Citation: Bo Dong, Rui Zhuang, Chun-yu Zhang, Wen-jie Zheng, He-xin Zhang, Yan-ming Hu, Guang-ping Sun, Xue-quan Zhang. Living Polymerization of 1, 3-Butadiene Catalyzed by Half-titanocene Complex Bearing Dibenzhydryl-substituted Aryloxide Ligand[J]. Chinese Journal of Polymer Science, ;2017, 35(6): 721-727. doi: 10.1007/s10118-017-1923-8 shu

Living Polymerization of 1, 3-Butadiene Catalyzed by Half-titanocene Complex Bearing Dibenzhydryl-substituted Aryloxide Ligand

a.
College of Materials Science and Engineering, Jilin University, Changchun 130022, China
b.
Key Laboratory of Synthetic Rubber, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: Guang-ping Sun, sungp@jlu.edu.cn Xue-quan Zhang, xqzhang@ciac.ac.cn
Received Date: 30 October 2016
Revised Date: 30 November 2016
Accepted Date: 20 December 2016

Fund Project: financially supported by the National Basic Research Program of China 2015CB654700the National Key Technology R & D Program 2014BAE14B00the National Natural Science Foundation of China U1462124

Half-titanocene complexes bearing dibenzhydryl-substituted aryloxide ligands (2a-2d) were prepared. Among them, 2c adopted a three-legged distorted tetrahedral geometry evidenced by X-ray crystallography. The poly-1, 3-butadiene with high molecular weight and narrow molecular weight distribution was obtained by using these complexes as the catalysts activated with methylaluminoxane (MAO). The catalytic activities of the complexes depended on their structures. The Ti―O―C bond in the complexes with large angle afforded them with higher activity, while Cp*-based complexes exhibited lower activities than the Cp-based analogues. The activity of complex increased with increasing the polymerization temperature while the selectivity remained no change, indicating the high thermal stability. Furthermore, the polymerization of 1, 3-butadiene catalyzed by 2a/MAO at 0 ℃ has been found in a living fashion.
- Half-titanocene complexes,
- 1, 3-Butadiene,
- Thermal stability,
- Living polymerization
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1.
沈阳化工大学材料科学与工程学院沈阳 110142