synthesis of a well-defined diblock copolymer consisting of isotactic polystyrene (iPS) and linear polyethylene, isotactic polystyrene-block-polyethylene (iPS-b-PE), by the combination of sequential monomer addition and hydrogenation. Isospecific living polymerization of styrene and living trans-1,4-polymerization of 1,3-butadiene were catalyzed by 1,4-dithiabutandiyl-2,2′-bis(6-cumenyl-4-methylphenoxy) titanium dichloride (complex 1) activated by triisobutyl aluminum modified methylaluminoxane (MMAO) at room temperature to provide highly isotactic polystyrene (iPS) and 1,4-trans-polybutadiene (1,4-trans-PBD) with narrow molecular weight distribution. Furthermore, the iPS-b-1,4-trans-PBD was synthesized via sequential monomer addition in the presence of complex 1 and MMAO. The hydrogenation of the 1,4-trans-PBD block was promoted by RuCl₂(PPh₃)₃ used as a catalyst to produce iPS-b-PE.
- Isotactic polystyrene,
- 1, 4-Trans-polybutadiene,
- Linear polyethylene,
- Diblock copolymer,
- Sequential monomer addition,
- Hydrogenation
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