Citation: Zi-qing Wang, Yuan-sheng Bai, Wei Jiang, Xian-gui Yang, Shao-ying Liu, Gong-ying Wang. Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process[J]. Chinese Journal of Polymer Science, ;2017, 35(1): 130-140. doi: 10.1007/s10118-017-1887-8 shu

Structure-Activity Correlations of Calcined Mg-Al Hydrocalcites for Aliphatic Polycarbonate Synthesis via Transesterification Process

Zi-qing Wang ^a,b,c ,
Yuan-sheng Bai ^a ,
Wei Jiang ^a ,
Xian-gui Yang ^a,c ,
Shao-ying Liu ^a,c ,
Gong-ying Wang ^a,c,,

a.
Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Changzhou Institute of Chemistry, Changzhou 213164, China

Corresponding author: Gong-ying Wang, gywang@cioc.ac.cn;wanggongying1102@126.com
Received Date: 19 August 2016
Revised Date: 5 September 2016
Accepted Date: 11 September 2016

Fund Project: Key Research and Innovation Program of Jiangsu Province BE2015055the National Key Technology Pillar Program 2013BAC11B05the Science&Technology Pillar Program in Sichuan Province 2016GZ0228

Mg-Al mixed oxides with different Mg/Al molar ratio were prepared by thermal decomposition of hydrotalcite-like precursors at 500℃ for 5.0 h and used as catalysts for the transesterification of diphenyl carbonate with 1,4-butanediol to synthesize high-molecular-weight poly(butylene carbonate) (PBC). The structure-activity correlations of these catalysts in this transesterification process were discussed by means of various characterization techniques. It was found that the chain growth for the formation of PBC can only be obtained through connecting-OH and-OC(C) OC₆H₅ end-group upon removing the generated phenol, and the sample with Mg/Al molar ratio of 4.0 exhibited the best catalytic performance, giving PBC with M_w of 1.64×10⁵ g/mol at 210℃ for 3.0 h. This excellent activity depended mainly on the specific surface area and basicity rather than pore structure or crystallite size of MgO.
- Mg-Al hydrotalcite,
- Poly(butylene carbonate),
- Diphenyl carbonate,
- Transesterification,
- Basic sites
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