Citation: Huang Zhi-hao, Zhou Yan-yan, Wang Zi-mu, Li Ying, Zhang Wei, Zhou Nian-chen, Zhang Zheng-biao, Zhu Xiu-lin. Recent Advances of CuAAC Click Reaction in Building Cyclic Polymer[J]. Chinese Journal of Polymer Science, ;2017, 35(3): 317-341. doi: 10.1007/s10118-017-1902-0 shu

Recent Advances of CuAAC Click Reaction in Building Cyclic Polymer

State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

Corresponding author: Zhang Zheng-biao, zhangzhengbiao@suda.edu.cn Zhu Xiu-lin, xlzhu@suda.edu.cn
Received Date: 5 September 2016
Revised Date: 28 September 2016
Accepted Date: 28 September 2016

Fund Project: the National Natural Science Foundation of China 21234005the State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) and the Program of Innovative Research Team of Soochow University

Cyclic polymers have attracted more and more attentions in recent years because of their unique topological structures and characteristic properties in both solution and bulk state. There are relatively few reports on cyclic polymers, partly because of the more demanding synthetic procedures. In recent years, "click" reaction, especially Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC), has been widely utilized in the synthesis of cyclic polymer materials because of its high efficiency and low susceptibility to side reactions. In this review, we will focus on three aspects:(1) Constructions of monocyclic polymer using CuAAC "click" chemistry; (2) Formation of complex cyclic polymer topologies through CuAAC reactions; (3) Using CuAAC "click" reaction in the precise synthesis of molecularly defined macrocycles. We believe that the CuAAC click reaction is playing an important role in the design and synthesis of functional cyclic polymers.
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沈阳化工大学材料科学与工程学院沈阳 110142