Citation: Rong Liang, Yi-chun Chen, Chun-qiu Zhang, Jing Yin, Xue-lei Liu, Lu-kai Wang, Rui Kong, Xin Feng, Jin-jun Yang. Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate[J]. Chinese Journal of Polymer Science, ;2017, 35(4): 558-568. doi: 10.1007/s10118-017-1917-6 shu

Crystallization Behavior of Biodegradable Poly (ethylene adipate) Modulated by a Benign Nucleating Agent: Zinc Phenylphosphonate

Rong Liang ^a,† ,
Yi-chun Chen ^a,† ,
Chun-qiu Zhang ^b ,
Jing Yin ^a ,
Xue-lei Liu ^a ,
Lu-kai Wang ^a ,
Rui Kong ^a ,
Xin Feng ^a ,
Jin-jun Yang ^a,,

a.
School of Environmental Science and Safety Engineering, Tianjin University of Technology, Tianjin 300384, China
b.
School of Mechanical Engineering, Tianjin University of Technology, Tianjin 300384, China

Corresponding author: Jin-jun Yang, tjyjj_2014@tjut.edu.cn

^†

Received Date: 3 September 2016
Revised Date: 9 October 2016
Accepted Date: 11 October 2016

Fund Project: Natural Science Foundation of Tianjin City 15JCYBJC47300the National Natural Science Foundation of China 21304070Major Program of National Natural Science Foundation of China 11432016the Municipal Key Program of Natural Science Foundation of Tianjin 14JCZDJC40700

Zinc phenylphosphonate (PPZn), a benign and biocompatible nucleating agent, was prepared and incorporated into the biodegradable poly (ethylene adipate) (PEA) to investigate its effect on the crystallization behavior, crystallization kinetics and spherulite morphology of PEA. Upon addition of PPZn, the crystallization temperature and crystallinity of PEA in the non-isothermal crystallization process increased significantly. Analysis of crystallization kinetics by Avrami equation suggests that the crystallization time shortened greatly and crystallization rate increased markedly after addition of PPZn. In the presence of PPZn, the spherulite size decreased and spherulite density increased significantly. It suggests that PPZn is an efficient nucleating agent for the crystallization of PEA. The accelerated crystallization in the presence of PPZn is mainly attributed to the epitaxial nucleation of PEA crystals on the surface of PPZn crystals, that is, a perfect lattice matching between PEA crystal and PPZn crystal occurs.
- Crystallization kinetics,
- Epitaxial growth,
- Poly (ethylene adipate),
- Nucleating agent
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