Citation: Prabakaran Pradeepa, Prabhu Manimuthu Ramesh, Gurusamy Sowmya, Sebasthiyan Edwinraj. Plasticized Polymer Electrolyte Membranes Based on PEO/PVdF-HFP for Use as an Effective Electrolyte in Lithium-ion Batteries[J]. Chinese Journal of Polymer Science, ;2017, 35(3): 407-421. doi: 10.1007/s10118-017-1906-9 shu

Plasticized Polymer Electrolyte Membranes Based on PEO/PVdF-HFP for Use as an Effective Electrolyte in Lithium-ion Batteries

School of Physics, Alagappa University, Karaikudi-630 004, Tamil Nadu, India

Corresponding author: Prabhu Manimuthu Ramesh, mkram83@gmail.com
Received Date: 5 July 2016
Revised Date: 14 October 2016
Accepted Date: 18 October 2016

Fund Project: This work was financially supported by the UGC-BSR, New Delhi, India

Plasticized polymer electrolytes were prepared using poly(ethylene oxide) (PEO)/poly(vinylidene fluoridehexafluoro propylene) (PVdF-HFP) with lithium perchlorate (LiClO₄) and different plasticizers. XRD and FTIR spectroscopic techniques were used to characterize the structure and the complexation of plasticizer with the host polymer matrix. The role of interaction between polymer hosts and plasticizer on conductivity is discussed using the results of alternating current (a.c.) impedance studies. TG-DTA and SEM were used for thermal and physical characterizations. Maximum ionic conductivity (3.26×10^-4 S·cm^-1) has been observed for ethylene carbonate (EC)-based polymer electrolytes. Electrochemical performance of the plasticized polymer electrolyte is evaluated in LiFePO₄/plasticized polymer electrolytes (PPEs)/Li coin cell. Good performance with low capacity fading on charge discharge cycling is demonstrated.
- X-ray diffraction,
- Impedance spectroscopy,
- Atomic force microscopy,
- Ionic conductivity,
- Dielectrics
References
1. [1]
  van Vliet, O., Brouwer, A.S., Kuramochi, T., van den Broek, M. and Faaij, A., J. Power Sources, 2011, 196: 2298
2. [2]
  Goodenough, J.B. and Kim, Y., Chem. Mater., 2010, 22: 587 doi: 10.1021/cm901452z
3. [3]
  Goriparti, S., Miele, E., de Angelis, F., di Fabrizio, E., Zaccaria, R.P. and Capiglia, C., J. Power Sources, 2014, 257: 421
4. [4]
  Vincent, C.A. and Scrosati, B., "Modern batteries: An introduction to electrochemical power sources", ButterworthHeinemann, London, 1997
5. [5]
  Armand, M. and Tarascon, J.M., Nature, 2008, 451: 652 doi: 10.1038/451652a
6. [6]
  Kalhammer, F.R., Solid State Ionics, 2000, 135: 315 doi: 10.1016/S0167-2738(00)00454-9
7. [7]
  Kunze, M., Karatas, Y., Wiemhofe, H.D., Ecker, H. and Schonh, M., Phys. Chem. Chem. Phys., 2010, 12: 6844 doi: 10.1039/b925840j
8. [8]
  Saikia, D., Chen, Y.H., Pan, Y.C., Fang, J., Tsai, L.D., Fey, G.T.K. and Kao, H.M., J. Mater. Chem., 2011, 21: 10542
9. [9]
  Costa, C.M, Rodrigues, L.C., Sencadas, V., Silva, M.M. and Lanceros-Méndez S., Solid State Ionics, 2012, 217: 19 doi: 10.1016/j.ssi.2012.04.011
