Citation: Zhi-lin Hou, Tong Huang, Cai-yun Cai, Tahir Resheed, Chun-yang Yu, Yong-feng Zhou, De-yue Yan. Polymer Vesicle Sensor through the Self-assembly of Hyperbranched Polymeric Ionic Liquids for the Detection of SO₂ Derivatives[J]. Chinese Journal of Polymer Science, ;2017, 35(5): 602-610. doi: 10.1007/s10118-017-1921-x shu

Polymer Vesicle Sensor through the Self-assembly of Hyperbranched Polymeric Ionic Liquids for the Detection of SO₂ Derivatives

a.
School of Chemistry and Chemical Engineering, Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, Shanghai Jiao Tong University, Shanghai 200240, China
b.
State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China

Corresponding author: Chun-yang Yu, chunyangyu@sjtu.edu.cn
Received Date: 6 November 2016
Revised Date: 3 December 2016
Accepted Date: 8 December 2016

Fund Project: Program of Shanghai Subject Chief Scientist 15XD1502400the National Natural Science Foundation of China 91127047the National Natural Science Foundation of China 21474062the National Natural Science Foundation of China 21404070the National Science Fund for Distinguished Young Scholars 21225420This work was financially supported by the National Basic Research Program 2013CB834506

This work reports a SO₂ derivative-detecting and colorful hyperbranched polymeric ionic liquid (HBPIL) vesicle through aqueous self-assembly. By a simple anion-exchange, we achieved the combination of functional small-molecule probe of acid fuchsin with HBPILs. The obtained HBPIL vesicle displayed ultraviolet absorption at 544 nm, and was used as a novel SO₂ derivative sensor with high sensitivity and visualization. Due to the functional ion pairs enriching on the surface, the SO₃^2- detection limit of the HBPILs vesicles was as low as 0.138 μmol/L, which was about 1.5 orders of magnitude lower than that of acid fuchsin.
- SO₂,
- Self-assembly,
- Polymeric ionic liquids,
- Vesicles
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Polymer Vesicle Sensor through the Self-assembly of Hyperbranched Polymeric Ionic Liquids for the Detection of SO2 Derivatives

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通讯作者: 陈斌, bchen63@163.com

Polymer Vesicle Sensor through the Self-assembly of Hyperbranched Polymeric Ionic Liquids for the Detection of SO₂ Derivatives