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Citation: Wang Li, Guo Zhao-xia, Yu Jian. Effects of Zinc Oxide Nanoparticles on the Morphology and Viscoelastic Properties of Polyamide 6/Poly(butylene terephthalate) Blends[J]. Chinese Journal of Polymer Science, ;2017, 35(3): 434-445. doi: 10.1007/s10118-017-1905-x shu

Effects of Zinc Oxide Nanoparticles on the Morphology and Viscoelastic Properties of Polyamide 6/Poly(butylene terephthalate) Blends

  • a.

    The State Key Laboratory of Chemical Resource Engineering, Beijing 100029, China

  • b.

    College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

  • c.

    Key Laboratory of Advanced Materials, Ministry of Education, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

  • The morphology of polyamide 6/poly(butylene terephthalate) (PA6/PBT, 70/30, W/W) blends filled with pristine Zinc oxide (ZnO) nanoparticles and ZnO surface-modified by γ-glycidoxypropyltrimethoxysilane (K-ZnO) was investigated. The incorporation of ZnO and K-ZnO by one-step compounding both resulted in a smaller size and narrower distribution of PBT domains and the effect of ZnO was greater than K-ZnO. To reveal the underlying mechanism, two-step compounding in which ZnO or K-ZnO was premixed with PA6 or PBT was conducted and the finest morphology was achieved when mixing PA6 with premixed PBT/ZnO. Transmission electron microscopy (TEM) demonstrated that ZnO was distributed in PBT in all cases and K-ZnO was enriched at the interface except when K-ZnO was premixed with PBT. ZnO and K-ZnO caused a deterioration in the melt rheological properties of PBT, which played a dominating role in the morphological changes. In addition, the interfacial localization of K-ZnO enhanced the dynamic rheological properties of PA6/PBT blends substantially.
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