10. [10]
  Ha, H.J., Kwon, Y.H., Kim, J.Y. and Lee, S.Y., Electrochim. Acta, 2011, 57: 40
11. [11]
  Chen, Y.T., Chuang, Y.C., Su, J.H., Yu, H.C. and Chen-Yang, Y.W., J. Power Sources, 2011, 196: 2802
12. [12]
  Zhang, J., Huang, X., Wei, H., Fu, J., Huang, Y. and Tang, X., J. Appl. Electrochem., 2010, 40: 1475
13. [13]
  Patel, M., Patel, M.U.M. and Bhattacharyya, A.J., Chem. Sus. Chem., 2010, 3: 1371
14. [14]
  Sarnowska, A., Polska, I., Niedzicki, L., Marcine, M. and Zalewska, A., Electrochim. Acta, 2011, 57: 180 doi: 10.1016/j.electacta.2011.04.079
15. [15]
  Rajendran, S., Prabhu, M.R. and Rani, M.U., J. Power Sources, 2008, 180: 880 doi: 10.1016/j.jpowsour.2008.02.063
16. [16]
  Saikia, D., Wu, H.Y., Pan, Y.C., Lin, C.P., Huang, K.P., Chen, K.N., Fey, G.T.K. and Kao, H.M.,J. Power Sources, 2011, 196: 2826
17. [17]
  Rajendran, S. and Bama, V.S., J. Non-Cryst. Solids, 2010, 356: 2764 doi: 10.1016/j.jnoncrysol.2010.09.042
18. [18]
  Sun, X.G., Liu, G., Xie, J.B. and Han, Y.B., Solid State Ionics, 2004, 175: 713 doi: 10.1016/j.ssi.2003.11.043
19. [19]
  Kim, K.M., Park, N.G., Ryu, K.S. and Chang, S.H., Electrochim. Acta, 2006, 51: 5636
20. [20]
  Singh, T.J. and Bhat, S.V., J. Power Sources, 2004, 129: 281
21. [21]
  Vignarooban, K., Dissanayake, M.A.K.L., Albinsson, I. and Mellander, B.E., Solid State Ionics, 2014, 266: 25 doi: 10.1016/j.ssi.2014.08.002
22. [22]
  Pitawala, H.M.J.C., Dissanayake, M.A.K.L., Seneviratne, V.A., Mellander, B.E. and Albinson, I., J. Solid State Electron.,2008, 12: 783
23. [23]
  Shin, J.H., Jung, S.S., Kim, K.M. and Ahn, J.H., J. Mater. Sci.: Mater. Electron., 2002, 13: 727 doi: 10.1023/A:1021521207247
24. [24]
  Fan, L.Z., Dang, Z.M., Nan, C.W. and Li, M., Electrochim. Acta, 2002, 487: 205
25. [25]
  Pradeepa, P., Edwinraj, S., Sowmya, G., Kalaiselvimary, J. and Prabhu, M.R., Mater. Sci. Eng., B., 2016, 205: 6 doi: 10.1016/j.mseb.2015.11.009
26. [26]
  Pradhan, D.K. and Tripathy, S.N., Adv. Chem. Sci., 2013, 2: 2013
27. [27]
  Prajapati, G.K., Rosh, R. and Gupt, P.N., J. Phys. Chem. Solids, 2010, 71: 1717 doi: 10.1016/j.jpcs.2010.08.023
28. [28]
  Noor, S.A.M., Ahmad, A., Talib, I.A. and Rahman, M.Y.A., Ionics, 2010, 16: 161
29. [29]
  Simon, G.P., Shen, Z. and Cheng, Y.B., Eur. Polym. J., 2003, 39: 1924
30. [30]
  Kumar, K.K., Ravi, M., Pavani, Y., Bhavani, S., Sharma, A.K. and Narasimha Rao, V.V.R., Physica B, 2011, 406: 1706
31. [31]
  Naveen Kumar, K., Sivaiah, K. and Buddhudu, S., J. Lumin., 2014, 147: 316
32. [32]
  Ulaganatha, M. and Rajendran, S., Ionics, 2010, 16: 515 doi: 10.1007/s11581-009-0415-4
33. [33]
  Shukla, N. and Thakur, A.K., Solid State Ionics, 2010, 181: 921 doi: 10.1016/j.ssi.2010.05.023
34. [34]
