Citation: Sheng-li Chen, Peng-fei Shi, Wang-qing Zhang. In Situ Synthesis of Block Copolymer Nano-assemblies by Polymerization-induced Self-assembly under Heterogeneous Condition[J]. Chinese Journal of Polymer Science, ;2017, 35(4): 455-479. doi: 10.1007/s10118-017-1907-8 shu

In Situ Synthesis of Block Copolymer Nano-assemblies by Polymerization-induced Self-assembly under Heterogeneous Condition

a.
Key Laboratory of Functional Polymer Materials of the Ministry of Education, Institute of Polymer Chemistry, Nankai University, Tianjin 300071, China
b.
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China

Corresponding author: Wang-qing Zhang, wqzhang@nankai.edu.cn
Received Date: 26 October 2016
Revised Date: 19 November 2016
Accepted Date: 20 November 2016

Fund Project: the National Natural Science Foundation of China 21474054the National Science Foundation for Distinguished Young Scholars 21525419the National Natural Science Foundation of China 21274066the National Key Research and Development Program of China 2016YFA0202503

Controlled synthesis of amphiphilic block copolymer nanoparticles in a convenient way is an important and interest topic in polymer science. In this review, three formulations of polymerization-induced self-assembly to in situ synthesize block copolymer nanoparticles are briefly introduced, which perform by reversible addition-fragmentation chain transfer (RAFT) polymerization under heterogeneous conditions, e.g., aqueous emulsion RAFT polymerization, dispersion RAFT polymerization and especially the recently proposed seeded RAFT polymerization. The latest developments in several selected areas on the synthesis of block copolymer nano-assemblies are highlighted.
- Block copolymers,
- Self-assembly,
- Emulsion RAFT polymerization,
- Dispersion RAFT polymerization,
- Seeded RAFT polymerization
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