Citation: Wei Wan-chu, Feng Shuo, Zheng Cai-xia, Liang Guo-dong, Zhu Fang-ming. Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films[J]. Chinese Journal of Polymer Science, ;2017, 35(3): 400-406. doi: 10.1007/s10118-017-1884-y shu

Fluorescent Quantum Yield of Pyrene Probe in Ultrathin Polymer Films

a.
Guangdong Provincial Key Laboratory for High Performance Polymeric Composites, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
b.
Key Laboratory for Polymer Composite and Functional Materials of Ministry of Education, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China

Corresponding author: Zhu Fang-ming, ceszfm@mail.sysu.edu.cn
Received Date: 20 August 2016
Revised Date: 20 September 2016
Accepted Date: 28 September 2016

Fund Project: the Natural Science Foundation of Guangdong Province S2013030013474 and 2014A030313178the National Natural Science Foundation of China 21174167 and 51573212

The fluorescently labelled polymers including pyrene-labelled polystyrene (PyPS) and pyrene-labelled poly(methyl methacrylate) (PyPMMA) with narrow molecular weight distributions were synthesized by the atom transfer radical copolymerization (ATRCP) of styrene or methyl methacrylate with 1-pyrenemethyl methacrylate (PyMMA). The ultrathin PyPS and PyPMMA films with the thickness ranging from 30 nm to 400 nm supported on the quartz slides were prepared by spin-coating. The fluorescent quantum yield (QY) of the pyrene probe in the ultrathin polymer films was investigated by the photoluminescence spectrometer using an integrating sphere detector. The QY decreased with the reduction of film thickness in the sub-200 nm range.
- Pyrene-labelled polystyrene,
- Pyrene-labelled poly(methyl methacrylate),
- Ultrathin polymer films,
- Fluorescent quantum yield
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