  Rajendran, S. and Sivakumar, P., Physica B, 2008, 403: 509 doi: 10.1016/j.physb.2007.06.012
35. [35]
  Rajendran, S. and Prabhu, M.R., J. Appl. Electrochem., 2010, 40: 327 doi: 10.1007/s10800-009-9979-y
36. [36]
  Lee, T.K., Afiqah, S., Ahmad, A., Dahlan, H.M. and Rahman, M.Y.A., J. Solid State Electrochem., 2012, 16: 2251 doi: 10.1007/s10008-011-1633-z
37. [37]
  Coates, J., "Interpretation of IR spectra, a particular approach", Wiley, Chichester, 2000
38. [38]
  Khanmirzaei, M.H. and Ramesh, S., Int. J. Electrochem. Sci., 2013, 8: 9977
39. [39]
  Subbu, C., Rajendran, S., Kesavan, K. and Premila, R., Ionics, 2016, 22: 229
40. [40]
  Raghavan, P., Manue, J., Zhao, X., Kim, D.S., Ahn, J.H. and Nah, C., J. Power Sources, 2011, 196: 6742 doi: 10.1016/j.jpowsour.2010.10.089
41. [41]
  Chandra Sekhar, P., Naveen Kumar, P. and Sharma, A.K., IOSR J. Appl. Phys., 2012, 2: 1
42. [42]
  Rajendran, S., Sivakumar, M. and Subadevi, R., Mater. Lett., 2004, 58: 641
43. [43]
  Saikia, D., Ho, S.Y., Chang, Y.J., Fang, J., Tsai, L.D. and Kao, H.M., J. Membr. Sci., 2016, 503: 59
44. [44]
  Sun, H., Lu, B.Y., Hu, D.F., Duan, X.M., Xu, J.K., Zhen, S.J., Zhang, K.X., Zhu, X.F., Dong, L.Q. and Mo, D.Z.,Chinese J. Polym. Sci., 2015, 33: 1527
45. [45]
  Saito, Y., Kataoka, H., Quartarone, E. and Mustarelli, P., J. Phys. Chem. B., 2002, 106: 7200 doi: 10.1021/jp020633v
46. [46]
  Ramesh, S. and Arof, A.K., J. Power Sources, 2001, 99: 41 doi: 10.1016/S0378-7753(00)00690-X
47. [47]
  Jayanth, S., Arulsankar, A. and Sundaresan, B., Appl. Phys. A., 2016, 122: 109 doi: 10.1007/s00339-016-9623-8
48. [48]
  Stephen, A.M., Saito, Y., Muniyandi, N., Ranganathan, N.G., Kalyanasundram, S. and Elizabeth, R., Solid State Ionics,2002, 148: 467 doi: 10.1016/S0167-2738(02)00089-9
49. [49]
  Kumar, M. and Sekhon, S.S., Ionics, 2002, 8: 223 doi: 10.1007/BF02376072
50. [50]
  Kim, C.S. and Oh, S.M., Electrochim. Acta, 2000, 45: 2101 doi: 10.1016/S0013-4686(99)00426-0
51. [51]
  Ulaganathan, M., Nithya, R., Rajendran, S. and Raghu, S., Solid State Ionics, 2012, 218: 7 doi: 10.1016/j.ssi.2012.04.029
52. [52]
  Rajendran, S., Prabhu, M.R. and Rani, M.U., Int. J. Electrochem. Sci., 2008, 3: 282
1. [1]
  van Vliet, O., Brouwer, A.S., Kuramochi, T., van den Broek, M. and Faaij, A., J. Power Sources, 2011, 196: 2298
2. [2]
  Goodenough, J.B. and Kim, Y., Chem. Mater., 2010, 22: 587 doi: 10.1021/cm901452z
3. [3]
  Goriparti, S., Miele, E., de Angelis, F., di Fabrizio, E., Zaccaria, R.P. and Capiglia, C., J. Power Sources, 2014, 257: 421
4. [4]
  Vincent, C.A. and Scrosati, B., "Modern batteries: An introduction to electrochemical power sources", ButterworthHeinemann, London, 1997
5. [5]
  Armand, M. and Tarascon, J.M., Nature, 2008, 451: 652 doi: 10.1038/451652a
6. [6]
  Kalhammer, F.R., Solid State Ionics, 2000, 135: 315 doi: 10.1016/S0167-2738(00)00454-9
7. [7]
