Citation: Kun-yuan Luo, Zheng-zhong Shao. A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities[J]. Chinese Journal of Polymer Science, ;2017, 35(4): 515-523. doi: 10.1007/s10118-017-1910-0 shu

A Novel Regenerated Silk Fibroin-based Hydrogels with Magnetic and Catalytic Activities

Kun-yuan Luo ,
Zheng-zhong Shao ^,

State Key Laboratory of Molecular Engineering of Polymers, Laboratory of Advanced Materials and Department of Macromolecular Science, Fudan University, Shanghai 200433, China

Corresponding author: Zheng-zhong Shao, zzshao@fudan.edu.cn
Received Date: 7 September 2016
Revised Date: 10 October 2016
Accepted Date: 11 October 2016

Fund Project: the National Natural Science Foundation of China 21574024

A simple and facile synthetic methodology for fabricating the regenerated silk fibroin (RSF)-based hydrogel which consisted of the in situ generated magnetic ferriferous oxide (Fe₃O₄) was developed. Using the co-precipitation of Fe²⁺ and Fe³⁺ within the RSF-based hydrogel with 90% RSF and 10% HPMC (hydroxypropyl methyl cellulose), the as-prepared RSF/Fe₃O₄ hydrogel not only showed high strength of saturation magnetization, but also exhibited excellent catalytic activities. For example, with the assistant of 3, 3', 5, 5'-tetramethylbenzidine (TMB), the RSF/Fe₃O₄ hydrogel could detect H₂O₂ at a concentration as low as 1×10^-6 mol·L^-1. In addition, the catalytic activities were able to be maintained for a long term under various conditions. These findings suggest that the RSF-based materials can be endowed with interesting properties, and have great potential for the applications in the fields of biotechnology and environmental chemistry.
- Natural polymer,
- Silk,
- Hydrogel,
- Nanoparticle,
- Magnetic and catalytic activity
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