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Citation: Fu-ai Teng, Feng-li Liu, Lu Han, Zheng-ju Zhu, Yi-fang Zhang, Zhi-jin Wu, Zhe-wen Han, Wen-bin Zhang, Hui Li. Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C60-oligofluorene Conjugates[J]. Chinese Journal of Polymer Science, ;2017, 35(4): 503-514. doi: 10.1007/s10118-017-1899-4 shu

Design, Synthesis, and Optical/Electronic Properties of a Series of Sphere-Rod Shape Amphiphiles Based on the C60-oligofluorene Conjugates

  • a.

    School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China

  • b.

    Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, College of Chemistry and Molecular Engineering, Center for Soft Matter Science and Engineering, Peking University, Beijing 100871, China

  • Corresponding author: Zhe-wen Han, zwhan@ecust.edu.cn Wen-bin Zhang, wenbin@pku.edu.cn Hui Li, lihui@ecust.edu.cn
  • Received Date: 6 September 2016
    Revised Date: 11 October 2016
    Accepted Date: 12 October 2016

    Fund Project: the Natural Science Foundation of Shanghai 10ZR1407600the International Science & Technology Cooperation Program of China 2010DFB70470

  • A series of sphere-rod shape amphiphiles were designed and synthesized by connecting the rod-like oligofluorenes with different lengths (OFn) to the different positions of the spherical[60]fullerene (C60) through a rigid linkage. The conjugates were characterized by 1H-NMR, 13C-NMR, FTIR, EA and MALDI-TOF mass spectrometry. The optical and electronic properties of the conjugates were studied by UV-Vis absorption spectroscopy, fluorescence spectrometry, and cyclic voltammetry. The results from UV-Vis absorption spectroscopy and cyclic voltammetry indicated that the energy profiles of C60 and OFn remained unchanged when different lengths of OFn were attached to C60. The electron affinities of the OFn-C60 conjugates were close to that of C60, while slight electronic interaction was found between the two individual chromophores (C60 and OFn) in their ground states. The fluorescence spectra exhibited a complete fluorescence quenching in the toluene solution, suggesting an effective energy transfer from OFn to C60. It presents a systematic study on the self-assembly, structure-property relationship, and potential technical applications of the conjugates.
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