  Kunze, M., Karatas, Y., Wiemhofe, H.D., Ecker, H. and Schonh, M., Phys. Chem. Chem. Phys., 2010, 12: 6844 doi: 10.1039/b925840j
8. [8]
  Saikia, D., Chen, Y.H., Pan, Y.C., Fang, J., Tsai, L.D., Fey, G.T.K. and Kao, H.M., J. Mater. Chem., 2011, 21: 10542
9. [9]
  Costa, C.M, Rodrigues, L.C., Sencadas, V., Silva, M.M. and Lanceros-Méndez S., Solid State Ionics, 2012, 217: 19 doi: 10.1016/j.ssi.2012.04.011
10. [10]
  Ha, H.J., Kwon, Y.H., Kim, J.Y. and Lee, S.Y., Electrochim. Acta, 2011, 57: 40
11. [11]
  Chen, Y.T., Chuang, Y.C., Su, J.H., Yu, H.C. and Chen-Yang, Y.W., J. Power Sources, 2011, 196: 2802
12. [12]
  Zhang, J., Huang, X., Wei, H., Fu, J., Huang, Y. and Tang, X., J. Appl. Electrochem., 2010, 40: 1475
13. [13]
  Patel, M., Patel, M.U.M. and Bhattacharyya, A.J., Chem. Sus. Chem., 2010, 3: 1371
14. [14]
  Sarnowska, A., Polska, I., Niedzicki, L., Marcine, M. and Zalewska, A., Electrochim. Acta, 2011, 57: 180 doi: 10.1016/j.electacta.2011.04.079
15. [15]
  Rajendran, S., Prabhu, M.R. and Rani, M.U., J. Power Sources, 2008, 180: 880 doi: 10.1016/j.jpowsour.2008.02.063
16. [16]
  Saikia, D., Wu, H.Y., Pan, Y.C., Lin, C.P., Huang, K.P., Chen, K.N., Fey, G.T.K. and Kao, H.M.,J. Power Sources, 2011, 196: 2826
17. [17]
  Rajendran, S. and Bama, V.S., J. Non-Cryst. Solids, 2010, 356: 2764 doi: 10.1016/j.jnoncrysol.2010.09.042
18. [18]
  Sun, X.G., Liu, G., Xie, J.B. and Han, Y.B., Solid State Ionics, 2004, 175: 713 doi: 10.1016/j.ssi.2003.11.043
19. [19]
  Kim, K.M., Park, N.G., Ryu, K.S. and Chang, S.H., Electrochim. Acta, 2006, 51: 5636
20. [20]
  Singh, T.J. and Bhat, S.V., J. Power Sources, 2004, 129: 281
21. [21]
  Vignarooban, K., Dissanayake, M.A.K.L., Albinsson, I. and Mellander, B.E., Solid State Ionics, 2014, 266: 25 doi: 10.1016/j.ssi.2014.08.002
22. [22]
  Pitawala, H.M.J.C., Dissanayake, M.A.K.L., Seneviratne, V.A., Mellander, B.E. and Albinson, I., J. Solid State Electron.,2008, 12: 783
23. [23]
  Shin, J.H., Jung, S.S., Kim, K.M. and Ahn, J.H., J. Mater. Sci.: Mater. Electron., 2002, 13: 727 doi: 10.1023/A:1021521207247
24. [24]
  Fan, L.Z., Dang, Z.M., Nan, C.W. and Li, M., Electrochim. Acta, 2002, 487: 205
25. [25]
  Pradeepa, P., Edwinraj, S., Sowmya, G., Kalaiselvimary, J. and Prabhu, M.R., Mater. Sci. Eng., B., 2016, 205: 6 doi: 10.1016/j.mseb.2015.11.009
26. [26]
  Pradhan, D.K. and Tripathy, S.N., Adv. Chem. Sci., 2013, 2: 2013
27. [27]
  Prajapati, G.K., Rosh, R. and Gupt, P.N., J. Phys. Chem. Solids, 2010, 71: 1717 doi: 10.1016/j.jpcs.2010.08.023
28. [28]
  Noor, S.A.M., Ahmad, A., Talib, I.A. and Rahman, M.Y.A., Ionics, 2010, 16: 161
29. [29]
  Simon, G.P., Shen, Z. and Cheng, Y.B., Eur. Polym. J., 2003, 39: 1924
30. [30]
  Kumar, K.K., Ravi, M., Pavani, Y., Bhavani, S., Sharma, A.K. and Narasimha Rao, V.V.R., Physica B, 2011, 406: 1706
31. [31]
  Naveen Kumar, K., Sivaiah, K. and Buddhudu, S., J. Lumin., 2014, 147: 316
32. [32]
  Ulaganatha, M. and Rajendran, S., Ionics, 2010, 16: 515 doi: 10.1007/s11581-009-0415-4
33. [33]
  Shukla, N. and Thakur, A.K., Solid State Ionics, 2010, 181: 921 doi: 10.1016/j.ssi.2010.05.023
34. [34]
  Rajendran, S. and Sivakumar, P., Physica B, 2008, 403: 509 doi: 10.1016/j.physb.2007.06.012
35. [35]
  Rajendran, S. and Prabhu, M.R., J. Appl. Electrochem., 2010, 40: 327 doi: 10.1007/s10800-009-9979-y
36. [36]
  Lee, T.K., Afiqah, S., Ahmad, A., Dahlan, H.M. and Rahman, M.Y.A., J. Solid State Electrochem., 2012, 16: 2251 doi: 10.1007/s10008-011-1633-z
37. [37]
  Coates, J., "Interpretation of IR spectra, a particular approach", Wiley, Chichester, 2000
38. [38]
  Khanmirzaei, M.H. and Ramesh, S., Int. J. Electrochem. Sci., 2013, 8: 9977
39. [39]
  Subbu, C., Rajendran, S., Kesavan, K. and Premila, R., Ionics, 2016, 22: 229
40. [40]
  Raghavan, P., Manue, J., Zhao, X., Kim, D.S., Ahn, J.H. and Nah, C., J. Power Sources, 2011, 196: 6742 doi: 10.1016/j.jpowsour.2010.10.089
41. [41]
  Chandra Sekhar, P., Naveen Kumar, P. and Sharma, A.K., IOSR J. Appl. Phys., 2012, 2: 1
42. [42]
  Rajendran, S., Sivakumar, M. and Subadevi, R., Mater. Lett., 2004, 58: 641
43. [43]
  Saikia, D., Ho, S.Y., Chang, Y.J., Fang, J., Tsai, L.D. and Kao, H.M., J. Membr. Sci., 2016, 503: 59
44. [44]
  Sun, H., Lu, B.Y., Hu, D.F., Duan, X.M., Xu, J.K., Zhen, S.J., Zhang, K.X., Zhu, X.F., Dong, L.Q. and Mo, D.Z.,Chinese J. Polym. Sci., 2015, 33: 1527
45. [45]
  Saito, Y., Kataoka, H., Quartarone, E. and Mustarelli, P., J. Phys. Chem. B., 2002, 106: 7200 doi: 10.1021/jp020633v
46. [46]
  Ramesh, S. and Arof, A.K., J. Power Sources, 2001, 99: 41 doi: 10.1016/S0378-7753(00)00690-X
47. [47]
  Jayanth, S., Arulsankar, A. and Sundaresan, B., Appl. Phys. A., 2016, 122: 109 doi: 10.1007/s00339-016-9623-8
48. [48]
  Stephen, A.M., Saito, Y., Muniyandi, N., Ranganathan, N.G., Kalyanasundram, S. and Elizabeth, R., Solid State Ionics,2002, 148: 467 doi: 10.1016/S0167-2738(02)00089-9
49. [49]
  Kumar, M. and Sekhon, S.S., Ionics, 2002, 8: 223 doi: 10.1007/BF02376072
50. [50]
  Kim, C.S. and Oh, S.M., Electrochim. Acta, 2000, 45: 2101 doi: 10.1016/S0013-4686(99)00426-0
51. [51]
  Ulaganathan, M., Nithya, R., Rajendran, S. and Raghu, S., Solid State Ionics, 2012, 218: 7 doi: 10.1016/j.ssi.2012.04.029
52. [52]
  Rajendran, S., Prabhu, M.R. and Rani, M.U., Int. J. Electrochem. Sci., 2008, 3: 282
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20. [20]
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沈阳化工大学材料科学与工程学院沈阳 110142

Plasticized Polymer Electrolyte Membranes Based on PEO/PVdF-HFP for Use as an Effective Electrolyte in Lithium-ion Batteries

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通讯作者: 陈斌, bchen63@163.com